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CoCl_2掺杂聚苯胺修饰电极测定水中的溶解氧
引用本文:钟平,钟陵,黄桂萍.CoCl_2掺杂聚苯胺修饰电极测定水中的溶解氧[J].赣南师范学院学报,2003(3):59-61.
作者姓名:钟平  钟陵  黄桂萍
作者单位:1. 赣南师范学院,化学系与生命科学,江西,赣州,341000
2. 赣州市环境监测站,江西,赣州,341000
摘    要:制备了可溶性聚苯胺掺杂CoCl2修饰玻碳电极,并用循环伏安法测定水中的溶解氧.研究表明:阴极峰电流ipc与水中的溶解氧浓度具有良好的线性关系.将测定结果与碘量法相比较,误差<±3%.另外该法操作简便、快速,所用电极性能稳定,为化学修饰电极用于分析水中溶解氧提供了一种新的途径.

关 键 词:聚苯胺  修饰电极  CoCl2掺杂  水中溶解氧
文章编号:1004-8332(2003)03-0059-03
修稿时间:2002年11月28

Polyaniline Mixed With CoCl2 Modified Glassy Carbon Eelectrode for Determination of Dissolved Dioxygen in Water
Abstract:This paper prepares the glassy carbon electrode modified by sofubilised polyaniline mixed with cobalt dichloride and measured the dissolved oxygen in the water with cyclic voltammetny.The research indicates that the cathodic peak current ipC is linear relative with the dissolved oxygen.Compared with iodinetry the deviation of the measurement is below five percent and has remarkable applied value.Moreover,the operation of the method is very simple and quick.The behaviour of electrode is stabe and it offered a new way to apply the modified electrode for measuring the oxygen dissolved in water.
Keywords:polyanliline  chemically modified electrode  Mixare of CoCl_2  Dissolved oxygen in water
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