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1.
Metal–organic frameworks (MOFs), which are generally considered to be crystalline materials comprising metal centers and organic ligands, have attracted growing attention because of their controllable structures and high porosity. MOFs based on transition metals (Fe, Co, Ni) are highly efficient electrode materials for electrochemical energy storage. In this review, the characteristics of Fe-MOFs, Co-MOFs, Ni-MOFs, and their derivatives are summarized, and the relationships between the structures and performance are unveiled in depth. Additionally, their applications in lithium–ion batteries, lithium–sulfur batteries, and supercapacitors are discussed. This review sheds light on the development of MOFs and their derivatives to realize excellent electrochemical performance. 相似文献
2.
作为镍氢电池负极活性物质,储氢合金是影响电极电化学性能的主要因素,对储氢合金进行表面处理可有效提高镍氢电池电极的电化学性能。实验采用电化学方法对储氢合金表面进行镍磷合金修饰处理,通过扫描电镜(SEM)及EDX能谱对电极表面进行了表征分析,测定了处理前后镍氢电池在1.5C和2C下的大电流放电性能,通过交流阻抗和循环伏安曲线对处理后电极进行了评价。测试结果表明,通过电化学修饰镍磷合金,储氢合金电极的大电流放电性能有所提高,电化学阻抗减小,循环寿命增长,有效提高了镍氢电池的性能。 相似文献
3.
金属钾由于具有较高的理论比容量、较低的电极电势以及低廉的成本等优点,用作电池负极近年来受到研究人员的广泛关注。然而,在电池循环过程中,金属钾与电解液间的界面副反应、不可控的枝晶生长以及体积波动等问题严重地阻碍了金属钾电池的发展。针对上述问题,研究人员提出了各种改进策略,如负极结构化设计、人工SEI界面修饰、电解质优化等。文章对近年来金属钾负极研究情况进行了简要的分析与总结,以期为金属钾电池的设计与开发提供参考。 相似文献
4.
作为一种新型储能器件,超级电容器因其高能量密度、快速充放电、长循环寿命等特点得到了越来越多的关注.目前超级电容器电极材料的研究主要分为三类,即碳材料(C)、金属氧化物(MxOy)和导电聚合物(ECP),这三种材料各有优缺点.将两种或两种以上的电极材料进行组合制成复合材料,由于各组分间的协同效应可大幅度提高材料的整体电化学性能.其中MxOy/碳复合材料的研究较为广泛,该文综述了该类复合材料的分类和最新研究概况. 相似文献
5.
A growing family of two-dimensional (2D) transition metal carbides or nitrides, known as MXenes, have received increasing attention because of their unique properties, such as metallic conductivity and good hydrophilicity. The studies on MXenes have been widely pursued, given the composition diversity of the parent MAX phases. This review focuses on MXene films, an important form of MXene-based materials for practical applications. We summarized the synthesis methods of MXenes, focusing on emerging synthesis strategies and reaction mechanisms. The advanced assembly technologies of MXene films, including vacuum-assisted filtration, spin-coating methods, and several other approaches, were then highlighted. Finally, recent progress in the applications of MXene films in electrochemical energy storage, membrane separation, electromagnetic shielding fields, and burgeoning areas, as well as the correlation between compositions, architecture, and performance, was discussed. 相似文献
6.
{3-[2-(2-methoxyethoxy) ethoxy]-propyl} triethoxysilane (TESM2) was synthesized and used as an electrolyte additive to improve the performances of lithium-ion batteries (LIBs). The electrochemical properties of the electrolyte (1 mol/L lithium hexafluorophosphate (LiPF 6)/ethylene carbonate (EC):diethylene carbonate (DEC):dimethyl carbonate (DMC), 1:1:1) with different contents of TESM2 were characterized by ionic conductivity measurement, galvanostatic charge/discharge test of graphite/Li half cells, and electrochemical impedance spectroscopy. Both the cycling performances and C-rate capabilities of graphite/Li half cells were significantly improved with an optimized content of 15% TESM2 in the electrolyte. The graphite/Li half cell delivered a very high specific capacity of 370 mAh/g at 0.2C rate without any capacity loss for 60 cycles, and retained a capacity of 292 mAh/g at 2C rate. The solid electrolyte interphase (SEI) film on the surface of the graphite anode was investigated by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), indicating that TESM2 was effectively involved in the formation of SEI film on the surface of graphite. 相似文献
7.
FePS_3, a classical 2D layered material with transition metal phosphorous trichalcogenides, was investigated as an anode material for Mg ion batteries. We used density functional theory to calculate the Mg storage properties of FePS_3, such as Mg adsorption energy, theoretical specifi c capacity, average voltage, diff usion energy barriers, volume change, and electronic conductivity. The theoretical specifi c capacity of the FePS_3 monolayer is 585.6 mA h/g with a relatively low average voltage of 0.483 V(vs. Mg/Mg~(2+)), which is favorable to a high energy density. The slight change in volume and good electronic conductivity of bulk FePS 3 are benefi cial to electrode stability during cycling. 相似文献
8.
