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1.
Twenty lead finds, unearthed in Late Bronze–Early Iron Age levels at the Santa Barbara nuraghe situated at Bauladu in Sardinia (Italy), have been examined. Their chemical composition has been determined using the ICP-MS plasma-mass technique (Cu, Fe, As, Ag, Sn, Sb, Bi, Zn, Cs, Tl, Mo, Cd, In, Te, W, Th, U, Li, Se). Lead isotope ratios (208/206, 207/206, 206/204) have also been determined. The results are discussed in relation to the mineral source and some aspects of the metal extraction processes. The finds are composed of high purity lead obtained using a smelting at low temperature. Based on the isotope ratios it has been possible to establish that the metal originated from Sardinian ore deposits type.  相似文献   

2.
Two different analytical approaches have been taken into account to investigate the role of Si-rich phases in enhance hydraulic reactions of bedding mortar mixtures from San Lorenzo Church in Milan (Northern Italy) and from the Medicean Aqueduct in Pisa (Central Italy). In the first case, mortars show clear hydraulic type reactions in the form of coronal layers between the reacting additive and the binder mass. In the second one, the hydraulic reactions do not develop visible mineral phases and processes have been inferred from chemical, mineralogical analyses and mass balance calculation. The microstructural studies not always are sufficient to understand the complex dynamics of reaction attained during pre-industrial manufacturing processing of mortars and related binders. In fact, if the reacting raw materials are fine-grained and/or have remarkable chemical reactivity, no relicts are preserved by mortar microtextures.  相似文献   

3.
The Carrera del Darro is a street within the city of Granada, Spain, which is emblematic owing to the architectural value of its buildings, to its significance for the urban structure of the city and to the implications it has for the surroundings of the Alhambra. Our study concerns the chemical analysis of the mural paintings on four façades, corresponding to numbers 23, 25, 27 and 29 of the Carrera del Darro. From the analysis of the mortar, it may be concluded that the composition is very similar, though not identical, in the four paintings studied: a limestone mortar. Ochre, white, black and red were used for the decoration of the four façades; green pigment was also observed in the second decoration of no. 29. The results of the morphological examination and EDX microanalysis of the paint samples are shown. By means of the thermogravimetric analysis we established the existence of an organically derived compound. After the existence of an oleaginous binder had been discounted by gas chromatography/mass spectrometry (GC/MS) analysis, we continued with the extraction and determination of proteins by spectrophotometry analysis, detecting low levels of proteins in the paint on the four façades analysed. The study was completed by evaluating the influence on the deterioration of the paintings by the possible surface presence of salts (such as nitrates or chlorides) and organic compounds.  相似文献   

4.
From 18 archaeological sites of the Lagoon of Venice 75 bricks belonging to Roman and medieval building levels have been analysed. Chemical composition and geometric measures allow the characterization of a group of 24 Roman bricks of Imperial age. The group formed by means of fuzzy c-means cluster analysis applied on chemical data have been tested by principal component analysis and finally subjected to discriminant analysis to estimate the relative weights of original variables and classify new elements. Correlations among the data of the major chemical elements confirm the reliability of the complex of chemical data. The aim of this research was to obtain a chemical characterization of Roman bricks (and later, of the medieval ones) coming from the lagoon of Venice thus making it possible: 1) to recognize the age of a brick by means of its chemical analysis; 2) to date the layers of archaeological excavations or the ground where there are medieval building foundations by means of membership bricks; 3) to calculate the rate of local ground lowering in the elapsed years by the difference in level from one layer to another; 4) to estimate local rates of land subsidence by comparison with mean values already known.  相似文献   

5.
The protective performances of two new fluorinated acrylic copolymers (based on the monomers 1H,1H,2H,2H-perfluorodecyl methacrylate (XFDM) and 1,1,1,3,3,3-hexafluoroisopropyl methacrylate (HFIM) are evaluated and compared with Paraloid B72, a commercial copolymer ethyl methacrylate/methyl acrylate (EM/MA) and its partially fluorinated homologous 2,2,2-trifluoroethyl methacrylate/MA (TFEM/MA). The polymeric materials have been tested on Candoglia marble, a very low open porosity stone (<1%) used in Italian historical architecture (Milan Cathedral). The copolymers were tested according to UNI-Normal protocol. Measurements of capillary water absorption, static contact angles, colour variation and water vapour permeability were made before and after accelerated photo-ageing. FTIR spectroscopy and size exclusion chromatography (SEC) analyses were carried out on samples aged on inert substrate to assess the photostability of the copolymers themselves. The relationship between the protection efficacy and the fluorine content and distribution has been investigated. The results obtained show that the addition of a partially fluorinated co-monomer to the Paraloid B72 copolymer structure did not result in the expected improvement of the coating properties, while the fluorination of the copolymer side chain gave rise to encouraging performance.  相似文献   

