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1IntroductionIn recent years,tri meric quaternary ammoniumsur-factants,which have three hydrophobic and three hy-drophilic groups connected bytwo spacer chains,havebeen developed[1-5].The tri meric surfactants appearunique physicochemical properties such … 相似文献
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Aerobically activated sludge processing was carried out to treat terylene artificial silk printing and dyeing wastewater (TPD wastewater) in a lab-scale experiment, focusing on the kinetics of the COD removal. The kinetics parameters determined from experiment were applied to evaluate the biological treatability of wastewater. Experiments showed that COD removal could be divided into two stages, in which the ratio BOD/COD (B/C) was the key factor for stage division. At the rapid-removal stage with B/C>0.1, COD removal could be described by a zero order reaction. At the moderate-removal stage with B/C<0.1, COD removal could be described by a first order reaction. Then Monod equation was introduced to indicate COD removal. The reaction rate constant (K) and half saturation constant (KS) were 0.0208-0.0642 L/(gMLSS)·h and 0.44-0.59 (gCOD)/L respectively at 20 ℃-35 ℃. Activation energy (Ea) was 6.05×104 J/mol. By comparison of kinetic parameters, the biological treatability of TPD wastewater was superior to that of traditional textile wastewater. But COD removal from TPD-wastewater was much more difficult than that from domestic and industrial wastewater, such as papermaking, beer, phenol wastewater, etc. The expected effluent quality strongly related to un-biodegradable COD and kinetics rather than total COD. The results provide useful basis for further scaling up and efficient operation of TPD wastewater treatment. 相似文献
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INTRODUCTIONInordertogetpliableandelegantterylenefabricjustlikesilk,terylenegreigeclothisalwayspretreatedwithalkali-decompositionprocesswh-ereinterylenegreigeclothishydrolyzedtosomeextentinNaOHsolutionatcertaintemperature(T)andpressure.Duringthisprocess,thesuperficialterylenefibreispeeledofffromtheclothanddis-solvedintosolution,inwhichteryleneacid(TA)andethyleneglycolaredischargedaspollutantsinwastewater.Theobtainedterylenefabricwithsi-lkenwrinkleandsoftfeelingiscalledartificialsilkfabr… 相似文献
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Electrocatalysis method for wastewater treatment using a novel beta-lead dioxide anode 总被引：1，自引：1，他引：1
A novel β-PbO2 anode modified with fluorine resin was developed for typical pollutant electrocatalytic degradation and wastewater treatment. Various operating parameters such as applied voltage (3.5-10.5 V), pH (2-6), salinity of the electrolyte (0.5-2 g／L K2SO4) and initial phenol concentration (100-400 mg／L) were investigated to explore the electrocatalytic ability of the anode by taking phenol as sample. A preliminary study on dyeing wastewater treatment by this method indicated that the biodegradability could be increased to suit subsequent biological treatment. The stability of the anode has been proved to be high against acidity. The anode showed promising application for treatment of wastewater, especially of high salinity and high acidity wastewater. 相似文献
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A treatability study of industrial wastewater containing chlorinated nitroaromatic compounds (CNACs) by a catalytic ozonation process (COP) with a modified Mn/Co ceramic catalyst and an aerobic sequencing batch reactor (SBR) was investigated.A preliminary attempt to treat the diluted wastewater with a single SBR resulted in ineffective removal of the color,ammonia,total organic carbon (TOC) and chemical oxygen demand (COD).Next,COP was applied as a pretreatment in order to obtain a bio-compatible wastewater for SBR treatment in a second step.The effectiveness of the COP pretreatment was assessed by evaluating wastewater biodegradability enhancement (the ratio of biology oxygen demand after 5 d (BOD5) to COD),as well as monitoring the evolution of TOC,carbon oxidation state (COS),average oxidation state (AOS),color,and major pollutant concentrations with reaction time.In the COP,the catalyst preserved its catalytic properties even after 70 reuse cycles,exhibiting good durability and stability.The performance of SBR to treat COP effluent was also examined.At an organic loading rate of 2.0 kg COD/(m3·d),with hydraulic retention time (HRT)=10 h and temperature (30±2) °C,the average removal efficiencies of NH3-N,COD,BOD5,TOC,and color in a coupled COP/SBR process were about 80%,95.8%,93.8%,97.6% and 99.3%,respectively,with average effluent concentrations of 10 mg/L,128 mg/L,27.5 mg/L,25.0 mg/L,and 20 multiples,respectively,which were all consistent with the national standards for secondary discharge of industrial wastewater into a public sewerage system (GB 8978-1996).The results indicated that the coupling of COP with a biological process was proved to be a technically and economically effective method for treating industrial wastewater containing recalcitrant CNACs. 相似文献
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This paper describes the removel of COD and nitrogen from wastewater with modified sequencing batch biofilm reactor,The strategy of simultaneous feeding and draining was explored.The results show that introduction of a new batch of wastewater and withdrawal of the purifeid water can be conducted simultaneously with the maximum volumetric exchange rate of about 70%,Application of this feeding and draining mode leads to the reduction of the cycle time,the increase of the utilization of the reactor volume and the simplification of the reactor structure.The treatment of a synthetic wastewater containing COD and nitrogen was investigated.The operation mode of F(D)-O(i.e.,simultaneous feeding and draining followed by the aerobic condition)was adopted.It was found that COD was degraded very fast in the initial reaction period of time,then reduced slowly and the ammonia nitrogen and nitrate nitrogen concentrations decreased and increased with time respectively,while the nitrite nitrogen level increased first and then reduced.The relationship between the COD or ammonia nitrogen loading and its removal rate was examined,and the removal of COD,ammonia nitrogen and total nitrogen could exceed 95%,90%and 80% respectively,The fact that nitrogen could e removed more completely under constant aeration(aerobic condition)of the SBBR operation mode is very interesting and could be explained in several respects. 相似文献
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固定化微生物--曝气生物滤池工艺在废水处理中的应用 总被引：1，自引：0，他引：1
采用固定化微生物-曝气生物滤池污水处理系统（IBAF工艺）对多种实际高浓度有机废水进行实验研究。实验结果表明：该工艺在去除COD、氨氮、挥发酚、色度、SS方面具有独特的优势，将成为处理高浓度有机废水的主导工艺。 相似文献
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采用价廉的涤纶滤膜作为电解体系隔膜,利用阴、阳极同时作用降解含酚工业废水,在反应时间80min,曝气量1.2L/min,电流密度30mA/cm2的最佳条件下,含酚废水COD去除率可达到80%,阴极室COD去除率高于阳极室。 相似文献
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膨润土复合无机高分子絮凝剂的制备及其在淀粉废水处理中的应用 总被引：2，自引：0，他引：2
以天然无机高分子材料膨润土为原料,应用化学改性方法,制备了膨润土复合无机高分子絮凝剂和自配膨润土复合无机高分子絮凝剂,并将其应用于淀汾废水处理,取得了较好效果,处理后的淀粉废水清澈透明,由实验可以得出结论淀粉废水中悬浮物COD的去除,受溶液的pH值影响较明,pH值越低效果越好. 相似文献
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INTRODUCTION Coking wastewater is generated in the produc- tion of coke, coal gas, tar and other coke by-products The coking wastewater includes inorganic pollutants such as ammonia, cyanogen, sulfocyan, heterocycle compounds and polycyclic aromatic compounds such as phenol, oils, naphthalene, pyridine, quinoline and anthracites, which are difficult to biodegradation under aerobic conditions (Ganczarczyk, 1972). Dis- charge of coking wastewater to the environment may cause severe contamin… 相似文献