共查询到18条相似文献，搜索用时 682 毫秒
1.
Pan Chengcheng Song Yang Jin Weixian Qin Zhenbo Song Shizhe Hu Wenbin Xia Da-Hai 《天津大学学报(英文版)》2020,26(2):135-141
The purpose of this work was to enhance the corrosion resistance of the passive film on 304 stainless steel(SS) by chemical modification in alkaline phosphate–molybdate solutions. The 304 SS was passivated in both phosphate and phosphate–molybdate mixed solutions to investigate the effect of molybdate on its corrosion resistance. The experimental results indicated that the passive film showed better corrosion resistance in Cl--containing solutions after modification in phosphate–molybdate solutions than in phosphate-only solutions. Energy-dispersive spectroscopy analyses revealed that the passive film formed in phosphate–molybdate solutions contained Mo and P after modification, which is the reason for the enhanced corrosion resistance. 相似文献
2.
RAHMAN M. M. ARIFFIN A. K. 《浙江大学学报(A卷英文版)》2006,7(3):352-360
INTRODUCTION Due to market pressures for improvements in productivity, reliability, ductility, wear resistance and profitability of mechanical systems, manufacturers are placing increasing demands on available materials.Economic constraints require that these materials are inexpensive and easily available. In order to enhance the surface properties of today’s materials, producers of components are turning to different surface finish and treatments. There are several techniques available … 相似文献
3.
In this paper the tensile properties of both ordered and disordered Ni-24Fe and Ni-24Fe-0.03%B （wt%） alloys in gaseous hydrogen was investigated. The result shows that the ductility of the disordered Ni3Fe is significantly larger than that of ordered material in gaseous hydrogen. However, the ductility of ordered Ni3Fe doped with 0.03%B is nearly the same as that of disordered one indicating the obvious suppressing effect of boron on the H2-induced embrittlement. Based on the segregation behavior of boron in Ni3A1, it is proposed that the suppressing effect of boron in Ni3Fe on the H2-induced embrittlement is attributed to the segregation of boron on grain boundaries, thereby reducing the hydrogen diffusivity along the grain boundaries. 相似文献
4.
硼对金属间化合物Ni_3Fe氢气诱发环境氢脆的影响(英文) 总被引：1，自引：0，他引：1
In this paper the tensile properties of both ordered and disordered Ni-24Fe and Ni-24Fe-0.03%B(wt%)alloys in gaseous hydrogen was investigated.The result shows that the ductility of the disordered Ni_3Fe is significantly larger than that of ordered material in gaseous hydrogen.However,the ductility of ordered Ni3Fe doped with 0.03%B is nearly the same as that of disordered one indicating the obvious suppressing effect of boron on the H_2-induced embrittlement.Based on the segregation behavior of boron in Ni_3Al,it is proposed that the suppressing effect of boron in Ni_3Fe on the H_2-induced embrittlement is attributed to the segregation of boron on grain boundaries,thereby reducing the hydrogen diffusivity along the grain boundaries. 相似文献
5.
AWAD Samir Hamid 《重庆大学学报(英文版)》2005,4(1)
1 Introduction Weight saving materials such as aluminum and its alloys are becoming increasingly important and have been attracting increasing attention over the past decade, specially in the automotive, aerospace and chemical industries, and electrical devices because of their high strength-to-weight ratio, high electrical and thermal conductivities, processability and recyclability and good resistance to degradation in some corrosive environments [1,2]. In the automotive industry, there is d… 相似文献
6.
汪凌云 《重庆大学学报(英文版)》2002,(2)
Magnesium and magnesium alloys, which have a density of 1.74 g cm-3, are the lightest structural metal. In addition to being extremely light, magnesium alloys have many advantages such as high specific strength and high specific rigidity [1-3]. Magnesium alloys have been paid more and more attention in recent years. A few die castings of magnesium alloys have been applied to automobile industry. Magnesium alloys have huge potentiality of application to automobile, motorcycle, aviation, spacefl… 相似文献
7.
The various stages and progress in the development of interconnect materials for solid oxide fuel cells (SOFCs) over the last two decades are reviewed. The criteria for the application of materials as interconnects are highlighted. Interconnects based on lanthanum chromite ceramics demonstrate many inherent drawbacks and therefore are only useful for SOFCs operating around 1000℃. The advance in the research of anode-supported flat SOFCs facilitates the replacement of ceramic interconnects with metallic ones due to their significantly lowered working temperature. Besides, interconnects made of metals or alloys offer many advantages as compared to their ceramic counterpart. The oxidation response and thermal expansion behaviors of various prospective metallic interconnects are examined and evaluated. The minimization of contact resistance to achieve desired and reliable stack performance during their projected lifetime still remains a highly challenging issue with metallic interconnects. Inexpensive coati 相似文献
8.