6.
The oil painting “La Medusa” executed by Caravaggio at the end of the XVI century on a wooden shield, was investigated by integrated physical–chemical and analytical methodologies in order to obtain scientific data capable of elucidating the state of conservation and the painting technique. Optical (OM) and electronic (SEM-EDS) microscopy, micro-FT-IR spectroscopy, gas chromatography–mass spectrometry (GC–MS) and pyrolysis GC–MS were applied on two microfragments and some organic samples obtained by solvent extraction using the swab cleaning technique. The obtained results indicated that Caravaggio probably reused an old shield as a previous gypsum preparation layer has been detected under the original painting layers. He used white lead, natural earths, verdigris and lead–tin yellow type I mixed with drying oils to paint. The considerable amount of amorphous particles of copper chlorides found in the green pigment verdigris suggests that it could have been produced according to the ancient recipe of verde salsum described by Theophilus. Mordant gilding has been identified on the upper part of the shield that can be related to an abandoned experiment to give the painting a mirror-like reflecting effect. Three different varnishes layers have been detected above the painted surface. The original and restoration varnishes have been identified and they contain a mixture of drying oil, mastic and turpentine and some beeswax. Cleaning tests, performed with different organic solvents, suggest the use of isopropyl alcohol as cleaning agent because it is less efficient in comparison to others solvents; thus it ensures a careful and controlled removal of the varnishes.  相似文献   

7.
Using inductively coupled plasma–atomic emission spectrometry (ICP-AES), atomic absorption spectrometry (AAS) and instrumental neutron activation analysis (INAA) the concentration of Ag, As, Au, Bi, Cu, Fe, Ga, In, Ni, Sb, Sn, and Zn in 53 samples taken from archaeological finds dated to 4th–2nd century BC and found in the territory of ancient Thracia was determined. Additionally using inductively coupled plasma–mass spectrometry (ICP-MS) and MS for determination of the lead isotope ratios in the samples was carried out. On the basis of these analytical results using cluster analysis for grouping the samples on the bases of the similarity in chemical and isotopic content and the available data from the literature for lead ore deposits in the Balkan Peninsula, the geological origin of the investigated archaeological finds was evaluated. That confirms the expectation that sources of lead might be almost all possible deposits of lead ores on the Balkan Peninsula—from Lavrion through Chalkidiki to the Rhodope mountain. The result indicates that the Thrace did not utilize one single lead source continuously but that lead was provided according to availability from different production centers.  相似文献   

8.
For the last 60 years, varnishes of ancient musical instruments, particularly stringed instruments of the violin family dating 17th and 18th centuries, have been analysed to establish their chemical composition and multi-layered structure. The objective was to rediscover the technology for making the varnish of esteemed Italian violins and to reconstitute it. This paper reviews the physico-chemical studies published on such varnishes and also focuses on a research project carried out since 2002 at the Musée de la musique in Paris. It aims to apply in a comprehensive way different non-destructive or micro destructive methods (Py-GC/MS, IR microscopy, SEM/EDX, EDXRF, synchrotron radiation-based techniques, …) to the study of a large and representative number of ancient varnished musical instruments from a museum collection.  相似文献   

9.
For this critical intercultural inquiry, I as an Asian/Japanese transnational cisgendered gay man write my autoethnography of queer (or non-heteronormative) Asian–Black (dis)connections. Specifically, I challenge, interrogate, and problematize my queer intercultural production of desire and attraction as I engage in my critical autoethnographic interrogation of dialogues with five Asian/Japanese transnational gay men who have previously engaged in queer Asian–Black relationality. In so doing, I intend to create a potential point of departure to decenter the discursive and material effects of White gay normativity in the knowledge production of Asian queer male desire and attraction.  相似文献   

