| 某些4-氨基-1-氮杂-1,3-丁二烯(Ⅱ)新化合物及其3-氯(Ⅲ)和3-溴(Ⅳ)衍生物的合成 |
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| 引用本文： | 谭成权,Pedro J.Campos,Miguel A.Rodriguez.某些4-氨基-1-氮杂-1,3-丁二烯(Ⅱ)新化合物及其3-氯(Ⅲ)和3-溴(Ⅳ)衍生物的合成[J].大连大学学报,1996(2). |
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| 作者姓名： | 谭成权 Pedro J.Campos Miguel A.Rodriguez |
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| 作者单位： | 大连大学化学化工系，西班牙La Rioja大学化学系，西班牙La Rioja大学化学系 大连 116622 |
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| 摘 要： | 用希夫碱(Ⅰ)在无水三氯化铝(AlCl_3)或二异丙胺锂(LDA)与氯化锌乙醚溶液(ZnCl_2·OEt_2)存在下加成于腈类化合物,制备了一些新的4-氨基-1-氮杂-1,3-丁二烯(Ⅱ)。用N-氯琥珀酰亚胺(NCS)和N-溴琥珀酰亚胺(NBS)与带有3-位烯胺氢原子的化合物Ⅱ合成了3-氯(Ⅲ)和3-溴(Ⅳ)衍生物。全部化合物Ⅱ、Ⅲ和Ⅳ都经MS、~1H和~(13)C NMR定性,文中给出了其MS、~1H和~(13)C NMR数据。
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| 关 键 词： | 4-氨基-1-氮杂-1 3-丁二烯 希夫碱 腈 |
Synthesis of Some New 4-Amino-1-aza-1,3-Butadienes (Ⅱ) and Their 3-Chloro(Ⅲ), 3-Bromo(Ⅳ) Derivatives |
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| Tan Chengquan.Synthesis of Some New 4-Amino-1-aza-1,3-Butadienes (Ⅱ) and Their 3-Chloro(Ⅲ), 3-Bromo(Ⅳ) Derivatives[J].Journal of Dalian University,1996(2). |
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| Authors: | Tan Chengquan |
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| Abstract: | Some new 4-amino-1-aza-1, 3-butadienes (Ⅱ) were prepared by the addition of Schiff base(Ⅰ) to nitrile in the presence of anhydrous aluminium trichloride (AlCl_3) or lithium diisopropylamide (LDA) and zinc chloride ether solution (ZnCl_2·OEt_2). 3-Chloro (Ⅲ) and 3-bromo (Ⅳ) derivatines of Ⅱ were synthesized by the reaction of N-chlorosuccinimide (NCS)and N-bromo-succinimide (NBS)with compounds Ⅱ which have a eniminic hydrogen on the 3-position. All compounds Ⅱ, Ⅲ and Ⅳ were full characterized by MS, ~1H and ~(13)C NMR, the data of M、S、~1H and ~(13)C NMR were listed. |
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| Keywords: | 4-amino- 1 -aza- 1 3 -butadiene Schiff base nitrile |
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