Ml0.7Mm0.3Ni3.7Co0.7Mn0.4Al0.2 nanocrystalline hydrogen storage materials are prepared by melt-spinning(MS).X-ray diffraction is used for the measurement of the nanocrystalline size.Compared to the electrode of polycrystalline alloys,the property of activation MH9metal hydride)electrode of the alloys with nanometer scale became worse and the inital discharge capacity decreased.It may be ascribed to the decrease of the total amount of rare earth metals and the increase of oxygen on the surface from the analysis of components of the alloys.After heat-treatment,the electrochemical performance of MH electrode of as-spun alloys could be improved,which could be attributed to the alleviation of the lattice strain. 相似文献
9.
磷化铜由于其高理论容量和资源丰富等优点,逐渐成为一种拥有发展前景的新型锂离子电池负极材料.但其在充放电过程中存在着严重的体积膨胀和团聚问题,导致其循环性能差、倍率性能低.为此,我们利用水热法和低温磷化法合成了磷化铜/还原氧化石墨烯(Cu3P/rGO)复合材料,并对其物化特性和储锂性能进行了表征与测试.结果表明,rGO的修饰复合能够有效提高Cu3P的电化学性能,为发展新型锂离子电池负极材料提供实验与理论指导. 相似文献
10.
Conversion of carbon dioxide(CO 2) into valuable chemicals and renewable fuels via photocatalysis represents an eco-friendly route to achieve the goal of carbon neutralization.Although various types of semiconductor materials have been intensively explored,some severe issues,such as rapid charge recombination and sluggish redox reaction kinetics,remain.In this regard,cocatalyst modification by trapping charges and boosting surface reactions is one of the most efficient strategies to im... 相似文献
11.
All-solid-state lithium batteries (ASSLBs) have advantages of safety and high energy density, and they are expected to become the next generation of energy storage devices. Sulfide-based solid-state electrolytes (SSEs) with high ionic conductivity and low grain boundary resistance exhibit remarkable practical application. However, the space charge layer (SCL) effect and high interfacial resistance caused by a mismatch with the current commercial oxide cathodes restrict the development of sulfide SSEs and ASSLBs. This review summarizes the research progress on the SCL effect of sulfide SSEs and oxide cathodes, including the mechanism and direct evidence from high performance in-situ characterizations, as well as recent progress on the interfacial modification strategies to alleviate the SCL effect. This study provides future direction to stabilize the high performance sulfide-based solid electrolyte/oxide cathode interface for state-of-the-art ASSLBs and future all-SSE storage devices. 相似文献
12.
采用陶瓷薄膜技术及溶胶一凝胶法制备了氧离子传导YSZ（Y2O3稳定的ZrO2）电解膜与电极催化剂,构建了膜电极组装（MEA）及结构为H2S、（复合MoS2阳极）／YSZ传导膜／（复合NiO阴极）、空气燃料电池系统;通过在MoS2中掺杂NiS、电解质、Ag粉和淀粉制备了双金属复合MoS2阳极催化剂,在NiO中添加电解质、Ag粉和淀粉制备了复合NiO阴极催化剂：考察了不同操作温度对电池性能的影响,比较了几种不同电极催化剂的性能,研究了H2S／air固体氧化物燃料电池的电化学性能。实验结果表明,在H2S环境中,复合MoS2阳极催化剂比MoS2和Pt具有更好的性能,复合Nio阴极Pt阴极的极化小;在电极催化剂中加入Ag可显著提高电极的导电性．添加电解质和淀粉可以提高电极的离子传导性和多孔性：操作温度增加．传导膜的电传导率和电化学反应速率增加,电池的输出电流与功率密度增加,电化学性能变好。电池连续运行1～4d几乎不降级。在850℃和101．13kPa时．燃料电池最大输出功率密度为155mW·cm^-2,对应的电流密度为240mA·cm^-2。 相似文献
13.
AB 5-type hydrogen storage alloys are the most promising materials used as the anode in commercial Ni-MH secondary battery. It
is very important for electrode materials to have a wider operation temperature range. The component Al is the dominant element
to control the electrochemical behavior of the AB 5-type alloys at elevated temperature. With the increase of the amount of Al the discharge capacity decreases and the retention
of discharge capacity increases with increasing temperature. It is mainly due to the formation of stable and dense surface
oxide film Al 2O 3, which inhibits the electrode corrosion and the further oxidation underneath the surface films. 相似文献
14.
