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芴9-位上的取代基对二聚芴多功能性质的影响
引用本文:李仲辉,奉强,何冰,刘玉容,张琦,孙康,夏萍芳,张小玲.芴9-位上的取代基对二聚芴多功能性质的影响[J].四川教育学院学报,2013(11):1-5.
作者姓名:李仲辉  奉强  何冰  刘玉容  张琦  孙康  夏萍芳  张小玲
作者单位:成都师范学院化学与应用化学系/多功能分子研究所,成都611130
基金项目:四川省科技厅科技支撑计划项目(编号2009GZ0167、2012FZ0129)
摘    要:化学分子结构与性质关系的研究一直是化学领域研究的热点.文章设计合成了末端被二苯胺基取代的对称的二聚芴的9-位氢分别被甲基、丁基和苯基取代后获得的二聚芴,并考察这些取代基对二聚芴的热稳定性、光学性质和电化学性质的影响.

关 键 词:二聚芴  合成  取代基  多功能性质

Influence of Substituents at the 9-Position of Fluorene on the Functional Properties of Bifluorenes
LI Zhong-hui,FENG Qiang,HE Bing,LIU Yu-rong,ZHANG Qi,SUN Kang,XIA Ping-fang,ZHANG Xiao-ling.Influence of Substituents at the 9-Position of Fluorene on the Functional Properties of Bifluorenes[J].Journal of Sichuan College of Education,2013(11):1-5.
Authors:LI Zhong-hui  FENG Qiang  HE Bing  LIU Yu-rong  ZHANG Qi  SUN Kang  XIA Ping-fang  ZHANG Xiao-ling
Institution:(Institute of Functional Molecules, Department of Chemistry and Applied Chemistry, Chengdu Normal University, Chengdu, Sichuan 611130, China)
Abstract:Research on relationships structures of and properties of chemical molecules is still a hot field in Chemis- try. The bifluorenes endcapped by diphenylamines and 9 - hydrogen substituted by methyl, n - butyl and phenyl have been designed and synthesized in this paper, the influence of these substituents on their functional property such as ther- mal stabilities, photophysical property, electrochemical stability have also been studied.
Keywords:bifluorene  synthesis  substituent  functional properties
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