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1.
在新参量S、H正方形核素图中,稳定区奇A核素的上界表现出优美的三点共线对称组.文中说明了坐标差K(=S-H)=0,K,2K类奇A上界表现出的三点共线对称规律.当差△K=3时,这些三点共线对称组序数组成为(0,1,2),(0,4,8),(0,7,14),(0,10,20)与(0,-2,-4).又组成以序数K=1,4,7,10K=2,8,14,20与K=1,2;K=-2,-4的两组平行线,以此线性规律为基础,可外推得到两种核素 87 40 33 Zr47 7,与225 84 37 PO131 47,这两核素有可能微量天然存在,应该与平行线上的其它核素具有相似的核基本性质.  相似文献   

2.
分子印记     
分子印记技术是近年来基于分子识别理论而迅速发展起来的一个新的研究领域,它可以为人们提供具有期望结构和性质的分子组合体,是当今超分子化学研究的最前沿课题之一。它是指制备对特定分子(模板分子)具有高选择性及识别能力的聚合物的过程,通常可描述为制备识别“分子钥匙”的“人工锁”的技术,即当体系中存在着模板分子时,功能单体可以通过聚合使这些模板分子以互补的形式固定下来。  相似文献   

3.
中国传统经典小说中叙事到明清时代,以几部重要的经典小说而完成小说叙事模式建构,即单体叙事结构、连缀叙事结构和网状叙事结构。单体叙事结构是以几个主要人物贯串故事始终,各阶段的故事在时间上有前后因果关系。连缀叙事结构表现为由几个角色贯连形成一个文本主旨统领的集合连缀叙事结构,在叙事上这两种叙事结构,尤其是在人物塑造上形成某种独到的叙事魅力。本文以"三国"和"水浒"为范本对这种叙事结构的叙事奥妙作点文本细读论析。  相似文献   

4.
以4-氨基安替比林为模板分子,甲基丙烯酸为功能单体,十二醇/甲苯为溶剂,采用沉淀聚合法制备了对模板分子具有特异吸附的分子印迹聚合物,考察了制备条件,如溶剂用量、功能单体浓度和交联剂浓度对聚合物吸附性能的影响.静态吸附实验结果表明,在模板分子与功能单体、交联剂摩尔比为1:5:20的条件下,可制备出吸附量大且特异性识别能力较佳的分子印迹聚合物,对4-氨基安替比林及其结构类似物安替比林的分离因子为3.72.  相似文献   

5.
基于分子拓扑学理论,给出了一组可根据链烷烃名称极易获取的分子拓扑指数(N,Pi,Sj),并对链烷烃的色谱保留指数、标准生成焓、标准熵、标准生成自由能以及在200C时链烷烃的摩尔体积、蒸发热、摩尔折光率七种理化性质进行定量结构-相关性研究,得多元线性回归方程.研究结果表明,本文给出的拓扑指数简单易得,应用面广,与链烷烃具有优良的性质相关性和较高的结构选择性.  相似文献   

6.
以金石蚕苷为模板分子,丙烯酰胺、丙烯酸乙酯和丙烯酸三种物质分别作为功能单体,运用量子化学方法模拟模板分子与不同功能单体按不同比例结合的印迹聚合物预组装体系的构型、能量及复合反应的结合能△E.通过不同功能单体与模板分子在不同比例条件下形成印迹聚合物的识别性能研究,结果显示金石蚕苷和丙烯酰胺按1:7的分子比例的印迹效应最好.  相似文献   

7.
电荷传输是有机电子材料非常重要的性质.使用电荷传输的Marcus半经典模型和密度泛函理论(DFT)方法,在B3LYP/6-31G**水平上对四-辛烷氧基取代四苯基[a,c,h,j]蒽的分子结构、电子结构及电荷传输性质进行理论研究.计算结果表明,该分子的正电荷传输速率常数k+(1.42×1013s-1)比负电荷传输速率常数(5.83×1012s-1)大近1个数量级,与苯并菲和六氮杂苯并菲比较,该分子更有利于正电荷传输,预示可设计成正电荷传输材料.  相似文献   

8.
快速选择性检测硝基酚(PNP)、三硝基芴酮(TNF)、苦味酸(PA)等硝基芳环爆炸物已成为当前强缺电子体系硝基芳香族研究的热点之一.基于B3LYP/6-311+g(d, p)理论水平,对氮杂苯并菲基元取代的α-氰基二苯乙烯(TPN-Ar-DPA:a)探针分子及硝基芳环分子进行结构优化与频率计算;对稳定结构分别计算气态和四氢呋喃(C4H8O)溶剂中的电子吸收光谱及荧光光谱;计算探针分子与硝基芳环所形成二聚体分子的结合能;最后对二聚体分子进行了RDG分析.研究结果表明,探针分子中的苯并菲环与所有苯环不共面.与气相相比,在C4H8O溶剂中,a分子的吸收光谱有一定的红移,但荧光光谱却出现了的蓝移.探针分子与六个被检测物所形成的二聚体中,a-PNP、a-TNF及a-PA的结合能绝对值相对较大,表明a分子对硝基酚(PNP)、三硝基芴酮(TNF)、苦味酸(PA)等硝基芳香环检测物的选择性和灵敏度较好,可设计为PNP、TNF、PA的探针分子.探针分子对硝基芳环具有较好的选择性和灵敏度,主要源于二聚体分子间既存在范德...  相似文献   