10.
The quality of a book reprint depends on several factors, e.g. paper, typesetting, reproduction of illustrations, printing and bookbinding. The quality of the 1958 and 1988 reprints of the fairytale edition from 1944 designed by the Slovenian architect Jo?e Ple?nik was studied using standard and other non-invasive testing methods, e.g. microscopic and spectroscopic techniques, sonic velocity, Young's modulus of elasticity, surface topography and image analysis. The chemical, physical and colorimetric properties of papers and typographic tonal density were analysed. The results showed that the reprints do not correspond to the originals. Some of the differences in the reprints, if compared with the original (e.g. typographic tonal density), could have been easily avoided, while others (e.g. structural and optical properties of paper) remain unavoidable, mainly due to the influence of internal and external factors on the ageing. The ageing process influences paper properties, since optical properties deteriorate in time. It has been concluded that a precise and systematic study of the properties of an old book should be performed before the preparation of a reprint. The results of the research have shown that the applied methods are useful and satisfactory for the characterisation of the paper properties and typography, and can be of use at the analysis of printing ink and illustration reproduction.  相似文献   

11.
The protection against graffiti has become a serious problem in most cities. Unfortunately such form of vandalism does not save the cultural heritage. The use of anti-graffiti coatings is a common treatment that can also temporary protect the surface from degradation due to interactions with the environment. Aspects that have not yet been sufficiently investigated from a metal artefact perspective are whether the presence of the anti-graffiti coating will influence the patina composition and reduce the degree of patina dissolution. Long-term (four years) effects of wax-based anti-graffiti coatings on bare copper sheet and pre-patinated copper exposed to urban atmospheric conditions are presented and discussed in terms of changes in patina dissolution rates, barrier properties and composition. The investigation is based on a multi-analytical approach combining chemical analysis, analytical and electrochemical tools (stereomicroscopy, FTIR, XRD, SEM/EDS, AAS, EIS, colorimetric measurements). Results are believed to provide important information related to the long-term applicability of such coatings to preserve the Cultural Heritage.  相似文献   

12.
Transylvanian glass icons are very specific heritage items of Romanian folk art, produced from the middle of 18th century until now. The present research reports the results of a study on the organic components of the paint layers, analyzing the binding media of a series of glass icons belonging to three important icon making centers: Nicula, Olt County (?ara Oltului) and Brasov area (?cheii Bra?ovului). The analysis of the binding media has been done by means of gas chromatography coupled with mass spectrometry (GC/MS). The applied analytical procedure allowed the characterization of the proteinaceous, polysaccharide and lipid-resinous content of the binding media starting from a unique microsample. Results showed that a wide range of materials were used by the icons painters, mostly applied as mixtures of a proteinaceous material and a lipid one. The proteinaceous component proved to be mainly egg, though animal glue and casein were ascertained too, and proteins were often mixed; the lipid material was identified as linseed oil. In some of the icons pine resin and saccharide material were found. Data also highlighted that though the materials used in all the glass icons under study are similar, some particularities could be observed in the painting technique of the studied producing centers and icon painters.  相似文献   

13.
戴盟 《文化交流》2009,(4):40-41
我与书法结下不解之缘,从拿毛笔算起,已经80个年头了,但真正下苦功还是在“两头”：青少年时打下一点基础;离休后又补用了一点功夫。  相似文献   

14.
The sculptural polychromy in the Zhongshan Grottoes, sited in northwest China, has been investigated in terms of chemical composition of employed materials and pigments, state of conservation and painting technique. Raman analysis, Fourier-transform infrared analysis, analysis through energy-dispersive X-ray spectrometry coupled to scanning electron microscopy and pyrolysis coupled to gas chromatography and mass spectrometry were applied. Six analyzed samples showed silicates and kaolin as main components of the ground layers. Also lead white has been found in these layers. Minium, red-earth and mercury sulfide are the red pigments detected in the polychromy. A mixed use of malachite and atacamite has been detected in three green samples. Optical characteristics of atacamite and malachite found in the samples indicate a synthetic origin. The presence of a synthetic organic pigment such as phthalocyanine chlorinated pigment was also revealed. Ultramarine blue pigment, obtained by purification of lapis lazuli, has been detected in the blue sample. As for the binders used, fatty materials and siccative oil were found.  相似文献   

15.
This article reports the first occurrence of the combined use of lead and tin yellow type I and type II identified on the same paint layer. The two forms have been identified by Raman microscopy on a green layer from the background of the painting Gonfalone della Giustizia (confraternity of Justice banner) executed at Perugia around 1496 by Pietro Perugino.  相似文献   

