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Sm_(1-x)Zn_xFeO_3半导体材料的制备和气敏性能研究
引用本文:李天应,李兵斌,谢小雪,童晓莹,黄敏建,王俊海,葛秀涛.Sm_(1-x)Zn_xFeO_3半导体材料的制备和气敏性能研究[J].滁州学院学报,2011,13(2):52-54.
作者姓名:李天应  李兵斌  谢小雪  童晓莹  黄敏建  王俊海  葛秀涛
作者单位:滁州学院化学与生命科学系,安徽滁州,239000
基金项目:滁州学院首届大学生科技创新基金项目,安徽省应用化学省级重点学科建设项目,安徽省教育厅基金项目
摘    要:用化学共沉淀法制备了Sm1-xZnxFeO3(0≤x≤0.10)半导体气敏材料。对其固相组成、导电行为和气敏性能进行了研究。结果表明:该系列粉体为正交晶系钙钛矿型结构;6%Zn掺杂SmFeO3导电优于纯相;在160℃工作温度下,6%Zn掺杂微粉制作的元件对0.1%丙酮的灵敏度高达568,是相同工作条件下纯相SmFeO3元件的8.5倍,响应-恢复时间分别为4S,和4min。

关 键 词:Sm1-xZnxFeO3  钙钛矿结构  气敏材料  丙酮

Preparation and Gas-Sensitivity of the Semiconducting Material Sm1-xZnxFeO3
Li Tianying,Li Bingbin,Xie Xiaoxue,Tong Xiaoying,Huang Minjian,Wang Junhai,Ge Xiutao.Preparation and Gas-Sensitivity of the Semiconducting Material Sm1-xZnxFeO3[J].Journal of Chuzhou University,2011,13(2):52-54.
Authors:Li Tianying  Li Bingbin  Xie Xiaoxue  Tong Xiaoying  Huang Minjian  Wang Junhai  Ge Xiutao
Institution:(Department of Chemistry and Life Science,Chuzhou University,Chuzhou 239000,China)
Abstract:The semiconducting gas-sensitive material Sm1-xZnxFeO3(0≤x≤0.10) was prepared by means of chemical coprecipitation.Its phase constituents,conductivity and gas-sensitivity were studied.The results show that Sm1-xZnxFeO3(0≤x≤0.10) powder has an orthorhombic perovskite structure;that conductivity of 6%Zn blended with SmFeO3 is better than its pure phase;and that in the operating temperature 160 ℃,the sensitivity of Sm0.94Zn0.06FeO3 is 568 to 0.1% acetone(volume fraction) with the response time of 4 seconds and the recovery time of 4 minutes,which is 8.5 times more than the pure phase sensor SmFeO3 under the same conditions.
Keywords:Sm1-xZnxFeO3  perovskite structure  gas-sensitive material  acetone
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