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1.
The aim of this paper is to study the influence of atmospheric humidity and temperature on the mural paintings in the Mogao Grottoes of Dunhuang by measuring the weight of a simulated mural block. Under open conditions, the daily changes in the atmospheric humidity and temperature have an apparent effect on the water content of these murals. There exists an obvious water exchange between atmosphere and mural, that is, there is a ±43?g?m?2 moisture absorption–desorption ‘breathing’ process between the two. Evapotranspiration from the tree-belt, precipitation, and extremely dry weather also have an effect on the moisture associated with a mural painting. If the cave is closed, a comparable study finds that closure can make the effects of temperature and humidity changes disappear. The mural water content in this case remains stable and the harm due to water-salt deterioration is greatly reduced. Under closed conditions, artificial condensation dehumidification and control of the cave's temperature and humidity stabilizes water activity in the mural paintings very effectively. This is a clear indication of the future steps required to protect the cave's cultural relics.  相似文献   

2.
《文物保护研究》2013,58(2):88-94
Abstract

This paper examines the impact of relative humidity on jades by enclosing the samples under constant relative humidity (RH) of 32, 49, 61.5, and 81.7% at the same temperature of 40 ± 0.1°C for 160 days. The simulated samples were pure and dense tremolite jade and serpentine jade, impure tremolite jade and serpentine jade containing some calcite, and serpentinized calcite, which are all common materials of ancient jade found in archaeological excavations. All samples were characterized through particle-induced X-ray emission and a glossmeter. The degree of deterioration proved to be greater in impure materials than in pure ones. The best RH to conserve various kinds of materials differs: for pure tremolite and serpentine, all of the RH levels are equal; for impure tremolite with some calcite, 61.5 and 81.7% were superior; for impure serpentine with some calcite, the highest RH (81.7%) was best; and as to the serpentinized calcite, there is no clear conclusion as yet and further research is needed.  相似文献   

3.
《文物保护研究》2013,58(1):29-41
Abstract

Chloride-contaminated archaeological iron is unstable and problematic to store and display within museum collections. Reducing its chloride ion content using aqueous desalination followed by storage in controlled relative humidity offers one treatment option. This study reports a quantitative assessment of chloride extraction by aqueous deoxygenated alkaline desalination solutions from 120 individual archaeological iron nails. The three treatment methods comprised alkaline sulphite solution (0.1 M NaOH/0.05 M Na2SO3) at room temperature and at 60°C and sodium hydroxide solution (0.1 M) deoxygenated using a nitrogen gas positive pressure system at room temperature. Chloride extraction was monitored using a specific ion meter. The nails were digested after treatment to measure their residual chloride content. A wide range of extraction patterns emerged, with the majority of individual treatments extracting 60–99% of the chloride present. Residual chloride levels for 87% of the objects fell below 1000 ppm and 42% were below 200 ppm. Although no treatment extracted 100% of the chloride in the object, alkaline desalination produced very significant reductions in chloride content. The impact of this on future corrosion of the objects is discussed. This quantitative and statistically viable assessment of deoxygenated desalination treatments provides evidence to support their use in conservation practice, which will impact on procedures for the preservation and management of archaeological heritage.  相似文献   

4.
ABSTRACT

Glass is often seen as a relatively stable material, unaffected by changes in environmental conditions, but recent studies indicate otherwise. Research on the atmospheric deterioration of glass has consistently shown a strong correlation between climate, especially relative humidity (RH), and the rate of deterioration. New studies by the authors have shown that even stable compositions are at risk, when the glasses are exposed to continuous broad fluctuations in RH and temperature. Letting standards slip for the long-term storage of glass can be devastating, eventually leading to irreversible damage that in the final stages can result in the complete destruction of an object. Current research and monitoring of collections at the Corning Museum of Glass indicates that the RH should be within the range of 40–50%. For already crizzled glasses, a tighter control to 40–42% is recommended. Analysis of compositions of already crizzled glasses is ongoing, and hopefully will lead to the identification of at least some groups of glasses that are more at risk. This will help in providing future environmental recommendations for identifiable compositions, selected glass types, or known manufacturers.  相似文献   

