共查询到20条相似文献，搜索用时 187 毫秒
1.
Xia Fengshun Li Wenpeng Guo Junheng Han You Zhang Minqing Wang Baoguo Li Wei Zhang Jinli 《天津大学学报(英文版)》2021,27(5):409-421
A pore-array intensified tube-in-tube microchannel (PA-TMC), which is characterized by high throughput and low pressure drop, was developed as a gas–liquid contactor. The sulfite oxidation method was used to determine the oxygen efficiency (φ) and volumetric mass transfer coefficient (kLa) of PA-TMC, and the mass transfer amount per unit energy (ε) was calculated by using the pressure drop. The effects of structural and operating parameters were investigated systematically, and the two-phase flow behavior was monitored by using a charge-coupled device imaging system. The results indicated that the gas absorption efficiency and mass transfer performance of the PA-TMC were improved with increasing pore number, flow rate, and number of helical coil turns and decreasing pore size, row number, annular size, annular length, and surface tension. The φ, ε and kLa of PA-TMC could reach 31.3%, 1.73 × 10−4 mol/J, and 7.0 s−1, respectively. The Sherwood number was correlated with the investigated parameters to guide the design of PA-TMC in gas absorption and mass transfer processes.
相似文献2.
The extractive reaction process of oxygen-working solution-water three-phase system for the production of hydrogen peroxide by the anthraquinone method was investigated in a sieve plate column of 50 mm in internal diameter. The oxidation reaction of anthrahydroquinone in the working solution with oxygen and the extraction of hydrogen peroxide from the working solution into aqueous phase occurred simultaneously in the countercurrent mode. The agitating effect caused by gaseous phase made the droplets of the dispersed phase become smaller, thus, increasing the liquid-liquid interfacial contact areas and resulting in the improvement of the mass transfer velocity. Results showed that the gas-agitation had a beneficial effect on the extraction of hydrogen peroxide from the working solution into the aqueous phase： the concentration of hydrogen peroxide in the raffinate decreased with the increase of the gaseous superficial velocities： and the concentration of H2O2 in the raffinate increased with the increase of the dispersed phase superficial velocity at the same superficial velocity of the gaseous phase. In the G-L-L extractive reaction process, with the increase of the gaseous superficial velocities, both the conversion of the anthrahydroquinone oxidation and the extraction efficiency of hydrogen peroxide first increased significantly, then increased gradually. 相似文献
3.
To understand the absorption mechanism of nitrogen dioxide into a sodium sulfide solution, a stirred tank reactor with a plane gas-liquid interface was used to measure the chemical absorption rate of diluted nitrogen dioxide into sodium sulfide solution. The absorption rates under various experimental conditions were measured and the effects of experimental conditions on nitrogen dioxide absorption rate were discussed. The results show that, in the range of this study, nitrogen dioxide absorption rate increases with increasing sodium sulfide concentration, nitrogen dioxide inlet concentration, and flue gas flow rate, but decreases with increasing reaction temperature and oxygen content in flue gas. 相似文献
4.
Xue-cheng Wu Qin-hui Wang Chen Tian Zhong-yang Luo Meng-xiang Fang Ke-fa Cen 《浙江大学学报(A卷英文版)》2008,9(7):922-931
Particle rotation plays an important role in gas-solid flows. This paper presents an experimental investigation on the spatial distribution of average rotation speed for glass beads in the upper dilute zone of a cold circulating fluidized bed （CFB） riser. It is shown that in the horizontal direction, the average rotation speed in the near-wall area is larger than that in the center area, while in the vertical direction, it decreases as the height increases. The reason resulting in this distribution is analyzed by considering several factors including particle size, particle shape, particle number density, particle collision behavior, and the surrounding flow field, etc. The effects of CFB operation conditions on the spatial distribution of average rotation speed are also studied. The results show that the increasing superficial gas velocity increases the average rotation speed of particles in the near wall area but takes nearly no effect on that in the center area. The external solids mass flux, however, takes the opposite effect. It is found that the average rotation speeds of particles in both areas are increased as the total amount of bed material increases. 相似文献
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Absorption of NO2 into Na2S solution in a stirred tank reactor 总被引：1，自引：1，他引：0
To understand the absorption mechanism of nitrogen dioxide into a sodium sulfide solution, a stirred tank reactor with a plane gas-liquid interface was used to measure the chemical absorption rate of diluted nitrogen dioxide into sodium sulfide solution. The absorption rates under various experimental conditions were measured and the effects of experimental conditions on nitrogen dioxide absorption rate were discussed. The results show that, in the range of this study, nitrogen dioxide absorption rate increases with increasing sodium sulfide concentration, nitrogen dioxide inlet concentration, and flue gas flow rate, but decreases with increasing reaction temperature and oxygen content in flue gas. 相似文献
7.
