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溶剂束缚球假说对稀溶液依数性的解释
引用本文:杨晓东,余玉叶,肖珊美.溶剂束缚球假说对稀溶液依数性的解释[J].金华职业技术学院学报,2001,1(4):57-62.
作者姓名:杨晓东  余玉叶  肖珊美
作者单位:1. 金华职业技术学院医学院,副教授,321000,金华市
2. 金华职业技术学院人文师范学院,高级讲师
3. 金华职业技术学院理工学院,副教授
摘    要:目的:从溶质和溶剂粒子之间的作用力和溶液的凝聚态解释稀溶液依数性。方法:根据拉乌尔定律提出后100多年来发现的实验事实,分析溶质和溶剂粒子的受力情况和凝聚态。结果:提出了“溶剂束缚球”假说,成功地解释了稀溶液依数性产生的原因,指出了拉乌尔定律错误的根源。结论:溶剂束缚球和分子平均缔合度是产生稀溶液依数性的原因。

关 键 词:拉乌尔定律  “溶剂束缚球”假说  稀溶液依数性  分子平均缔合度  凝聚态
修稿时间:2001年9月30日

The Explanation of Colligated Properties of Thin Solution through Fettered Solvent's Spheroid Hypothesis
Yang Xiaodong Yu Yuye Xiao Shanmei.The Explanation of Colligated Properties of Thin Solution through Fettered Solvent''''s Spheroid Hypothesis[J].Journal of Jinhua College of Profession and Technology,2001,1(4):57-62.
Authors:Yang Xiaodong Yu Yuye Xiao Shanmei
Institution:Jinhua College of Profession and Technology
Abstract:Purpose:To explain colligated properties of thin solution by the way of applied force between solute and solvent povrticles and condensed state of solution.Method:To analyze the applied force between solute and solvent particles and the condensed state of sdution according to the experimental findings over100years after Raoult Law put forward.Result:The hypothesis of fettered solvent's spheroid successfully interprets the causes of the development of colligated properties of thin solution and analyses the roots of the Raoult Law.Conclusion:Fettered solvent's spheroid and average molec-ular association level is the main reason for producing colligated properties of thin solution.
Keywords:Colligated properties of thin solution Raoult Law Fettered solvent's spheroid Average molecular association level Condensed state  
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