5.
Acid-detector (A-D) strips were originally developed to assess the deterioration of acetate film stock, but they can also be used more generally within enclosures to detect volatile acidic pollution. A hand-held reflectance spectrophotometer was used to record the colour of individual strips in order to make consistent and reproducible readings. Calibration was carried out using the yellow-blue axis b*(D65) value in the CIELAB1976 system to measure the colour of A-D strips suspended in enclosed containers over solutions of acetic acid in combinations with glycerol to control the relative humidity (RH). A-D strips were found to be sensitive to changes in high RH (60–90%) but affected little by changes in lower RH or temperatures in the museum display and storage range. A-D strips can be used to establish the presence of volatile acids, record the indication of acid vapour concentration, explore conditions within a container, and to find sources of volatile acidity. They respond very quickly and several can be placed around an object. They therefore show promise for measuring slowly changing conditions, such as seasonal changes and the gradual accumulation of acidity in poorly ventilated containers and spaces. A-D strips proved useful in assessing air quality in storage and display enclosures. Examples and test results are presented. Well-sealed plywood transit frames and storage cases were found to be most polluted with volatile acids. Storage rooms with air filtration systems but filled with wooden objects had significantly reduced air quality.  相似文献   

6.
《文物保护研究》2013,58(2):65-79
Abstract

Environmental standards for cultural heritage collections have been much debated in recent years. The interest in the issue has been driven by the growing movement towards green museums, that is, managing indoor museum environments in a responsible and efficient manner, especially in terms of reducing energy consumption and carbon emissions but at the same time maintaining high standards of collection care. Painted wood is among the category of heritage objects most vulnerable to relative humidity and temperature fluctuations. Therefore, scientific understanding of how changes in environmental conditions ultimately affect painted wood is crucial to the development of rational guidelines for the control of climate in museums and historic buildings. This review provides a systematic progression through two fundamental approaches to establish the allowable ranges of climatic variations – an analysis of the mechanical response of painted wood as a complex, multilayer system to climate variations, and an analysis of the historic climate to which the objects have acclimatized. The climate specifications and standards based on both these approaches are reviewed.  相似文献   

7.
Air pollution is one of the environmental influences that degrade cultural heritage objects situated indoors. Other essential influences, such as temperature, relative humidity, and light are often well monitored. The presence of air pollutants is less often measured or included in risk assessment. The MEMORI® technology presented in this paper was developed as a tool for easy measurement and assessment of the general risk of degradation of heritage objects situated indoors due to indoor exposure to air pollutants. MEMORI dosimetry was performed in locations belonging to English Heritage and Tate (both located in London) and the National Archives of Norway in Oslo, to assess air quality. The related damage risk for collection objects and the protection offered by display and storage designs was assessed. A high level of acidic effect was observed inside a number of showcases, and a high level of oxidizing effect was observed in some room locations. Relatively simple mitigation measures, such as constructing tightly sealed showcases using low emitting materials, installing active carbon absorbing media inside a ‘microclimate’ frame, and using cardboard storage boxes for paper, significantly improved air quality. Overall, implementation of such measures is likely to improve the preservation of objects and reduce conservation costs.  相似文献   

8.
ABSTRACT

The National Museum of Ethnology, Osaka, Japan, collects a vast amount of materials and information related to peoples’ life and culture, and makes them available to society through exhibitions and other activities. The number of collected items is increasing every year: 343581 objects have been collected from Japan and abroad as of March 2017. The continuous efforts have been necessary to improve storage conditions and to save space for both general and special storerooms. The former, which account for 90% of the storage capacity of the museum, are air-conditioned during working hours, with temperature and relative humidity (RH) settings varying with the seasons. The latter, which house objects for which strict conservation conditions are required, are air-conditioned for 24 hours with fixed settings of temperature/RH throughout the year determined by the nature of the materials from which the objects have been made or formed. Storage re-organization began with special storerooms, for which the number of objects and the storage area are far more limited in comparison with the general storerooms. The storage shelves for fur/skin/feather (almost 1000 objects) and for carpets (almost 550 objects) were all renewed in FY2007/2008. Then two large-scale innovation projects for general storerooms were conducted: construction of storage areas for ships equipped with a CO2-based and anoxic pest treatment facility (FY2015), and a complete refurbishing of the general storeroom for large objects (FY2016). Windows were set in the corner of this storeroom to provide visitors an opportunity to view and learn about the museum activities. In parallel to the above projects, daily storage improvement efforts have been undertaken. Storeroom No. 3, chosen as an example for general storerooms for small and medium-sized objects, was used to investigate the range of issues related to the shelving arrangement and storage conditions. Guidelines for storage re-organization were formulated according to the results of the investigation and according to the experiences gained through the renewal of special storerooms. Storage re-organization undertaken in storeroom No. 3 was conducted for 6 years at the rate of around 2000–4000 objects per year with a low budget and with reuse of existing shelves. In FY2016, all objects in storeroom No. 3 were properly redistributed. About 40% of the storage space was saved. Over these 10 years of storage re-organization, preventive measures have been taken for sustainable collection management. As early as FY1992, pest trap investigations have been carried out seasonally. Since FY2004, the results of investigations have been analyzed using a customized computer program. Subsequently, appropriate integrated pest management measures have been taken. In addition, since FY2014, energy-efficient air-condition control has been adopted for general storerooms. It consists of switching off air-conditioning in spring and autumn, and of starting it only when the temperature or RH values become too high in summer or too low in winter. Because the turning-off of air-conditioning causes comparable or even less climatic fluctuation, it was considered acceptable both economically and from a conservation perspective. It is estimated that turning the air-conditioning off during transitional seasons brings cost savings of about 3000000–4000000 JPY (about 26800–35700 USD as of 23 September 2017) per annum, which accounts for almost 30% of the electricity expenditures for all general storerooms.  相似文献   

