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1.
本将玻碳(GC)电极置入1 mol·L^-1NaNO2 1 mmol·L^-1NiNO3 1 mmol·L^-1K3Fe(CN)4混合溶液中进行循环伏安扫描(CV)可现场制备出性能稳定、厚度可控的NiHCF/GC修饰电极,且其电化学可逆性较NiHCF/Ni更好.研究表明对于在空白玻碳电极上氧化电位较高的神经传导物质多巴胺(DA),NIHCF膜可通过媒介作用使其氧化电位降低约200mV.大大提高其电子转移速率,利用这种电催化作用,可较好地对溶液中DA含量进行测定.  相似文献   

2.
96年全国高考上海化学试题第22题的命题“pH值为4的FeCl3溶液……”.是否存在PH值为4的FeCl3溶液呢?对于这个问题,我们不妨分析一下.在FeCl3溶液中存在水解平衡:Fe3++3H2OFe(OH)3+3H+已知KspFe(OH)3=4×10-38,Kw=10×10-14设FeCl3溶液中[Fe3+]=0.1mol/L,Fe3+完全沉淀为Fe(OH)3时的[Fe3+]=1.0×10-6mol/L根据溶度积公式,可以求得Fe3+开始形成Fe(OH)3沉淀的pH值为1.87.同理,也可以求得pH值为4时溶液中Fe3+的浓度.[Fe3+]=Ksp/[OH-]3=4×10-38/(10-10)3=4×10-8(mol/L)…  相似文献   

3.
用循环伏安法电聚合烟酰胺(3-吡啶甲酰胺),在玻碳电极上的制备了聚合物膜修饰电极,考察其对NO2^-及共存离子的作用情况,该修饰电极对NO2^-有良好的电化学催化作用和选择性,用差分脉冲伏安法(DPV)测定其氧化电流在N0f浓度1.68×10^-6mol/L~-1.76×10^-3 mol/L范围内呈线性关系,线性相关系数为0.999,检测限5.6×10^-7 mol/L。  相似文献   

4.
本文研制了一种高效、灵敏的葡萄糖生物传感器。通过在玻碳(GC)电极表面先后修饰四胺基钴酞菁(CoTAPC)和葡萄糖氧化酶(GOD),最后涂敷一层Nafion膜,获得了抗干扰力强、灵敏度高、稳定性好、寿命长的葡萄糖生物传感器,在1.0&;#215;10^-5-5.0&;#215;10^-3mol/L浓度范围内与峰电流呈良好的线性关系,寿命达一个月以上。同时,本文将微渗析取样技术与HPLC-电化学检查(HPLC-EC)联用测定了大鼠脑皮层中的葡萄糖(glucose)含量,结果为0.74&;#177;0.01mmol/L(n=4)。  相似文献   

5.
本文研究了铅(Ⅱ)-胱氨酸-甘氨酸体系在悬汞电极上的吸附伏安特性。在0.001mol/L甘氨酸溶液中(pH=8.2),加入铅(Ⅱ)溶液后,使胱氨酸的峰电流增大,最佳实验条件下,该峰电流与优氨酸浓度在3.3×10-8~1.0×10-6mol/L范围内呈良好的线性关系,检测限过3.3×10-9mol/L。通过对该峰的性质及反应机理的研究,证明此峰为配合物吸附还原峰,吸附反应物为铅(Ⅱ)与胱氨酸形成的1:1配合物,电机反应为二电子还原。  相似文献   

6.
采用N一丁基吡啶六氟磷酸盐EBuPy]PF6和壳聚糖(Chi)作为修饰剂,通过静电吸附作用在玻碳电极表面形成稳定性较强的自组装膜修饰电极[BuPy]PF4-Chi/GC.采用电化学阻抗谱技术和循环伏安法研究自组装膜在K3[Fe(CN)4]-K4EFe(CN)6]溶液中的电化学行为,结果表明:形成的自组装膜对溶液与基底间的界面电子转移有强烈的阻碍作用,氧化还原峰电流与扫速的1/2次方在20~100mV/s的范围内呈良好的线性关系,表明该电极过程受扩散控制.该修饰电极对铜离子有很好的选择性,响应灵敏度相比于未修饰的电极提高60倍,铜离子的溶出线性伏安峰电流与其浓度在1.56×10“~6.25×10-4mol·L-1范围内呈良好的线性关系(R=0.9966).  相似文献   

7.
利用壳聚糖(CTS)与香草醛合成改性壳聚糖席夫碱衍生物(VCG),将其滴涂在玻碳电极表面形成薄膜,通过吸附富集电子介体Fe(CN)6^3-,使其固定在电极表面,制备了壳聚糖席夫碱衍生物修饰玻碳电极(Fe(CN)6^3-3-/VCG/GC).以此修饰电极为工作电极,铂电极为对电极,饱和甘汞电极为参比电极,用循环伏安法对槲皮素的电化学行为进行了研究.在pH 6.0的磷酸盐缓冲液(PBS)中,氧化峰电流与槲皮素浓度在10^-4~10^-2 mol/L范围内呈比较好的线形关系,可用于槲皮素测定.  相似文献   

8.
通过介绍一种新电解池──微界面ITIES四电极分立式悬液电解池的某些操作技巧,并通过O/W界面循环伏安法测试了它的某些性能,同时.用它通过O/W界面循环伏安法(恒电位法)研究L─赖氨酸在水相为1mol/l水溶液,抽相为5×10-2mol/ITBA+TPB-+DCE溶液参比为TBACL溶液体系中的某些电迁移性质。  相似文献   

