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1.
吉世Yu 《昆明师范高等专科学校学报》2001,23(4):77-78
通过对温度从300K到2500K范围内，作为热发射体常用基底金属W的导热系数的实验结果进行分析，得到了W的导热系数随温度变化的经验公式，为W作为基底的发射材料的热学研究提供了依据。 相似文献
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在293K～313K温度范围内测定了Er(ClO4)3在DMF溶剂中的电导率,根据λ=(K液-K剂)×10-3/c公式求得Er(ClO4)3的摩尔电导率λ值,应用Kohlraush经验规则:λ=λ0(1-βc),使用Origin软件进行线性拟合,作图外推求得Er(ClO4)3在DMF溶剂中的无限稀释摩尔电导率λ0值,讨论了Er(ClO4)3在DMF溶剂中的无限稀释摩尔电导率与温度的关系 相似文献
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电导法测定醋酸在H2O和THF混合溶剂中的活度系数 总被引：1，自引：0，他引：1
用电导法测定了醋酸在不同温度时和不同浓度下在H2O和THF混合溶剂中的电导丰，应用Debye-Hucker和OsagerFalkenhangen公式计算了醋酸在混合溶剂中的活度系数。并讨论了温度和浓度对电解质活度系数的影响。结果表明。电解质溶液的活度系数随着温度的增加而增大，随着浓度的增加而减小。 相似文献
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Te对Bi0.85Sb0.15低温热电性能的影响 总被引：1，自引：0，他引：1
宋春梅 《遵义师范学院学报》2007,9(4):57-59
采用机械合金化法在553K、6Gp下压制30分钟获得Bi_(0.85)Sb_(0.15) x%Te(其中,x=0.1、0.2、0.5、1和2)的纳米晶热电材料,并对Bi_(0.85)Sb_(0.15) x%Te材料的热电性能进行了研究。通过对样品的X-ray衍射实验分析,证实已形成了单相合金。在80-300K温区测量了样品的Seebeck系数、热导率和电导率,并计算出材料的优质参数。结果表明:Bi_(0.85)Sb_(0.15) x%Te材料在80-300K温区表现出金属特征。Bi_(0.85)Sb_(0.15) 0.1%Te样品的电导率要比Bi_(0.85)Sb_(0.15)样品电导率高2-3倍,而Seebeck系数绝对值比Bi_(0.85)Sb_(1.15)样品减少了近80%。表明掺入Te可以提高Bi_(0.85)Sb_(0.15)纳米晶粉末材料的电导率。 相似文献
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Different responses of two Mosla species to potassium limitation in relation to acid rain deposition
Meng WANG Bao-jing GU Ying GE Zhen LIU De-an JIANG Scott X. CHANG Jie CHANG 《Journal of Zhejiang University. Science. B》2009,10(8)
The increasingly serious problem of acid rain is leading to increased potassium (K) loss from soils, and in our field investigation, we found that even congenerically relative Mosla species show different tolerance to K-deficiency. A hydroponic study was conducted on the growth of two Mosla species and their morphological, physiological and stoichiometric traits in response to limited (0.35 mmol K/L), normal (3.25 mmol K/L) and excessive (6.50 mmol K/L) K concentrations. Mosla hang-chowensis is an endangered plant, whereas Mosla dianthera a widespread weed. In the case of M. hangchowensis, in comparison with normal K concentration, K-limitation induced a significant reduction in net photosynthetic rate (Pn), soluble protein content, and superoxide dismutase (SOD) activity, but an increase in malondialdehyde (MDA) concentration. However, leaf mass ratio (LMR) and root mass ratio (RMR) were changed little by K-limitation. In contrast, for M. dianthera, K-limitation had little effect on Pn, soluble protein content, SOD activity, and MDA concentration, but increased LMR and RMR. Critical values of N (nitrogen):K and K:P (phosphorus) ratios in the shoots indicated that limitation in acquiring K occurred under K-limited conditions for M. hangchowensis but not for M. dianthera. We found that low K content in natural habitats was a restrictive factor in the growth and distribution of M. hangchowensis, and soil K-deficiency caused by acid rain worsened the situation of M. hangchowensis, while M. dianthera could well acclimate to the increasing K-deficiency. We suggest that controlling the acid rain and applying K fertilizers may be an effective way to rescue the endangered M. hangchowensis. 相似文献
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This study deals with the effect of hydrotropes on the solubility and mass transfer coefficient of salicylic acid. The solubility and mass transfer studies were performed using the hydrotropes, i.e., sodium acetate, sodium salicylate, citric acid, and urea at concentrations of 0-3.0 mol/L and system temperatures of 303-333 K. It was found that the solubility and mass transfer coefficient of salicylic acid increases with increase in hydrotrope concentration and also with system temperature. All hydrotropes used in this work showed an enhancement in solubility and mass transfer coefficient to different degrees. The maximum enhancement factor values were determined for all hydrotropes used in this study. The highest value was 28.08 for solubility studies and 10.42 for mass transfer studies. The performance of hydrotropes was measured in terms of the Setschenow constant （Ks）. The highest value observed was 0.696. 相似文献
