| 固体酸催化合成氯乙酸戊酯 |
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| 引用本文： | 俞善信.固体酸催化合成氯乙酸戊酯[J].湘南学院学报,2009,30(5):51-55. |
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| 作者姓名： | 俞善信 |
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| 作者单位： | 湖南师范大学化学化工学院,湖南,长沙,410081 |
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| 摘 要： | 固体酸是一种好的催化剂，它能够代替硫酸作为酯化催化剂．评述了对甲苯磺酸、磺酸盐、氨基磺酸、强酸性阳离子交换树脂、六水三氯化铁、五水四氯化锡、三氯化铝-硫酸铜复盐、结晶硫酸铝、一水硫酸氢钠、固体超强酸、杂多酸和分子筛等催化合成氯乙酸戊酯的合成方法．认为有机磺酸盐、氨基磺酸、强酸性阳离子交换树脂、结晶硫酸铝、一水硫酸氢钠、固体超强酸、杂多酸和分子筛等是合成氯乙酸正丁酯具有实用价值的催化剂．
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| 关 键 词： | 氯乙酸戊酯 合成 固体酸 催化 |
Synthesis of Amyl Chloroacetate Catalyzed by Solid Acid |
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| YU Shan-xin.Synthesis of Amyl Chloroacetate Catalyzed by Solid Acid[J].Journal of Xiangnan University,2009,30(5):51-55. |
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| Authors: | YU Shan-xin |
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| Institution: | YU Shan-xin(College of Chemistry , Chemical Engineering,Hunan Normal University,Changsha 410081,China) |
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| Abstract: | Solid acid is a good catalyst.It can be used as catalyst for the esterification instead of sulphuric acid.The synthesis methods of amyl chloroacetate catalyzed by p-toluene sulfonic acid,sulfonate,amino sulfonic acid,strongly acidic cationic exchange resin,ferric chloride hexahydrate,stannic chloride pentahydrate,aluminium chloride-copper sulfate,crystal aluminum sulfate,sodium bisulfate monohydrate,solid super acid,heteropoly acid and molecular sieve et al.were reviewed.It is suggested that organic sulfona... |
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| Keywords: | amyl chloroacetate synthesis solid acid catalysis |
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