9.
ABSTRACT

This work considers areas where our present lack of knowledge curtails the effectiveness or efficiency of preventive conservation practice. Mixed media, especially archaeological metals and organics have incompatible requirements for relative humidity (RH). An approach based on understanding the risk versus RH for both materials and considering the showcase performance is elucidated as a solution. Pollution, both the mixed atmospheres around most cultural heritage and the complex, variable nature of deposited particles, are further areas in need of more research. Damage functions and measurement of object deterioration rates are investigated as a path forward, and examples are given.  相似文献   

10.
ABSTRACT

The impact of relative humidity (RH) and temperature variation on the mechanical behaviour of paintings on canvas was investigated, based on the various environmental recommendations that are applied by museums and institutions worldwide. Paint samples were constructed based on the works of twentieth-century artists such as Soulages and Riopelle. The various samples are based on criteria such as paint media, additives, pigment type, canvas type, thickness, type of application, and drying time. Once they are fully dry, paint films behave as elastic, viscoelastic, or viscoplastic materials depending on the chemical nature of their components. These properties, as well as tensile strength, were determined by a series of tensile tests. Other samples were included, originating from discarded oil paintings on canvas from the seventeenth and nineteenth centuries. To carry out mechanical tests under controlled conditions of temperature and RH, a climatic chamber was built around the column of a universal testing machine. Samples were submitted to stress relaxation tests to observe their response to changes in environmental conditions. RH was increased from 20 to 90% and temperature from 15 to 60°C. Reactivity diagrams were drawn based on the results. The endurance limit under mechanical fatigue was determined from the diagrams and helped define the risks associated with each painting type when exposed to the accepted environmental recommendations.  相似文献   

11.
ABSTRACT

Historic buildings in Denmark have a high relative humidity (RH) all year, so the interiors are exposed to biological degradation. The acceptable range for RH is 60–70%, which is higher than the usual recommendations for museums and galleries. There are two options for humidity control: conservation heating or mechanical dehumidification. Calculation of the energy performance of a generic building was used to determine which method is the most efficient. Studies of a cottage in Liselund Park, and of two medieval churches in Hellerup and Vemb have confirmed these predictions: dehumidification is less energy consuming than conservation heating in buildings with poor thermal insulation and a moderate air infiltration rate (AER?<?0.6?h?1). Dehumidification is suitable for historic buildings, where heating is not needed for human comfort. A condensing dehumidifier uses less than half the energy per kg water compared to an absorption dehumidifier. But it does not work at temperatures below 2°C. The combination of a condensing dehumidifier and a little heating to prevent frost is the most energy efficient solution for humidity control. These results are only valid in mild and humid climatic conditions similar to Denmark.  相似文献   

12.
《文物保护研究》2013,58(3):201-210
Abstract

Thirty artists' colors have been exposed for 12weeks to 120ppb of formaldehyde in purified air as well as to purified air alone (control experiment). The exposure was carried out in the dark at ambient temperature (19 ± 2°C) and humidity (RH 44–52%). Color change (?E) was measured using a reflectance color analyzer after one, two, three, four, six, eight, 11 and 12 weeks of exposure. Color parameters (x, y, X, Y, Z, L*, a*, b* and ?E)"were also calculated from the 380–700nm spectra, recorded with a reflectance spectrophotometer, of unexposed colorants and of colorants exposed for 12 weeks to purified air and to formaldehyde. Regression analysis of the two data sets indicated that the color changes measured by these two methods were in excellent agreement (nearunity slopes, with correlation coefficients > 0.99). Exposure to either formaldehyde or pure air on watercolor paper resulted in little or no color change for all the colorants tested, including inorganic colorants, alizarin lakes, quinacridones, triphenyl methanes, indigo derivatives, arylamides and natural colorants such as curcumin. Formaldehyde, which is ubiquitous in indoor air, including museum air, does not appear to be a major threat to colorants in museum collections.  相似文献   