16.
In the present work, an analytical characterization of painted plaster samples coming from ancient buildings dated back to 2nd cent. B.C., located in Licata (Sicily, Southern Italy), has been carried out. The investigation has been performed through different spectroscopic techniques: X-ray fluorescence (XRF) using an handheld energy-dispersive XRF analyzer, scanning electron microscopy equipped with an Energy Dispersive Spectrometry microanalysis detector (SEM-EDS) and Fourier transform infrared absorbance spectroscopy (FT-IR). The main goal is to identify the plaster and pigments material. In particular, the XRF investigation of surfaces is the first step for a preliminary elemental characterization. Then, through SEM-EDS measurements, a quantitative analysis of the chemical composition of the plaster and the pigmenting agents along with eventual components related to deterioration processes has been obtained. Finally, FT-IR absorbance spectra have proven to be a useful tool to investigate the molecular nature of the used materials.  相似文献   

17.
In the present article we report a study on some sodium dodecyl sulphate/propylene carbonate based aqueous micellar solutions developed with the aim of setting up a nanotechnological cleaning system to remove naturally aged polymeric acrylic layers from the surface of the wall paintings in the Old Sacristy of Santa Maria della Scala in Siena (15th century). Being these systems mainly composed of water (more than 70% by weight), the cleaning of the painted surface have been performed with low environmental impact, due to the small amount of the pure organic solvents used (always less than 25% by weight). Furthermore, the aqueous phase constitutes a hydrophilic barrier to the penetration of the hydrophobic acrylic materials into the porous support. Fourier Transform InfraRed spectroscopy (FTIR), Scanning Electron Microscopy coupled with Energy Dispersive X-rays analysis (SEM/EDX) and in situ capillary water adsorption measurements indicated the efficacy of this cleaning procedure. Finally, the chemical diagnostics investigation enabled to ascertain the presence of both salts (nitrates and gypsum) and the acrylic polymeric material.  相似文献   

18.
During the restoration plan of the famous painting “Madonna col Bambino e S. Giovannino” by Sandro Botticelli, located in the Museo Civico of Piacenza (Italy), a study on painting materials was carried out. The pigments, the binders and the materials used for the application of ground and priming layers were studied using micro-Raman spectroscopy, gas chromatography coupled with mass spectrometry (GC/MS), optical and electronic microscopies. Gypsum and anhydrite were found in the ground layer, while carbon black and lead white were used in the priming layers. The precious pigments of the artist's palette and the binders used (egg and animal glue) were determined.  相似文献   

19.
This paper reports petrographic and chemical data and magnetic susceptibility values for trachytes of quarries recognizable within the Euganean Hills and sets out diagnostic parameters for these rocks. The diagnostic scheme proposed is basic for the definition of provenance of trachytes used in ancient artefacts spread over northern Italy. Trachytes were extensively used by the Romans for paving Via Aemilia, the most important road in the Po Plains connecting Ariminum (present-day Rimini on the Adriatic sea) to Placentia (present-day Piacenza on the Po river). Remains of the trachytic flagstones (basoli) used for paving segments of Via Aemilia crossing Regium Lepidi (present-day Reggio Emilia) and Bononia (present-day Bologna) have been characterised petrographically, chemically and also using magnetic susceptibility data. The discriminating scheme proposed here for the Euganean trachytes has been applied to the data obtained for basoli and thus the provenance of each investigated block has been inferred. The rocks sampled at Regium Lepidi mostly come from Monselice (only a few blocks from Monte Oliveto and Monte Merlo) and those of Bononia come mostly from Monte Merlo and, subordinately, from Monte Oliveto and Monselice (only one sample from Monte San Daniele). The dominant provenance of blocks, which is different in the two colonies distant by less than 50 km, suggests that the two segments of Via Aemilia were not built simultaneously.  相似文献   

20.
Since their arrival in Papua New Guinea (PNG) in 2007, mobile phones have become objects of broad moral concern, particularly around issues of female social and physical mobility. I explore these concerns through a discussion of stories about ‘phone friends’ – frequently unknown callers who initiate long-term correspondence and exchange relationships via mobile. I argue that these stories, which resemble the long-established genre of giaman (trickster) folktales, condense and make explicit one of the central problems generated by mobile phone use in PNG: that of how to maintain morally appropriate forms of exchange in a context where spatiotemporal relations have been radically distorted and in which the identity of participants can be easily hidden. The appeal of phone friend stories, I suggest, lies not so much in their critique of social climbing or female mobility, but in their consideration of the problem of mediation.  相似文献   

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