9.
在化学键理论中 ,MO理论与 VB理论是描述分子中化学键的两大理论 ,这两种理论在解释分子结构及成键等性质方面各有所长 ,VB理论适合描述分子的静态性质如分子的结构、成键特性及键的形成和断裂行为等 ;而 MO理论则适合于处理基态、激发态分子的性质及阐明分子光谱、光电子能谱的性质。对这两个理论的异同点作一些初步分析 ,可以更好的学习和理解化学键理论。一、不同的数学物理思想MO理论研究的是分子中单电子的运动状态 ,选取分子轨道 (原子轨道的线性组合 )作为线性变分法的变分函数 ,占据在分子轨道上的电子的运动遍及整个分子空间 ,…  相似文献   

10.
为了增加学生对功能高分子材料的学习兴趣,让学生进一步了解材料结构与性能之间的关系,设计了以水解聚丙烯腈底膜为支撑层、甲苯-2,4-二异氰酸酯(TDI)与聚乙烯亚胺(PEI)为功能单体,采用层层界面聚合法制备聚脲型渗透汽化膜。基于渗透汽化膜的溶解扩散机理,通过改变油相单体TDI浓度,获得了具有阶梯交联度的新型结构,用于无水乙醇的有效制备。该实验涵盖膜材料的制备、结构表征及性能测试等多个知识点,有利于提高学生的综合能力和素质。  相似文献   

11.
《海外英语》2007,(5):44-45
It is worthy of noting that, whilst Crookston Castle witnessed the earlier and happier portion of Mary's variegated life,  相似文献   

12.
一、吃和喝吃苹果 eat an apple, 吃药 take medicine,吃糖 have some sweets,吃饭 have one's meals,吃馆子 dine out,吃惊 be surprised/  相似文献   

13.
《海外英语》2007,(5):10-11
Many college freshmen arrive woefully unprepared to do college work, and as disadvantaged populations continue to grow, the share of the American work force that has made it through college is expected to plummet. Many experts blame that educational failure not just on high schools but also on colleges. School & College, a special report by The Chronicle, looks at efforts to fix the system. What reforms would better prepare students for college? What should schools and colleges be doing differently? How should state and federal officials help?  相似文献   

14.
The communication of people partially is the communication of cultures. Culture has a direct effect on international commercial activities in all aspects. Different conceptions about time, space, equality, law and the like, lead people to deal with things in different ways. So to know cultures of the counterpart is to facil-itate our enterprises so as to have a smooth and successful communication in commercial activity.  相似文献   

15.
《海外英语》2007,(4):36
There are numbers of crossroads on our long and unpredictable life journey where we totally have no idea about which direction to choose. No matter what our decision is, we should not turn back, but face the music and go ahead instead. I am this kind of girl who always does try without regretting, one example is how I dealt with my love.  相似文献   

16.
王菲 《华章》2007,(12):273-273
Migration occurs behind a variety of reasons and has a great effect on the whole world. People may migrate in order to improve their economic situation, or in order to escape civil strife, persecution, and environmental disasters. The impact of migration is complex, bringing both benefits anddisadvantages. This paper briefly talks about the causes of migration, the allocation of benefits, and the ways in which individual countries and the international community deal with this important subject.  相似文献   

17.
风的曲线     
Rosco and I wait for the fishermen to return.I sit at a wooden bench near the store at Mt.Baker Resort and watch the clouds change shape. Rosco has my belt around his neck and an eight foot tow chain hooked to a tree. Dogs must be on a leash. Ducks and rabbits are loose.  相似文献   

18.
Given a graph G,a subgraph C is called a clique of G if C is a complete subgraph of G maximal under inclusion and |C|≥2. A clique-transversal set S of G is a set of vertices of G such that S meets all cliques of G. The clique-transversal number, denoted as TC (G), is the minimum cardinality of a clique-transversal set in G. The clique-graph of G, denoted as K (G), is the graph obtained by taking the cliques of G as vertices, and two vertices are adjacent if and only if the corresponding cliques in G have nonempty intersection. Let F be a class of graphs G such that F={G|K(G) is a tree}. In this paper the graphs in F having independent clique-transversal sets are shown and thus TC (G)/|G|≤1/2 for all G ∈ F.  相似文献   

19.
裴水妹 《华章》2007,(11):196
Sister Carrie is one of the most controversial characters in American literature.Thought as a "fallen woman" firstly,she was defined as a "new woman" by some critics later. However, by digging into the motivaton behind the whole process of Carrie's "success", the relationship between Carrie and her creator (the author), the social conditions of then American, it can be found that Carrie has never been free-standing on her thought and she has never found her real-sdf even after becoming a famous actress. In a society dominated by mass consumerism Carrie is only an adherent of her own desires. She also is a representative of all those country girls flooded into cities, a symbol and a sacrifice of the urbanization of America in a time countryside was overcome by cities.  相似文献   

20.
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