13.
In this work, experimental results on the influence of high temperature and relative air humidity on the aging dynamics of recordable DVDs of the R+ and R? formats of the most well-known trademarks (Sony, TDK, Imation, Digitex, Mirex, Verbatim, Philips, Fujifilm) are presented. The state of disks and recorded information is estimated qualitatively and quantitatively by computer testing using special software. Relative longevity is calculated using results on the artificial aging of compact disc specimens in harsh conditions (a temperature of + 80°C, a relative air humidity of 85%), the “stability series” of DVD±R discs of different trademarks is established. Recommendations on the practical application of DVD discs of R+ and R? formats of particular trademarks for durable storage of scientific-technical information are given on the basis of the obtained data.  相似文献   

14.
《文物保护研究》2013,58(3):161-171
Abstract

Four iron meteorite fragments and 13 archaeological iron objects were exposed to a lowpressure hydrogen plasma for up to two weeks in a pilot apparatus. In the experiment the objects acted as cathodes in a 600–1600V d.c. electrical field. While the chlorine-containing β-FeOOH, akaganeite, was present in all objects before the test, no akaganeite and no chlorides were present afterwards. The objects, including one meteorite which had been exposed for more than 5000 years to seawater, were found to be stable after the glow discharge treatment. The major mineral after treatment was identified as magnetite, and the objects generally assumed an iron-grey surface colour. No sputtering and no reduction to free iron took place under the test conditions, operating at or below 120°C and at pressures of O·4–1mb hydrogen.  相似文献   

15.
《文物保护研究》2013,58(1):13-22
Abstract

Insect pests are an important source of concern in historic houses as the larval stages in particular can feed on a variety of important heritage materials, causing significant and sometimes irreparable damage to collections. Damage to wood and textiles is a special problem. The lifecycles of insects are sensitive to climate and require relatively warm conditions. There has been a significant increase in the presence of insect pests within historic houses in the early twenty-first century. The reasons may include: warmer winters, widespread use of natural fibres, less potent insecticides, and occupation of new niches indoors. The interior climate, especially increasing warmth, offers the potential for greater insect growth and survivability. Modelling changes in the temperature and humidity within the Cartoon Gallery at Knole, southern England, for the period 1770–2100 suggests a dramatic increase in favourable temperature conditions through the current century.  相似文献   

16.
ABSTRACT

Many museums are housed in historic buildings, sometimes the building itself is part of the museum collection. Creating a stable environment by providing a nearly constant temperature and relative humidity at correct levels decreases the risk of object degradation. Maintaining this steady indoor environment, however, increases energy consumption and risks to the historic building. Museum display cases offer a solution to the mitigation of risks to which valuable objects may be subjected by providing an extra layer of protection to indoor climate fluctuations. The Anne Frank House is a historic house museum located in Amsterdam. The museum has undergone several renovations in the last years to deal with an increase in the number of visitors to over 1.2 million a year. The original diaries and other documents of Anne Frank are permanently on display in the Anne Frank House. With the recent refurbishment the possibility arose to design a new state-of-the-art display case. This study presents the results of the experimental research related to the design, performed in-situ. The temperature and relative humidity in the new exhibition space and inside the new display cases were monitored to gain insight into the hygrothermal behavior of these controlled environments. A complementary numerical study was performed to investigate effects of dynamic climate control of the exhibition gallery and climate conditions in the display case under various circumstances. Four main conclusions are presented in this paper. The investigated display case design is able to provide a stable relative humidity environment by means of silica gel, while using an active box-in-box climate control system to create stable temperature conditions. The inner case temperature depends on the temperature supplied by the display case air handling unit. Protocols must be in place in case of malfunction or failure of the climate control system of the display case. The air handling unit of the case needs to be shut off to create a passive environment for the objects on display until necessary actions are taken. Exhibition gallery set points can be less stringent when susceptible museum objects are on display in the display case. The environments are separated and provide an opportunity for energy saving set point strategies. The last conclusion drawn is that the numerical study provides valuable insight into imposing dynamic control of set points for temperature and relative humidity in the exhibition gallery and the effect on the display case environment.  相似文献   

