| AOM对八面体和平面四方形配合物的应用 |
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| 引用本文： | 钟平.AOM对八面体和平面四方形配合物的应用[J].赣南师范学院学报,1990(Z1). |
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| 作者姓名： | 钟平 |
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| 作者单位： | 赣南师范学院化学系 |
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| 摘 要： | 本文用AOM(角重叠模型)的近似方法,计算了各种电子构型的八面体和平面四方形配合物的MOSE,得出了八面体配合物的畸变倾向于四方畸变的结论。用此方法还能预测一些姜一太勒定理不能预测的配合物的几何构型。
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| 关 键 词： | 八面体配合物 畸变 AOM应用 |
APPIYING AOM TO THE COORDINATION COMPOUNDS OF OCTAHEDROM AND TETRAGON |
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| Zhong Ping.APPIYING AOM TO THE COORDINATION COMPOUNDS OF OCTAHEDROM AND TETRAGON[J].Journal of Gannan Teachers' College(Social Science(2)),1990(Z1). |
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| Authors: | Zhong Ping |
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| Institution: | Department of Chemistry |
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| Abstract: | Using the approximate method of AOM (Angle Overlap Model) , the paper calculates the MOSE (Molecular Orbit Energy) of coodinat-ion compounds of octahedron and tetragon of various eletronic configudr-ations.The calculation comes to the conclusion that the distortion of the coordinatioh compound of octahedron tends towards tetragonal distortion, This method can also be used to calculate some geomctrical configurations of the coordination which H.A. Jahn's and E.Teller's theorems cannot calculate. |
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| Keywords: | coordination compounds of octahedron distortion AOM applioation |
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