3D couette flow of dusty fluid with transpiration cooling 总被引：1，自引：0，他引：1
GOVINDARAJAN A RAMAMURTHY V SUNDARAMMAL K 《浙江大学学报(A卷英文版)》2007,8(2):313-322
INTRODUCTION Transpiration cooling is a very effective process to protect certain structural elements like combustion chamber walls, exhaust nozzles, or gas turbine blades in turbojet and rocket engines, from the influence of hot gases. In view of this, Eckert (1958) obtained an exact solution of the plane couette flow with transpi-ration cooling. The problem remained 2D due to the uniform injection and suction applied at the porous plates. Flow and heat transfer along a plane wall with… 相似文献
8.
Chemical absorption of CO2 into aqueous slurries of Ca(OH)2 was studied in a stirred thermostatic reactor. The influence of solid loading and stirring speed on absorption rate were investigated experimentally, and the results show that the enhancement factor increases with particle content due to the increase of reactive particles in the gas-liquid interfacial region. The absorption process was controlled by the diffusion of gas molecules in slurry. The influence of stirring intensity on enhancement factor is an integration of gas-liquid and liquid-solid mass transfer variation. A novel prediction model of enhancement factors was proposed with the partition of interface into two various zones, and the prediction values by the presented model are in agreement with the experimental data. 相似文献
9.
CHERALATHAN M VELRAJ R. RENGANARAYANAN S. 《浙江大学学报(A卷英文版)》2006,7(11):1886-1895
INTRODUCTION Cool thermal energy storage (CTES) using the latent heat concept as an alternative to sensible heat storage offers a good option because of its high storage density and the nearly constant temperature heat removal characteristics during the discharging cycle. Since the principle of latent cool storage nec- essarily involves a change of state, heat transfer must occur in different modes depending on the state of charging and discharging. During the periods of low cooling dema… 相似文献
10.
Based on a three-step kinetic mechanism, a one-dimensional, time dependent, numerical model is presented forthe smoldering propagation in a horizontally packed bed of cellulosic material. The kinetic processes include pyrolysis andoxidation degradation of fuel and oxidation of char. Heat transfer between solid and gas is taken into account, and the diffusioncoefficient varies with the temperature. Radiative heat transfer is included by using the diffusion approximation. The effectsof airflow velocity and oxygen concentration are simulated on the smoldering velocity and the averaged maximum temperatureof smoldering fuel. The results indicate that the spread rate varies linearly with increasing airflow velocity, and the inlet airvelocity has little effect on the maximum temperature. The evolutions of gas species and solid compositions are predicted.The effects of frequency factors (A1, A2 and A3) are analyzed. Simulations show that the smoldering spread rate increaseswith increasing A2 (fuel oxidation), but decreases with A1 (fuel pyrolysis) and A3 (char oxidation). 相似文献
11.
INTRODUCTION Cross flow and heat transfer were widely found in oil production and chemical facilities.A detailed study of the hydrodynamic characteristics and heat transfer of cross flow is necessary for optimal design of the system and the development of new measuring techniques.Studies on the heat transfer in sin-gle-phase liquid cross flow were carried out in the past decades.Air or water was often chosen as the working fluid,in these studies commonly focused on fluids flowing across r… 相似文献
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Numerical study of heat transfer characteristics of downward supercritical kerosene flow inside circular tubes 总被引：3，自引：0，他引：3
The heat transfer characteristics of China RP-3 aviation kerosene flowing in a vertical downward tube with an inner diameter of 4 mm under supercritical pressures are numerically studied. A ten-species surrogate model is used to calculate the thermophysical properties of kerosene and the re-normalization group (RNG) k-ε turbulent model with the enhanced wall treatment is adopted to consider the turbulent effect. The effects of mass flow rate, wall heat flux, inlet temperature, and pressure on heat transfer are investigated. The numerical results show that three types of heat transfer deterioration exist for the aviation kerosene flow. The first type of deterioration occurred at the tube inlet region and is caused by the development of the thermal boundary layer, while the other two types are observed when the inner wall temperature or the bulk fuel temperature approaches the pseudo-critical temperature. The heat transfer coefficient increases with the increasing mass flow rate and the decreasing wall heat flux, while the inlet bulk fluid temperature only influences the starting point of the heat transfer coefficient curve plotted against the bulk fluid temperature. The increase of inlet pressure can effectively eliminate the deterioration due to the small variations of properties near the pseudo-critical point at relatively high pressure. The numerical heat transfer coefficients fit well with the empirical correlations, especially at higher pressures (about 5 MPa). 相似文献
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将热管系统的蒸发器作为连铸结晶器,通过测试蒸发室及熔融室内的温度,揭示热管运行温度和熔融室温度的关系。结果表明：在普通环境温度下和物质熔融温度为160℃时．热管工作温度为50-70℃,热管系统蒸发器面积和冷凝器面积之比从1：15增加到1：30时。热管工作温度降低较快,下降约23％;当面积比从1：30增加到1：60时,下降约8％：将热管系统运用于连铸生产时．增大热管系统的冷凝器面积,可以降低热管工作温度。但降低程度随面积比的增大而减小;当用于镁合金连铸时,热管的运行温度将超过100℃． 相似文献
14.
