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Extending previous investigations by Loeb of mobilities in gaseous mixtures using his procedure except that the auxiliary field in these measurements was made equal to the advancing field thus giving absolute values of the mobilities, measurements of mobilities were made in mixtures of CH3NO2H2 and CH3CNH2. The mobilities in H2 were 7.12 for the positive ions and 10.46 for the negative ions in cm./sec. per volt/cm. Those in CH3NO2 were 0.221 cm./sec. per volt/cm. for both ions and in CH3CN they were 0.234 cm./sec. per volt/cm. for both ions. Both ion mobilities deviated from Blanc's law in CH3NO2 indicating the formation of complexes with the CH3NO2 ions somewhat greater in size than the normal ions in H2. The molecules attached to negative ions somewhat less readily than to the positive ions but both final ions were of the same size. In CH3CN mixtures both positive and negative ions deviated from Blanc's law, the positive ion showing more ready attachment of CH3CN. The negative ion had consistently a higher mobility than the positive ion, a circumstance indicating a smaller ion and suggesting that the attaching molecule might not be CH3CN but some impurity. Both ion addition products in CH3CN are larger than the normal ion in H2 but smaller than those in CH3NO2 as was to be expected. 相似文献
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本文介绍了采用高能球磨法制备出纳米CeO2/Zn、纳米CeO2/A1复合粉末,用粉末冶金真空热压烧结制备出纳米CeO2/Zn、纳米CeO2/Ai复合材料块体的方法. 相似文献
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本文采用高温熔融法制备了SiO2-Bi2O3-Sb2O3-Er2O3玻璃。测量和研究了样品的吸收光谱和发射光谱。结果表明,Ω2的值和1.5μm附近的发射带宽均随着Er3+浓度的升高而增大。 相似文献
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本文考察了添加不同助剂对Ni/Al2O3催化剂对乙醇水蒸气重整反应性能的影响,结果表明,添加K助剂可以改进催化剂活性并提高了反应稳定性。 相似文献
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首先,把K2(Z[(Cp)2×Cpn])p-秩的计算约化为对特定正合列的估计,然后,给出SK(ZG,p ZG)元素个数的一个上界;最后,得到K2(Z[(Cp)21×Cpn])p-秩的一个下界. 相似文献
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Yuxiang Shen Tianfu Liu Rongtan Li Houfu Lv Na Ta Xiaomin Zhang Yuefeng Song Qingxue Liu Weicheng Feng Guoxiong Wang Xinhe Bao 《国家科学评论(英文版)》2023,(9):37-45
Solid oxide electrolysis cells provide a practical solution for the direct conversion of CO2 to other chemicals(i.e.CO),however,an in-depth mechanistic understanding of the dynamic reconstruction of active sites for perovskite cathodes during CO2 electrolysis remains a great challenge.Herein,we identify that iridium-doped Sr2Fe1.45Ir0.05Mo0.5O6-δ(SFIrM) perovskite displays a dynamic electrochemical reconstruction feature during CO... 相似文献
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我国作为碳排放大国,面临着碳达峰、碳中和(以下简称“双碳”)目标任务和国际碳减排压力。因此,准确的碳排放数据对于评估“双碳”目标和国际履约非常重要。联合国政府间气候变化专门委员会(IPCC)报告推荐将二氧化碳(CO2)观测与大气反演结合来“自上而下”地校验“自下而上”的碳排放清单,并指出加入大气14CO2观测可以更准确地校验碳排放清单。放射性碳同位素( 14C)是化石源CO2最准确的示踪剂,已被国际社会广泛推荐用于碳排放评估。文章基于大气14CO2观测的国际发展趋势和国内的紧迫状况,建议加大支持力度,建立大气14CO2观测网络;开展培训,统一相关标准,积极参与国际交流;尽快开展14CO2观测与大气反演相结合的研究。以此使我国的碳排放研究水平与国际接轨,并提高碳排放数据的可靠性,进而服务国家的“双碳”目标和气候外交谈判。 相似文献
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针对一起220kV变压器在安装过程中及投运后非故障原因造成油中反复出现C2H2的案例分析,提出处理建议和防范措施。 相似文献
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纳米TiO2对染料敏化纳米薄膜 总被引:5,自引:0,他引:5
《中国科学院研究生院学报》2001,18(1):28-30
在染料敏化纳米薄膜太阳电池中,纳米TiO2是重要的组成物质之一.用溶胶-凝胶法制备纳米TiO2的过程中,为了控制纳米TiO2的大小及晶型采用了一系列方法.主要介绍热处理方法及实验结果.随着热处理温度的升高,纳米TiO2的晶粒度随着长大.而且当水解pH~
1,热处理温度达到270℃时就已经有43%的金红石相纳米TiO2出现.通过计算发现,其中金红石相纳米TiO2比锐钛矿相纳米TiO2的晶粒度大得多.将制备的纳米TiO2应用于染料电池,通过太阳电池的测试实验证实,合适的热处理温度可得到较好的光电转换效率. 相似文献
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以含钠质量百分比高达2.5%~3%的Al(OH)3为原料,通过添加除钠剂进行除钠,并结合氢氧化铝的差热-热重曲线,根据氧化铝相变机理来确定合理的烧结制度,同时研究了α-Al2O3晶种以及降温催化剂在氢氧化铝烧结过程中促进氧化铝相变、降低α-Al2O3的相变温度的幅度及其机理。 相似文献