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The solubilities of 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate in sulfuric acid solutions were measured at temperatures ranging from 278.15 to 338.15 K by using a dynamic method. The concentration of sulfuric acid solution ranged from 0 to 80wt%,. The solubilities of 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate increased with temperature, and both of them were the lowest at 70wt %, of sulfuric acid solution(w~0_3 =0.70)while the highest in pure water. The solubility data were correlated by the modified Apelblat equation. Based on the solubility difference between 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate, a new technique in which sodium sulfate was used to replace sodium sulfite in the neutralization reaction was developed. The suitable mole ratio of H_2O to Na_2SO_4 in the neutralization reaction was 80∶1, and that of 2-naphthalenesulfonic acid monohydrate to Na_2SO_4 was 3.2∶1. The material balance under the suitable mole ratios was given and discussed. 相似文献
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以纤维状的碱式碳酸铵铝(AACH)和硼酸为原料,在150℃左右发生低热固相反应,得到铝氧骨架上含有部分硼酸基团的纤维状中间体,接着在助熔剂硫酸钾的存在下将中间体在1100℃焙烧4h,得到反应混合物,用热水洗去该混合物中的可溶性助熔剂,烘干后得到产物。经XRD及SEM表征,证实该产物为直径分布均匀的硼酸铝晶须,晶须的平均直径为0．3um长度平均为15um．鉴于AACH在较低温度分解得到活性氧化铝时还保持着纤维状的形状以及这一温度硼酸基已接到铝氧骨架上的事实,初步提出了原位诱导合成硼酸铝晶须的生长机理。 相似文献
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Different responses of two Mosla species to potassium limitation in relation to acid rain deposition
Meng Wang Bao-jing Gu Ying Ge Zhen Liu De-an Jiang Scott X. Chang Jie Chang 《Journal of Zhejiang University. Science. B》2009,10(8):563-571
The increasingly serious problem of acid rain is leading to increased potassium (K) loss from soils, and in our field investigation,
we found that even congenerically relative Mosla species show different tolerance to K-deficiency. A hydroponic study was conducted on the growth of two Mosla species and their morphological, physiological and stoichiometric traits in response to limited (0.35 mmol K/L), normal (3.25
mmol K/L) and excessive (6.50 mmol K/L) K concentrations. Mosla hangchowensis is an endangered plant, whereas Mosla dianthera a widespread weed. In the case of M. hangchowensis, in comparison with normal K concentration, K-limitation induced a significant reduction in net photosynthetic rate (P
n), soluble protein content, and superoxide dismutase (SOD) activity, but an increase in malondialdehyde (MDA) concentration.
However, leaf mass ratio (LMR) and root mass ratio (RMR) were changed little by K-limitation. In contrast, for M. dianthera, K-limitation had little effect on P
n, soluble protein content, SOD activity, and MDA concentration, but increased LMR and RMR. Critical values of N (nitrogen):
K and K:P (phosphorus) ratios in the shoots indicated that limitation in acquiring K occurred under K-limited conditions for
M. hangchowensis but not for M. dianthera. We found that low K content in natural habitats was a restrictive factor in the growth and distribution of M. hangchowensis, and soil K-deficiency caused by acid rain worsened the situation of M. hangchowensis, while M. dianthera could well acclimate to the increasing K-deficiency. We suggest that controlling the acid rain and applying K fertilizers
may be an effective way to rescue the endangered M. hangchowensis.
