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乙烯基聚合物和(口恶)二唑衍生物的电致发光器件中激基复合物的蓝色发射
引用本文:朱文清,蒋雪茵,张志林.乙烯基聚合物和(口恶)二唑衍生物的电致发光器件中激基复合物的蓝色发射[J].上海大学学报(英文版),2005,9(3):275-278.
作者姓名:朱文清  蒋雪茵  张志林
作者单位:SchoolofMaterialsScienceandEngineering,ShanghaiUniversity,Shanghai201800,P.R.China
基金项目:theNationalNaturalScienceFoundationofChina(GrantNos.60077020,90201034),NationalHighTechnologyResearchandDevelopmentProgram(GrantNo.863-2001AA313070),theScienceFoundationofShanghaiMunicipalCommissionofScienceandTechnology(GrantNo.012261055),theScienceFoundationofShanghaiMunicipalCommissionofEducation(GrantNo.03AK26)
摘    要:Two types of molecular and polymer devices employing (2-(4′-biphenyl)-5-(4““““““““-tert-butylphenyl)-1,3,4-oxadiazole) (PBD)and poly(N-vinylcarbazole) (PVK) as electron transport and hole transport materials, respectively, have been fabricated. The structures of these two devices are ITO/PVK( 70 nm)/PBD(60 nm)/A1 and ITO/PVK: PBD (1:1 by mass, 70 nm)/A1. The formation of exciplex is evident by comparing the electroluminescence (EL) of a bi-layer device and the photoluminescence (PL) of a PVK and PBD mixed film.The maximum emission energy of exciplex evaluated is consistent with the peak emission of EL. Blue emissions from both devices are obtained. The type of exicplex is interpreted based on the energy level diagram of the bi-layer device.

关 键 词:场致发光  蓝散射光  颜色调整  聚乙烯
收稿时间:31 October 2003

Blue emission from exciplex in electroluminescent devices made from vinyl polymer and oxadiazole derivative
Zhu?Wen-qing,Jiang?Xue-yin,Zhang?Zhi-lin.Blue emission from exciplex in electroluminescent devices made from vinyl polymer and oxadiazole derivative[J].Journal of Shanghai University(English Edition),2005,9(3):275-278.
Authors:Zhu Wen-qing  Jiang Xue-yin  Zhang Zhi-lin
Institution:School of Materials Science and Engineering, Shanghai University, Shanghai 201800, P.R. China
Abstract:Two types of molecular and polymer devices employing (2-(4′-biphenyl)-5-(4″-tert-butylphenyl)-l,3,4-oxadiazole) (PBD) and poly(N-vinylcarbazole)(PVK) as electron transport and hole transport materials, respectively, have been fabricated. The structures of these two devices are ITO/PVK(70 nm)/PBD(60 nm)/Al and ITO/FVK: PBD(1:1 by mass, 70 nm)/Al. The formation of exciplex is evident by comparing the electroluminescence (EL) of a bi-layer device and the photoluminescence (PL) of a PVK and PBD mixed film. The maximum emission energy of exciplex evaluated is consistent with the peak emission of EL. Blue emissions from both devices are obtained. The type of exicplex is interpreted based on the energy level diagram of the bi-layer device. Project supported by the National Natural Science Foundation of China(Grant Nos. 60077020, 90201034), National High-Technology Research and Development Program ( Grant No. 863 -2001AA313070), the Science Foundation of Shanghai Municipal Commission of Science and Technology (Grant No. 012261055), the Science Foundation of Shanghai Municipal Commission of Education Grant No. 03AK26)
Keywords:organic electroluminescence  exciplex  blue emission  color tuning  
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