共查询到20条相似文献，搜索用时 15 毫秒
1.
Structure and Magnetic Propoerty of Amorphous Fe—Ni Particles prepared by Mechanical Alloying 总被引：1，自引：0，他引：1
The amorphous Fe67.5 alloy particles have been prepared by mechanical alloying(MA) process of elemental powders.The crystallization is observed at temperature around 405℃ by means of differential thermal analyzer,It is found that the coercivity Hc and the effective magnetic anisotropy value of amorphous phase are not far from that of crystal phase.The magnetization behavior of amorphous and nanocrystalline samples prepared by mechanical alloying and milling process are quite similar,they obey 1/H law at middle-high field and 1/H^2 at higher field.The 1/H field dependence is attributed to a large number of dislocations created during MA process.The studies on the 1/H^2 field dependence reveals that magnetization of Fe-Ni ultrafine particles are governed predominantly by internal stress fields induced by MA process. 相似文献
2.
The magnetic properties of as-quenched and annealed Fe73.5Ag1Nb3Si13.5B9 alloys were investigated. X-ray diffraction was used to monitor the structure changes of the samples under different annealing
temperatures. It was found that by Cu addition, the crystallization temperature T
x1 of Fe-Nb-Si-B alloy is decreased, whereas by Ag addition, the T
x1 is increased. A small amount of α-Fe and Ag were obtained after the sample was annealed at 500°C for 1 h. With increasing
the annealing temperature, Fe23B6, Fe2B, Fe3B were separated out and magnetic properties of the samples were impaired quickly. A mostly single nanocrystalline grain of
a-Fe phase could not be obtained in the annealed samples. 相似文献
3.
Hot extrusion was conducted in the α+β phase region for promoting mechanical properties of Ti42Al9V0.3Y. The microstructures and tensile properties before and after hot extrusion were studied. The results show that the microstructure of the as-cast alloy mainly consists of massive γ phase in β matrix and the as-extruded alloy mainly consists of lamellar α2/γ, lamellar β/γ, and strip γ propagating from elongated β phase. In the as-cast alloy, the predominantly observed fracture mode is transgranular cleavage failure at room temperature and intergranular fracture at 650-750 °C. After hot extrusion, it transforms into transgranular cleavage-like failure, including translamellar cleavage and delamination. The excellent tensile properties of the as-extruded material are attributed to the obvious refined microstructure with broken YAl2 particles and the micro-crack shielding action of the TiAl lamellasome. 相似文献
4.
Supersaturated solid solutions Fe1-xCx （0≤x≤0.9 ） of wide composition range have been prepared by mechanical alloying process. Nanocrystalline phase was formed for 0 ≤ x ≤ 0.67 and a large grain phase for 0.75 ≤ x ≤ 0.9. The large fraction of graphite volume puts off formation of nanocrystalline phase for high carbon content. In the large grain phase, magnetization follows simple magnetic dilution, and eoereivity He is mainly due to dissolution of carbon at grain boundaries. In the nanocrystalline phase the alloying effect of carbon is revealed by a distinct reduction of average magnetic moment. The increasing lattice constant with increasing carbon content is observed for x ≤ 0.5, suggesting that the high carbon concentration may enhance diffusion of carbon into the Fe lattice. It shows a discontinuity in the Hc variation with a grain size D of nanocrystalline phase. For small grain D below the critical value, Hc increases with D. For a large grain D, Hc decreases with increasing D. The solubility limit of carbon in a-Fe extended by nanocry- stalline phase formation is discussed. 相似文献
5.
新型铁磁性材料的结构电磁特性及在配电变压器中的应用 总被引：1，自引：0，他引：1
文章系统地论述了新型铁磁性材料--铁基非晶、铁基大块非晶、铁基纳米晶、铁基大块纳米晶合金的结构、电磁性能及它们作为变压器铁芯使用的优点和缺点;论述了发展大块铁基纳米晶合金对于优化变压器性能的重要性以及配电变压器铁芯材料的发展趋势. 相似文献
6.
7.
A new supported amorphous catalyst CoP/TiO2 was prepared by chemical reduction and characterized by ICP, XRD, TEM, BET and DSC Its application in decomposing PH3 to high purity phosphor and its catalytic activity were studied. The decomposition rate is over 95% at 450 ℃. For comparison, unsupported CoP amorphous catalyst was prepared by the same method. The result suggests that CoP/TiO2 exhibits higher thermal stability and catalytic activity than CoP, which is attributed to the high dispersion of CoP alloy particles on the support-TiO2. 相似文献
8.