Project supported by the National Natural Science Foundation of China (No. 30570113) and the Research Fund for the Doctoral
Program of Higher Education (No. 20060335008), China 相似文献
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利用溶胶凝胶法在单晶LaAlO3（100）衬底上成功的制备了La0.7Pb0.3MnO3外延膜.用X射线衍射仪、直流四探针法对其结构及电特性进行了研究.结果表明,薄膜为赝立方钙钛矿结构,晶胞参数为a=3.907nm.电阻率随着温度的增加,从金属导电行为向半导体行为转变,转变温度为TP=336K,利用双交换理论对此现象作了合理的解释.其电阻率在低温区时满足ρ=ρ0＋ρ1T2＋ρ2T4.5,其导电机制主要是电子与电子的散射,在T〉TMI时主要是小极化子输运. 相似文献
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Non-dispersive solvent extraction (NDSE) with p-xylene as extractant was employed as a novel separation method to recover both p-toluic (PT) acid and water from purified terephthalic acid (PTA) wastewater. The mass transport behavior of PT acid from aqueous solution to p-xylene was investigated by experiments and numerical simulation. Experiments showed that NDSE is feasible and effective. Residual PT acid in the raffinate can be reduced to lower than the permitted limit of wastewater re-use (100 g/m3) with extraction time longer than 60 s in industrial conditions. A mathematical model of PT acid mass transport was developed to optimize the membrane module performance. The model was validated with the experimental results with relative errors of less than 6%. Numerical analysis for mass transfer through the lumen side, the porous membrane layer, and the shell side showed that PT acid transport in the aqueous solution is the rate determining step. The effects of the membrane and operating parameters on membrane module performance were investigated by means of computational simulations. The key parameters suggested for industrial NDSE design are: fiber inner radius r1=200–250 µm, extraction time te=50–60 s, aqueous/organic volumetric ratio a/o=9.0, and temperature T=318 K. 相似文献
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The combined characterizations of mobility and phonon scattering spectra allow us to probe hole transport process in epitaxial PbSe crystalline films grown by molecular beam epitaxy （MBE）. The measurements of Hall effect show p-type conductivity of PbSe epitaxial films. At 295 K, the PbSe samples display hole concentrations of （5-8）× 10^17 cm^-3 with mobilities of about 300 cm^2/（V·s）, and at 77 K the hole mobility is as high as 3×10^3 cm^2/（V·s）. Five scattering mechanisms limiting hole mobilities are theoretically analyzed. The calculations and Raman scattering measurements show that, in the temperatures between 200 and 295 K, the scattering of polar optical phonon modes dominates the impact on the observed hole mobility in the epitaxial PbSe films. Raman spectra characterization observed strong optical phonon scatterings at high temperature in the PbSe epitaxial films, which is consistent with the result of the measured hole mobility. 相似文献
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* In recentyears, the solvent-based absorption sys-tem[1], in which di-n-butyl phthalate(DBP) is usedas the solvent recovering maleic anhydride, is beingdeveloped in China. The organic solvent (di-n-butylphthalate) needs to be washed by water to recycle it-self in the process of recovering maleic anhydride[2].This is a back extraction process involved in the pro-duction of maleic anhydride. The extraction efficiencydepends on the distribution coefficients of the organicsolutes,o-phthalic aci… 相似文献
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Kinetics of esterification of 2-keto-L-gulonic acid with methanol catalyzed by cation exchange resin
The kinetics of esterification of 2-keto-L-gulonic acid with methanol in the liquid phase catalyzed by cation exchange resin, D001, was studied. The experiments were carried out in a stirred batch reactor at 318, 323, 328, 333, 338, 341 K under atmospheric pressure, It is found that the speed of rotating rate has no effect on the esterification rate in the range of 300-500 r/min and the effect of internal mass transfer resistance is not obvious. The effects of temperature and catalyst loading on the reaction rate were researched under the condition of eliminating the effect of diffusion. The rate was found to increase with the increase of the temperature and catalyst loading. The experimental data were correlated with a kinetic model based on the pseudo- homogeneous catalysis, The kinetic equation for describing the reaction catalyzed by cation exchange resin was developed, The experimental data are in good agreement with the model 相似文献
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在0℃和10℃的低温胁迫条件下,研究了白三叶草SOD的活性P、OD的活性、电导率和MDA的含量。研究结果表明：随着胁迫温度的降低,SOD的活性P、OD的活性、电导率和丙二醛的含量都表现出了明显增加的趋势,表明白三叶草具有较强的抗寒能力。 相似文献
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We report physicochemical characteristics of various kinds of liquid milk commercially available in Pakistan in comparison with those of fresh natural milk from animals. Milk samples were collected from local markets at Peshawar, Pakistan,and analyzed for their physical features, including moisture, total solids, specific gravity, conductivity, viscosity and titratable acidity (lactic acid equivalent), and chemical components and macro-minerals, including total protein, casein, lactose, ash and minerals (Na, K and Mg). These items were compared with the physicochemical characteristics of the fresh natural milk samples from buffalo, cow and goat. The results were also compared with reported nutritional quality of milk from various countries and World Health Organization (WHO) standards. We found that all the physical features and chemical components of commercially available milk in Pakistan markets meet WHO's requirements, except for Na, K, Ca and Mg, which are below the standards. 相似文献