To evaluate the respouses of fixed and pinned pile groups under torsiun, a method is presented to analyze the nonlinear behavior of free-standing pile groups with rigid pile caps. The method is capable of simulating the nonlinear soil response in the near field usingp-y and τ-θ curves, the far-field interactions through Mindlin's and Randolph's elastic solutions, and the coupling effect of lateral resistance on torsional resistance of the individual piles using an empirical factor. Based on comparisons of the solutions for fixedand pinned-head, 1×2, 2×2, and 3×3 pile groups subjected to torsion, it was found that pile-cap connection significantly influences the torsional capacity of pile groups and the assignment of applied torques in the pile groups. In this study, the applied torques for the pinned-head pile groups are only 44%～64% of those for the corresponding fixed-head pile groups at a twist angle of 2°. Such a difference is mainly due to the change of the lateral resistances of individual piles in the groups. 相似文献
9.
1 Introduction Cavitation phenomenon,i.e.,the sudden forma-tion of void , has been observed in a wide variety ofmetals and alloys[1].It has also been observed in rub-ber[2]and elastomers[3].As cavitation phenomenon re-lates to the mechanism of local failu… 相似文献
10.
It‘s importat that HTS tapes have lower thermal conductivity and higher transversal resistivity in order to reduce the heat leaks conducted along the tapes and AC losses in the high temperature superconducting system conduction-cooled by GM coolers,This paper presents an experimental investigation into the effects of pure Ag and AgAu alloys sheath materials on the properties of Bi(2223) multifilamentary tapes and the optimisation of conduction-cooled hybrid current leads made from copper and Bi(2223)/Ag or Bi(2223/)AgAu tapes,The thermal conductivity of the tapes were measured by cryogenic steady healt flux method and the resistance was measured by using standard DC four-probe method at lo temperature,The results showed that the reduction of thermal conductivity by the addition of Au into the sheath material of Bi(2223) tapes was 65%,75% and 85% lower than that of pure Ag sheathed Bi(2223) tapes and the increase of resistivity was 4.9,10 and 19.4 times higher than that of pure Ag for the addition of 2.2%,5.7% and 10.7% Au(atom ratio )respectively.And the study also attempts to optimise thermodynamically the conduction-cooled hybrid current lead by using a devel-oped model ,which took the irrevesibility of commercial GM coolers,the contact resistance and thermal conductance into account,Predictions from the model showed that AgAu alloys were suitable candiate materials to replace Ag as sheath material of Bi(2223) tapes applied in THS current leads,In addition,Bi(2223)/AgAu was a suitable material to be applied as the THS section of hybrid current leads in conduction-coled superconducting electric systems. 相似文献
11.
The fracture behavior of disordered and ordered Ni4Mo alloy was investigated by tensile tests in hydrogen gas or during hydrogen charging. The results show that the ductility of the disordered alloy decreased slightly with the hydrogen pressure increasing, while that of the ordered alloy decreased rapidly with the hydrogen pressure increasing. However, the ductility of both disordered and ordered alloys reduced similarly seriously with the charging current density increasing. Therefore, the mechanism of order-induced embrittlement of Ni4 Mo alloy in hydrogen gas is supposed to be that atomic order accelerates the kinetics of the catalytic reaction for the dissociation of molecular H2 into atomic H. 相似文献
12.
The mechanism involving the effect of disorder/order transformation on the environmental embrittlement in gaseous H2 is summarized. It is shown that there is no hydrogen embrittlement in disordered state of Kurnakov type intermetallics in gaseous H2. However, the H2-induced environmental embrittlement for the ordered alloy having identical chemical composition becomes severer as the degree of the order increases. The results of testing on the ion gage turned on and off during tensile testing show that the more sensitive to H2-induced hydrogen embrittlement for ordered alloy than disordered one is attributed to the fact that atomic ordering may accelerate the kinetics of the catalytic reaction to produce more atomic hydrogen. The results on simultaneous hydrogen charging show that disordered alloys embrittled as hydrogen atoms are forced into the material implying that the embrittlement of ordered alloy in gaseous H2 is also due to the acceleration of the kinetics of catalytic reaction. The above suggestion was further verified by the adsorption tests of Ni3Fe intermetallics powder. It is shown that the amount of chemically adsorbed hydrogen in ordered state is significantly larger than that adsorbed by the disordered alloy, indicating that the more sensitive to H2-induced embrittlement in the ordered state of alloy is essentially due to the accelerated catalytic reaction. 相似文献
13.