对顶喷流化床中的颗粒干燥过程进行模拟.引进润湿率参数表示喷雾液滴对流化颗粒的有限润湿,并利用聚丙烯和水物系的实验数据回归得到了该物系的润湿率表达式.通过得到的润湿率对顶喷流态化过程进行模拟,模拟结果与实验结果基本一致,润湿率及过程模型得到了验证. 相似文献
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建立了模拟逆流降膜除湿过程传热传质的数学模型,给出了传热传质的控制方程和适当的边界条件和气液界面条件.采用氯化钙作为除湿剂,运用控制容积法对降膜除湿溶液与被处理空气之间的除湿过程进行了分析和计算.获得了相应的除湿溶液与被处理空气的速度场、温度分布和出口参数.计算结果表明:沿着除湿器高度方向溶液和空气的温度、溶液的浓度、空气的湿度在入口区域变化较快而在出口区域变化较慢.可分别通过增加竖壁的高度、溶液的入口浓度和溶液的流速来改善除湿过程;同样,也可通过降低空气的流速或空气入口湿度达到改善除湿过程的目的.研究结果有利于改进除湿器的性能,为太阳能液体除湿、空调系统的优化设计和运行调节提供了理论依据. 相似文献
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为了探索油气在冷凝回收过程中的冷凝规律,采用气液两相流模型描述了油气在竖直管内湍流流动时的冷凝过程.采用有效传质系数描述了油气组分的质量传递.模拟了油气在管内冷凝时的温度、管内压力、液膜厚度和Nusselt数的变化,得到了入口油气和管壁的温差、雷诺数对冷凝率和Nusselt数的影响.结果显示：增大入口雷诺数能显著增强传热和冷凝,但是增大入口油气和管壁的温差对冷凝率的影响较小;另外,还发现传质阻力对油气冷凝率有较大影响.此模型的计算结果与先前的实验数据能够很好地符合. 相似文献
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SRITHAR K. MANI A 《浙江大学学报(A卷英文版)》2006,7(11):1870-1877
INTRODUCTION The tannery effluent (soak liquor) spewed out by tanneries to the surroundings has been polluting the land and water bodies in and around the tanneries and is evaporated over a period of time. The rate of evaporation over this period is small in the natural evaporative ponds and so large area is required. But land in urban and semi-urban sectors is scarce and very costly. Hence, it is required to augment the evaporation rate by adopting some suitable techniques. The rate of e… 相似文献
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在气体样品池条件下,用调频半导体激光器激发Rb原子至Rb（sPj）态,通过测量样品池前后光强比,得到不同温度下样品的吸收系数。对于Rb（5S1/2→5Pj）的跃迁,可获得g2／g1值和5Pj的寿命值（我们取j=1／2,即用D1线794nm计算）,从而得出不同温度下样品的基态原子密度．实验结果表明：基态原子的密度N随着温度的升高而增大．通过与其它实验结果进行比较,得出在低温下的数据比较准确,可见利用光学吸收方法测量低激发态原子密度较为理想． 相似文献
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Marangoni effectis of interestto the chemical en-gineers from both scientific and practical points ofview[1—6]. The Marangoni convection contributes tothe renewal of the interfacial surface and is capable ofincreasing the mass transfer rate, resulting in intensi-fication of separation processes such as distillation,extraction, absorption, and desorption. The theoretical studies of Marangoni instability inthe past were focused on determining the critical tran-sition point. The critical condit… 相似文献
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This study deals with the effect of hydrotropes on the solubility and mass transfer coefficient of salicylic acid. The solubility and mass transfer studies were performed using the hydrotropes, i.e., sodium acetate, sodium salicylate, citric acid, and urea at concentrations of 0-3.0 mol/L and system temperatures of 303-333 K. It was found that the solubility and mass transfer coefficient of salicylic acid increases with increase in hydrotrope concentration and also with system temperature. All hydrotropes used in this work showed an enhancement in solubility and mass transfer coefficient to different degrees. The maximum enhancement factor values were determined for all hydrotropes used in this study. The highest value was 28.08 for solubility studies and 10.42 for mass transfer studies. The performance of hydrotropes was measured in terms of the Setschenow constant （Ks）. The highest value observed was 0.696. 相似文献