9.
用卡拉胶将肌红蛋白(Mb)固定在玻碳电极(Gc)表面,制备了MB-卡拉胶膜修饰电极.包埋在卡拉胶中的Mb可以与电极发生直接电子传递.Mb-卡拉胶膜修饰电极在水/有机混合溶液中,表现出准可逆的直接电化学过程.式电势(E^0’=-0.407V)表明该电化学响应是MbFe(Ⅲ)/Fe(Ⅱ)电对的氧化还原.在一定范围内,溶液pH增加,Mb氧化还原式电势负移,且呈线性关系,说明Mb的电子传递过程伴随有质子的转移.扫描电镜显微研究表明,卡拉胶水凝胶与肌红蛋白之间有较强的作用,紫外光谱表明.血红素周围的微环境没有改变.  相似文献   

10.
在镧离子掺杂类普鲁士蓝(La-PB)修饰的玻碳电极表面电沉积汞膜,制备了一种新型化学修饰复合汞膜电极La-PB/MFE/GC;研究了修饰层厚度、镀汞方式和汞膜成长过程对复合汞膜形成的影响;并以Pb2+为探针离子,对镧、钴离子掺杂类普鲁士蓝复合汞膜电极和常规玻碳汞膜电极的汞膜稳定性和金属离子的溶出伏安行为等进行了对比研究;同时,应用该电极结合示差脉冲阳极溶出伏安法对实际水样中微量Pb2+的质量浓度进行了测定.结果表明,Pb2+在该复合汞膜电极上的阳极溶出氧化峰电流在4.82×10-9~4.82×10-7mol/L范围有良好的线性关系(r=0.995 5,n=13),检出限为9.06×10-10mol/L,RSD值为2.6%,加标回收率为97%~102%.可用于实际样品的测定.  相似文献   

11.
《海外英语》2007,(5):44-45
It is worthy of noting that, whilst Crookston Castle witnessed the earlier and happier portion of Mary's variegated life,  相似文献   

12.
一、吃和喝吃苹果 eat an apple, 吃药 take medicine,吃糖 have some sweets,吃饭 have one's meals,吃馆子 dine out,吃惊 be surprised/  相似文献   

13.
《海外英语》2007,(5):10-11
Many college freshmen arrive woefully unprepared to do college work, and as disadvantaged populations continue to grow, the share of the American work force that has made it through college is expected to plummet. Many experts blame that educational failure not just on high schools but also on colleges. School & College, a special report by The Chronicle, looks at efforts to fix the system. What reforms would better prepare students for college? What should schools and colleges be doing differently? How should state and federal officials help?  相似文献   

14.
汉字倒说     
汉字的六书,《说文》对“转注”一类,语焉不详。后世学者提及转注,也仅限于许慎所举出的例字。《汉字例说》一文,作者从转注的角度综合考虑,对部分现代常用字作了分析,跟传统的解释有所不同。希望能抛砖引玉,互相切磋,以推进学术研究。  相似文献   

15.
《海外英语》2007,(4):36
There are numbers of crossroads on our long and unpredictable life journey where we totally have no idea about which direction to choose. No matter what our decision is, we should not turn back, but face the music and go ahead instead. I am this kind of girl who always does try without regretting, one example is how I dealt with my love.  相似文献   

16.
王菲 《华章》2007,(12):273-273
Migration occurs behind a variety of reasons and has a great effect on the whole world. People may migrate in order to improve their economic situation, or in order to escape civil strife, persecution, and environmental disasters. The impact of migration is complex, bringing both benefits anddisadvantages. This paper briefly talks about the causes of migration, the allocation of benefits, and the ways in which individual countries and the international community deal with this important subject.  相似文献   

17.
钱生钱!     
我们绝大部分人都同意一件事情——我们喜欢金钱。但是你对金钱的喜欢之情足够到让你创立一份事业么?.财富通常被人忽视,主要在于人们不能真正了  相似文献   

18.
裴水妹 《华章》2007,(11):196
Sister Carrie is one of the most controversial characters in American literature.Thought as a "fallen woman" firstly,she was defined as a "new woman" by some critics later. However, by digging into the motivaton behind the whole process of Carrie's "success", the relationship between Carrie and her creator (the author), the social conditions of then American, it can be found that Carrie has never been free-standing on her thought and she has never found her real-sdf even after becoming a famous actress. In a society dominated by mass consumerism Carrie is only an adherent of her own desires. She also is a representative of all those country girls flooded into cities, a symbol and a sacrifice of the urbanization of America in a time countryside was overcome by cities.  相似文献   

19.
20.
1.IntroductionOne-cyclecontrolmethod,whichwasproposedaboutonedecadeago[1],hasbecomeanattractivemethodinspecialfieldssuchaspowerfactorcorrection[2-6],switchingamplifiers[7,8],etc.Themainideaofthiscontrollerisbasedonintegrationofdiodevoltageinone-cycleandforcesittobeexactlyequaltothereferencevalue.Themainadvantageofthiscontrollerisitsrealtimeabilitytorejectthevariationofinputvoltage[1].Despitethisgreatability,ithasnogoodperformancesinrejectingofloaddisturbanceandfollowingreferencecommands.Espec…  相似文献   

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