| 二元含铜类水滑石催化苯制苯酚反应的研究 |
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| 引用本文： | 黄军左,刘青青,刘宝生,陈小平.二元含铜类水滑石催化苯制苯酚反应的研究[J].茂名学院学报,2013(3):1-3. |
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| 作者姓名： | 黄军左 刘青青 刘宝生 陈小平 |
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| 作者单位： | 1. 广东石油化工学院工业催化研究所,广东茂名,525000
2. 广东石油化工学院工业催化研究所，广东茂名525000; 成都理工大学材料与化学化工学院，四川成都610059 |
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| 摘 要： | 采用共沉淀法制备二元含铜类水滑石，并用于苯直接氧化制苯酚反应的催化性能研究。结果表明，当适宜的反应条件为：反应温度65℃、反应时间6h、催化剂用量10mg、溶剂用量15mL、n（C6H6）：n（H2O2）=3：1时，CuA1-IDHs具有最强的催化活性，苯酚收率达3．5％，无副产物，经表征证明产物的存在。
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| 关 键 词： | 共沉淀法 类水滑石 二元 苯 苯酚 |
The Preparation of the Binary Copper -containing LDHs and Catalytic of Benzene to Phenol |
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| HUANG Jun-zuo
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LIU Qing-qing
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LIU Bao-sheng
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CHEN Xiao-ping.The Preparation of the Binary Copper -containing LDHs and Catalytic of Benzene to Phenol[J].Journal of Maoming College,2013(3):1-3. |
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| Authors: | HUANG Jun-zuo LIU Qing-qing LIU Bao-sheng CHEN Xiao-ping |
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| Institution: | 1(1.Institute of Industrial Catalysis,Guangdong University of Petrochemical Technology,Maoming 525000,China;2.College of Material,Chemistry & Chemical Engineering,Chengdu University of Technology,Chengdu 610059,China) |
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| Abstract: | The Coppercontaining LDHs metal composite oxides were obtained. The structural information of catalysts was characterized by XRD, FT- IR. The results showed that the benzene conversion was 3.5% and found no byproducts in the appropriate conditions of reaction tempemaxre 65 ℃, and reaction time 6 h, taking 15 mL pyridine as solvent, and 10 mg catalyst, and n （C6H6 ） / n （H2O2 ） is 3：1 with CuAl - LDHs. |
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| Keywords: | coprecipitation method LDHs binary benzene phenol |
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