This article reports first-principles band structure calculations forRMn6Sn6 (R=Tb, Dy). The calculation uses the linear muffin-tin orbitals (LMTO) method in the atomic-sphere-approximation (ASA), and
yields results showing that both TbMn6Sn6 and DyMn6Sn6 are ferrimagnetic compounds with antiparallel aligned moments ofR and Mn atoms. In this research the 4f states ofR atoms are treated as localized states, i.e., the hybridization of 4f states with other valence electrons is neglected. The moments of Mn in both compounds were determined to be 2.43 μB and 2.38 μB, respectively. The considerably small additional moments for Mn from the spin-orbit coupling indicates that the spin-orbital
coupling is not dominated for Mn atoms. The total moments of Tb and Dy atoms are 10.28 μB and 11.20 μB. All the calculation findings accorded well with experimental results.
Project supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
of China. 相似文献
9.
The room temperature tensile properties of cold-rolled and annealed Fe3(Al,Cr,Zr) alloy are similar to those of warm-rolled Fe3Al alloys. The cold-rolled Fe3(Al,Cr,Zr) alloy is also susceptible to test environments. It has been shown that the ductility in various environments decreases
in sequence of oxygen-oil-air-distilled water. The results of X-ray diffraction analysis show that (211) preferred orientation
of B2 phase appears in cold-rolled Fe3(Al,Cr,Zr) alloy after recrystallization annealing.
Supported by the National Natural Science Foundation of China (59895157) and the Natural Science Foundation of Shanghai Municipal
Commission of Science and Technology (98ZE14020) 相似文献
10.
Ultra-high vacuum gaseous hydrogen permeation experiments on Fe3Al-based alloy were performed in the temperature range of 330∼450°C with an upstream hydrogen pressure between 3. 38×104 Pa and 7.28×104 Pa. The results show that the hydrogen diffusivity and permeability in Fe3Al-based alloy obey Arrhenius relationship in the experimental temperature range and the hydrogen permeation process is controlled
by the lattice diffusion of hydrogen at relative high temperature. The activation energy of hydrogen diffusion in the Fe3Al-based alloy was found to be 75 kJ/mol.
Supported by the National Natural Science Foundation of China (59895157) 相似文献
11.
Surface morphologies of Zr52.5 Al10 Ni10 Cu15 Be12.5 bulk metallic glass after being rolled at both a temperature around T9 and near （ Tx - 50） K were investigated with a scanning electron microscopy. Macroscopic and microscopic observation results show that squamae, cracks, steps and wedges exist on the surface when the samples were rolled at temperatures around Ty. However, a smooth and fiat surface appears when the samples were rolled at temperatures near （ Tx - 50） K. These results indicate that the mode of deformation in the supercooled liquid region is a partially homogeneous flow at a temperature around T9, and a fully homogeneous one at temperatures near （ Tx - 50） K. According to the results, it is more feasible to roll the amorphous alloys at temperatures near （ Tx - 50） K to obtain parts with smooth and fiat surface. 相似文献
12.
Thermodynamic Optimization of DyCl3 -NaCl System 总被引：2，自引：0，他引：2
In this paper, the phase diagram of the DyCl3 -NaCl system is optimized and calculated with CALPHAD ( calculation of phase diagram ) technology. A set of thermodynamic functions of compounds Na3 DyCl6, NaDyCl4, and NaDY2 Cl7 have been optimized and calculated based on an interactive computer-assisted analysis. The optimized thermodynamic parameters, calculated phase diagram and experimental phase diagram are thermodynamically serf-consistent. 相似文献
13.
Shiyue Xu Hangde Chen Zhengming He Yaoming Shi Chuanhua Dong Zhengming Zhang 《上海大学学报(英文版)》1998,2(4):301-304
Nanocrystalline Fe25Ni75 powders were prepared by the mechanical alloying process. They were investigated by X-ray diffraction and magnetic measurements.
The ball milling time dependence of grain size, internal strain and magnetic properties has been discussed. The results show
that the formation of Fe25Ni75 alloy phase is almost completed after milling for 30 hours. The reduction of grain size accompanied by the growth of internal
strain was observed after extended milling. An average grain size about 10–20 nm of alloyed powders has been determined by
Sherrer formula estimation. The saturation magnetisation Ms has a slight increase when the average grain size continues to
decrease by intensive milling. This fine size of mechanically alloyed powders (10–20 nm) results in a single domain magnetic
structure and the formation of superparamagnetic phase. 相似文献
14.