The process of gaseous hydrogen charging into a Ti3Al-based alloy in the temperature range of 500–650°C is investigated. The results showe that the relationship between the
average hydrogen concentration at constant temperature and charging time reveals a parabolic rate law. Applying the theory
of lattice diffusion to analyze the hydrogen diffusion in the alloy, we find that the apparent activation energy of hydrogen
diffusion is 90.40 kJ/mol, and the equilibrium hydrogen content in the alloy depends on the temperature of the gaseous hydrogen
charging process.
Project supported by the Natural Science Foundation of Shanghai (93QE14002) 相似文献
14.
孙龙 《实验室研究与探索》2005,24(8):19-20
介绍了用于压力测量的新型bridgman装置，并结合X射线衍射分析技术（XRD）研究了常压、高压条件下Zr41．2Ti13．8Cu12．5Ni10Be22．5块体非晶合金的晶化。结果表明，在相同的退火条件下（400℃，退火3小时），增大压力有利于Zr41．2Ti13．8Cu12．5Ni10Be22．5块体非晶合金的晶化；压力越大获得晶化相的晶粒尺寸越大。 相似文献
15.
Ultra-high vacuum gaseous hydrogen permeation experiments on Fe3Al-based alloy were performed in the temperature range of 330∼450°C with an upstream hydrogen pressure between 3. 38×104 Pa and 7.28×104 Pa. The results show that the hydrogen diffusivity and permeability in Fe3Al-based alloy obey Arrhenius relationship in the experimental temperature range and the hydrogen permeation process is controlled
by the lattice diffusion of hydrogen at relative high temperature. The activation energy of hydrogen diffusion in the Fe3Al-based alloy was found to be 75 kJ/mol.
Supported by the National Natural Science Foundation of China (59895157) 相似文献
16.
1 Ｉｎｔｒｏｄｕｃｔｉｏｎ ＩｒｏｎａｌｕｍｉｎｉｄｅｓｂａｓｅｄｏｎＦｅ3 Ａｌｈａｖｅｍａｎｙａｄｖａｎｔａｇｅｓｆｏｒｓｔｒｕｃｔｕｒａｌｕｓｅｓａｔｅｌｅｖａｔｅｄｔｅｍｐｅｒａｔｕｒｅｂｅｃａｕｓｅｏｆｔｈｅｉｒｅｘｃｅｌｌｅｎｔｃｏｒｒｏｓｉｏｎｒｅｓｉｓｔａｎｃｅａｎｄｒｅｌａｔｉｖｅｌｙｌｏｗｍａｔｅｒｉａｌｃｏｓｔ.Ｈｏｗｅｖｅｒ,ｔｈｅｓｅａｌｌｏｙｓｈａｖｅｎｏｔｙｅｔｆｏｕｎｄｗｉｄｅｓｐｒｅａｄｕｓｅｂｅｃａｕｓｅｔｈｅｙｅｘｈｉｂｉｔｐｏｏｒｄｕｃｔｉｌｉｔｙａｎｄｂｒ… 相似文献
17.
金属La部分取代M l(混合稀土)的贮氢合金电极M l0.8La0.2N i4.0Mn0.4Co0.4A l0.1(A)容易活化,其充电效率、放电容量、快速放电能力以及荷电保持能力比电极M lN i4.0Mn0.4Co0.4A l0.1(B)分别提高5.5%、7.0%、4.0%和8.2%。电极A放电过电位比电极增大,且循环稳定性下降。 相似文献
18.
作为镍氢电池负极活性物质,储氢合金是影响电极电化学性能的主要因素,对储氢合金进行表面处理可有效提高镍氢电池电极的电化学性能。实验采用电化学方法对储氢合金表面进行镍磷合金修饰处理,通过扫描电镜(SEM)及EDX能谱对电极表面进行了表征分析,测定了处理前后镍氢电池在1.5C和2C下的大电流放电性能,通过交流阻抗和循环伏安曲线对处理后电极进行了评价。测试结果表明,通过电化学修饰镍磷合金,储氢合金电极的大电流放电性能有所提高,电化学阻抗减小,循环寿命增长,有效提高了镍氢电池的性能。 相似文献