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CaO+SiO2+Al2O3+MgO+FeO五元渣系中FeO活度的研究
引用本文:吕庆,赵丽树,王成立,张淑会,李福民,刘增勋.CaO+SiO2+Al2O3+MgO+FeO五元渣系中FeO活度的研究[J].上海大学学报(英文版),2008,12(5).
作者姓名:吕庆  赵丽树  王成立  张淑会  李福民  刘增勋
作者单位:[1]School of Metallurgy and Energy, Hebei Polytechnic University, Tangshan 063009, P. R. China [2]School of Materialsand Metallurgy, Northeastern University, Shenyang 110004, P: R. China
摘    要:

关 键 词:CaO+Si02+A1203+Mg0+FeO  五元渣系  FeO  活度

Activities of FeO in CaO-SiO2-Al2O3-MgO-FeO slags
L Qing,ZHAO Li-shu,WANG Cheng-li,ZHANG Shu-hui,LI Fu-min,LIU Zeng-xun.Activities of FeO in CaO-SiO2-Al2O3-MgO-FeO slags[J].Journal of Shanghai University(English Edition),2008,12(5).
Authors:L Qing  ZHAO Li-shu  WANG Cheng-li  ZHANG Shu-hui  LI Fu-min  LIU Zeng-xun
Institution:1. School of Metallurgy and Energy, Hebei Polytechnic University, Tangshan 063009, P. R. China
2. School of Materials and Metallurgy, Northeastern University, Shenyang 110004, P. R. China
Abstract:Activities of FeO in CaO-SiO2-Al2O3-MgO-FeO slags were determined at 1673 K by electrochemical measurements of the solid electrolyte cell: Mo |Mo MoO2ZrO2(MgO)Fe (CaO-SiO2-Al2O3-MgO-FeO) Ag|Fe. The influences of slag compositions and basicity on FeO activities were analyzed. The results reveal that, for slags of fixed (?O)/(%SiO2) ratio, MgO and Al2O3 content, there was an increase of FeO activities with increase of FeO content. For slags with constant {(?O) (%MgO)}/(%SiO2) ratio, fixed FeO and Al,2O3 content, FeO activities decreased when MgO content increased from 5% to 10%, and increased with the increase of MgO content when it was over 10%. The FeO activities increased when (?O)/(%SiO2) ratio changed from 1.03 to 1.30 in the slags of constant MgO, FeO and Al2O3 content.
Keywords:CaO-SiO2-Al2O3-MgO-FeO slags  FeO activities  solid electrolyte cell  basicity  MgO content
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