17.
《文物保护研究》2013,58(4):251-268
Abstract

Extensive investigations of the deterioration of the romanesque painted wooden ceiling in the church of Saint Martin in Zillis (Switzerland) have revealed three major active deterioration phenomena: (1) tented flaking of paint layers; (2) flaking of the wheat starch fixative together with parts of the paint layer; and (3) fungal growth. These deterioration processes correlate with the dynamics of the prevailing room climate. Both forms of flaking are mainly driven by fluctuations of the relative humidity (RH), whereas the fungal attack can be related to high average RH and stagnant air. Frequent daily fluctuations in RH of up to 20% in summer are due to visitors leaving the doors open, while fluctuations of up to 25% are related to heating in winter. Given the risks of new consolidation treatments, the aim is to slow the decay processes by influencing the climate in the room. Installation of automatic door-closers reduced fluctuations but led to a rise in RH and a reduction of air movement, causing greater fungal growth. Subsequently, an automatic air-exchange system triggered by absolute humidity values was installed to reduce excess humidity and to exchange stale air without producing major fluctuations in the relative humidity. This kind of 'climatisation' has the advantage of being highly flexible, allowing variation of the rate and scale of exchange; it is, moreover, truly reversible.  相似文献   

18.
A study was conducted to investigate white bloom found on more than 130 polyvinyl chloride (PVC) dolls from the 1980s and 1990s produced by the Danish factory Dan Hill Plast A/S. The bloom was discovered on the dolls after 10 years of storage in a climate controlled facility with average temperature at 11–12°C and a relative humidity at 50?±?5%. Analysis of the dolls and the bloom was carried out using Fourier transform infrared spectroscopy, which revealed that the bloom consisted primarily of stearyl alcohol. Subsequent analysis with gas chromatography–mass spectrometry showed a minor presence of cetyl alcohol. It is proposed that the alcohol had been added as a lubricant to aid flow during processing. The stearyl alcohol was almost completely reabsorbed into the PVC dolls following one month storage at room temperature, suggesting that low temperature storage played a decisive role in the appearance of the bloom. It is likely that a decrease in temperature has led to a decrease in compatibility of the stearyl alcohol in the PVC compound, thus promoting its exudation. This paper also discusses an extreme bloom of white crystals on other PVC dolls of unknown provenance.  相似文献   

19.
It has often been observed anecdotally and implied through experimentation that acrylic emulsion paintings accumulate and entrain soils over time due to the inherent mechanical softness in artist's acrylic paint films, through the presence of hydrophilic film components, and by virtue of the ubiquitous presence of surfactant moieties on these film surfaces once they dry. In the present study, it has been this last effect that we have sought to describe more fully in terms of surfactant responsiveness to both temperature and relative humidity (RH). Surfactant hydration and dehydration under varying temperature and RH conditions affects the ultimate partitioning of the surfactant at the paint–air interface, as well as the inherent size, aggregation tendencies, and solubility of surfactant in the bulk paint materials which contain components that are highly responsive to changes in temperature and RH (e.g. polyacrylic or polymaleic anhydride-type dispersal materials). In this work, analytical techniques including three-dimensional microscopy and quartz crystal microbalance with dissipation were used to add to and reinforce current understanding of the physical and mechanical changes to acrylic paint films with temperature and RH. The migration of surfactant at the film surface was studied using desorption electrospray ionization-mass spectrometry and attenuated total reflectance Fourier transform infrared microscopy.  相似文献   

20.
［目的/意义］ 面向文化遗产领域的知识分析研究,对领域知识建模、知识组织、智慧数据资源建设等具有重要意义。［方法/过程］ 为明确文化遗产领域知识结构与特征,基于对领域本体的计算与分析,系统剖析文化遗产领域核心共享概念以及领域知识关联关系,提出并构建文化遗产领域知识纲要。［结果/结论］ 文化遗产领域核心共享概念包括领域对象与实体、类型与概念、时间与空间、事件与活动、文献与作品、代理者等内容,领域知识关联关系丰富多样且较为复杂。研究结论有助于更全面地理解与认识文化遗产领域知识体系,指导领域本体开发与知识建模,促进领域知识的有效组织与管理。  相似文献   

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