Lithium-ion batteries(LIBs) have been developed for over 30 years; however, existing electrode materials cannot satisfy the increasing requirements of high-energy density, stable cycling, and low cost. Here, we present a perovskite-type LaNiO_3 oxide(LNO) as a new negative electrode material. LNO was successfully synthesized by a sol–gel method. The microstructure and electrochemical performance of LNO calcined at various temperatures have been systematically investigated. The LNO electrode shows a high rate capability and long cycling stability. In a C-rate test, a specific capacity of 77 mAh/g was exhibited at 6 C. LNO can also deliver a specific capacity of 92 mAh/g after 200 cycles at 1 C. This paper presents a type of binary metal oxide as a new anode material for high-performance LIBs. 相似文献
15.
Renewable and economical generation of hydrogen via electrochemical methods shows great potential in addressing the energy crisis. In this study, an emerging molten salt method was adopted for the synthesis of a cerium-modified rhenium disulfide nanosheet for electrical hydrogen evolution reactions. The prepared 1% Ce-doped rhenium disulfide (ReS2) sample showed promoted hydrogen evolution performance in both acid and alkaline electrolytes compared to bare ReS2. Generating of abundant defects in ReS2 exposed more reaction active sites. Moreover, adding cerium accelerated the hydrogen evolution dynamics. Hopefully, this work will offer new insight into developing ReS2-based electrocatalysts for hydrogen evolution reactions. 相似文献
16.
1IntroductionThe synthesis and characterization of nano-struc-tured materials are the subject of intense current re-search.Hyperfineγ-Fe2O3particle with good perfor-mance,such as magnetism,catalysis,gas-sensitivityand so on,are widely applied in various fields[1].It ishighly significant to research and develop the methodsfor synthesis of nanometerγ-Fe2O3.With the development of nano-science and nano-technology,the methods for preparation ofγ-Fe2O3have been greatly progressed,for example,… 相似文献
17.
Phosphorus in energy storage has received widespread attention in recent years. Both the high specific capacity and ion mobility of phosphorus may lead to a breakthrough in energy storage materials. Black phosphorus, an allotrope of phosphorus, has a sheet-like structure similar to graphite. In this review, we describe the structure and properties of black phosphorus and characteristics of the conductive electrode material, including theoretical calculation and analysis. The research progress in various ion batteries, including lithium-sulfur batteries, lithium–air batteries, and supercapacitors, is summarized according to the introduction of black phosphorus materials in different electrochemical applications. Among them, with the introduction of black phosphorus in lithium-ion batteries and sodium-ion batteries, the research on the properties of black phosphorus and carbon composite is introduced. Based on the summary, the future development trend and potential of black phosphorus materials in the field of electrochemistry are analyzed. 相似文献
18.
Interest in the development of grid-level energy storage systems has increased over the years.As one of the most popular energy storage technologies currently available,batteries offer a number of high-value opportunities due to their rapid responses,flexible installation,and excellent performances.However,because of the complexity,multifunctionality,and wide deployment of power grids,trade-offs in battery performance exist,especially when considering economics,environmental effects,and safety.Therefore,establishing a comprehensive assessment of battery technologies is an urgent undertaking.In this work,we present an analysis of rough sets to evaluate the integration of battery systems(e.g.,lead-acid batteries,lithium-ion batteries,nickel/metal-hydrogen batteries,zinc-air batteries,and Na-S batteries) into a power grid.Specifically,technological properties,economic significance,environmental effects,and safety of these battery systems are evaluated on the basis of rough set theory.In addition,some perspectives are provided to promote the development of battery technologies for grid-level energy storage. 相似文献
19.
The cyclic oxidation behaviors of Fe-28Al-5Cr-O. 1Zr (at%) and Fe-28A15Cr-O. 5Nb (at%) alloys have been investigated in air
at high temperature. The results show that the distinctive whisker-like oxides were formed on the surface of Zr-containing
Fe 3 Al based alloy after 500 hrs. cyclic oxidation at 800 °C and 1000 °C. The results also indicate that the addition of small
amount of Zr to Fe 3 Al based alloy can improve its adherence strength between the oxides and metal substrate and is beneficial to the oxidation
resistance. However, for the Nb-containing Fe 3 Al based alloy, porous convoluted oxides were formed after 350 hrs. cyclic oxidation at 1000°C, and this type of oxides didn’t
not contribute to the oxidation resistance. 相似文献
20.
Grid-level large-scale electrical energy storage(GLEES) is an essential approach for balancing the supply–demand of electricity generation, distribution, and usage. Compared with conventional energy storage methods, battery technologies are desirable energy storage devices for GLEES due to their easy modularization, rapid response, flexible installation, and short construction cycles. In general, battery energy storage technologies are expected to meet the requirements of GLEES such as peak shaving and load leveling, voltage and frequency regulation, and emergency response, which are highlighted in this perspective. Furthermore, several types of battery technologies, including lead–acid, nickel–cadmium, nickel–metal hydride, sodium–sulfur, lithium-ion, and flow batteries, are discussed in detail for the application of GLEES. Moreover, some possible developing directions to facilitate efforts in this area are presented to establish a perspective on battery technology, provide a road map for guiding future studies, and promote the commercial application of batteries for GLEES. 相似文献
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