Díaz MP Rizo OD Díaz AL Aparicio EE Díaz RR 《Journal of Zhejiang University. Science. B》2006,7(12):947-956
A discriminant method for optimizing activity in nuclear medicine studies is validated by comparison with ROC （received operating characteristic）-curves. The method is tested in 21 single photon emission computerized tomography （SPECT）, performed with a cardiac phantom. Three different lesions （Lb L2 and L3） were placed in the myocardium-wall by pairs fbr each SPECT. Three activities （84, 37 or 18.5 MBq） of 99mTc were used as background. Linear discriminant analysis was used to select the parameters that characterize image quality among the measured variables in the images [（Background-to-Lesion （B/Li） and Signal-to-Noise （S/N） ratios）]. Two clusters with different image quality （P=0.021 ） were obtained. The ratios B/Lj, B/L2 and B/L3 are the parameters used to construct the function with 100% of cases correctly classified into the clusters. The value of 37 MBq was the lowest tested activity for which good results for the B/Li ratios were obtained. The result coincides with the applied ROC-analysis （r=0.89）. 相似文献
15.
In this study, the structure of nanocrystalline CaCO3 was analyzed using TEM, SEM, FT-IR and XRD measurements. An unusually narrowv
3 band with remarkable blue shift about 40 cm−1 in the infrared spectrum was observed. XRD analysis revealed a somewhat large crystallite strain in the nano-particle CaCO3. The strain was possibly related to the weakened lattice vibration. This suggests a preliminary explanation for the abnormal
IR assimilation characteristics of nanocrystalline CaCO3 aforementioned. 相似文献
16.
Ml0.7Mm0.3Ni3.7Co0.7Mn0.4Al0.2 nanocrystalline hydrogen storage materials are prepared by melt-spinning(MS).X-ray diffraction is used for the measurement of the nanocrystalline size.Compared to the electrode of polycrystalline alloys,the property of activation MH9metal hydride)electrode of the alloys with nanometer scale became worse and the inital discharge capacity decreased.It may be ascribed to the decrease of the total amount of rare earth metals and the increase of oxygen on the surface from the analysis of components of the alloys.After heat-treatment,the electrochemical performance of MH electrode of as-spun alloys could be improved,which could be attributed to the alleviation of the lattice strain. 相似文献
17.
K. Hussain Reddy 《Resonance》1999,4(6):67-77
Vitamin B12 is an important coordination compound in biology. It is an interesting biomolecule in the sense that no other vitamin contains a metal ion. This is the only naturally occurring organometallic compound found in biology. An intriguing aspect of vitamin B12 is the great stability of the metal-carbon bond. A great deal of new and interesting inorganic chemistry has been uncovered while studying systems pertinent to B12. In this article some salient features of this unique molecule (B12) and its model compounds are presented. 相似文献
18.
Evolution of Surface Oxide Film of Typical Aluminum Alloy During Medium-Temperature Brazing Process简 总被引：1，自引：0，他引：1
The evolution of the surface oxide film along the depth direction of typical aluminum alloy under medium-temperature brazing was investigated by means of X-ray photoelectron spectroscopy （XPS）. For the alloy with Mg content below 2.0wt%, whether under cold rolling condition or during medium-temperature brazing process, the en-richment of Mg element on the surface was not detected and the oxide film was pure Al2O3. However, the oxide film grew obviously during medium-temperature brazing process, and the thickness was about 80 nm. For the alloy with Mg content above 2.0wt%, under cold rolling condition, the original surface oxide film was pure Al2O3. However, the Mg element was significantly enriched on the outermost surface during medium-temperature brazing process, and MgO-based oxide film mixed with small amount of MgAl2O4 was formed with a thickness of about 130 nm. The alloy-ing elements of Mn and Si were not enriched on the surface neither under cold rolling condition nor during medium-temperature brazing process for all the selected aluminum alloy, and the surface oxide film was similar to that of pure aluminum, which was almost entire Al2O3. 相似文献
19.
K. Hussain Reddy 《Resonance》2011,16(12):1273-1283
Vitamin B12 is an important coordination compound in biology. It is an interesting biomolecule in the sense that no other vitamin contains
a metal ion. This is the only naturally occurring organometallic compound found in biology. An intriguing aspect of vitamin
B12 is the great stability of the metal-carbon bond. A great deal of new and interesting inorganic chemistry has been uncovered
while studying systems pertinent to B12. In this article some salient features of this unique molecule (B12) and its model compounds are presented. 相似文献
20.
Magnetic properties of nanocrystalline Fe60 Cr40 powders prepared by mechanical alloying in vacuum and air were investigated by utilizing the measurements of magnetization, X-ray diffraction, and ^67Fe M（oe）ssbauer spectrum. The results show that the Fe60 Cr40 powders keep the bcc structure during milling in air and vacuum. The saturation magnetization of the Fe60 Cr40 powders milled in vacuum and air decreases with the increase of the milling time up to 45 h. The decrease of saturation magnetization of the Fe60Cr40 powders milled in vacuum is due to the formation of Fe-Cr solid solution, while in air it is due to the formation of paramagnetic disorder structure and solid solution. 相似文献