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The new intermetallic compound La3Cu3Bi4 was synthesized by arc melting method followed by annealing.The crystal structure refined using the Rietveld method and X-ray powder diffraction data showed to be Y3Au3Sb4 structure type with space group I43D(No.220).The unit cell parameters were a = 0.997 797(7) nm and V = 0.993 41(2) nm3.The structure was characterized by covalent Cu-Bi4 tetrahedron, which formed three-dimensional network by sharing corners and La atoms separated in the space of Cu-Bi4 tetragon.The expansion of La3Cu3Bi4 studied by using low temperature X-ray di?raction showed to be positive expansion and diminished with the temperature rising.  相似文献   
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Systematic studies of the transport properties of La0.67Ca0.33Mn1-xFexO3 (x=0-0.3) systems showed that with increasing Fe-doping content x the resistance increases and the insulator-metal transition temperature moves to lower temperature. For small doping content, the transport property satisfies metal transport behavior below the transition temperature, and above the transition temperature it satisfies the small polaron model. This behavior can be explained by Fe3 doping, which easily forms Fe3 -O2--Mn4 channel, suppressing the double exchange Mn3 -O2--Mn4 channel and enhancing the spin scattering of Mn ions induced by antiferromagnetic clusters of Fe ions.  相似文献   
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研究了湿法合成ZnO陶瓷样品的结构及缺陷对材料电性能的影响。结果表明,湿法合成的ZnO材料是由主晶相ZnO、尖晶石相和富Bi液相组成的。随着烧结温度的提高,材料中出现了微空洞型缺陷。通过SEM、XRD结构分析和对材料电性能的测试,给出了阈值电压E0、非线性系数。的变化特点,并定性地讨论了材料的结构和缺陷对阈值电压、非线性系数的影响。  相似文献   
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1IntroductionIt is well known that the solubility of carbon in Fefor both body-centered-cubic (bcc) and face-centered-cubic (fcc) structures is very low, even in a liquidstate. The maxi mum solubility of carbon in ferrite isonly about 0 .1 atompercent .The difference of atomicradius between Fe and C is so large that C is em-bedded at the interstitial site in the bcc or fcc Fe lat-tice . Hume-Rothery rules suggest that the atomic sizeof the solute and solvent should differ by less than15 %to…  相似文献   
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The new intermetallic compound La3Cu3Bi4 was synthesized by arc melting method followed by annealing. The crystal structure refined using the Rietveld method and X-ray powder diffraction data showed to be Y3Au3Sb4 structure type with space group I-^43D (No.220). The unit cell parameters were a = 0.997 797(7) nm and V = 0.993 41(2) nm^3. The structure was characterized by covalent Cu-Bi4 tetrahedron, which formed three-dimensional network by sharing corners and La atoms separated in the space of Cu-Bi4 tetragon. The expansion of La3Cu3Bi4 studied by using low temperature X-ray diffraction showed to be positive expansion and diminished with the temperature rising.  相似文献   
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Supersaturated solid solutions Fe1-xCx (0≤x≤0.9 ) of wide composition range have been prepared by mechanical alloying process. Nanocrystalline phase was formed for 0 ≤ x ≤ 0.67 and a large grain phase for 0.75 ≤ x ≤ 0.9. The large fraction of graphite volume puts off formation of nanocrystalline phase for high carbon content. In the large grain phase, magnetization follows simple magnetic dilution, and eoereivity He is mainly due to dissolution of carbon at grain boundaries. In the nanocrystalline phase the alloying effect of carbon is revealed by a distinct reduction of average magnetic moment. The increasing lattice constant with increasing carbon content is observed for x ≤ 0.5, suggesting that the high carbon concentration may enhance diffusion of carbon into the Fe lattice. It shows a discontinuity in the Hc variation with a grain size D of nanocrystalline phase. For small grain D below the critical value, Hc increases with D. For a large grain D, Hc decreases with increasing D. The solubility limit of carbon in a-Fe extended by nanocry- stalline phase formation is discussed.  相似文献   
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Out-of-plane angular dependence of ferromagnetic resonance spectra was measured in sputtered Co/Pt multilayers and analyzed with the Landau-Lifshitz-Gilbert equation. The effective demagnetizing field 4πMeff is found to increase with decreasing tPt and decreasing 1/tco, which can be considered as a result of interplay between the interlayer coupling and a lowdimensional effect. The g factor increases with increasing tpt and decreasing tCo, indicating contribution of spin-polarization of Pt atoms and additional contribution of orbital moment of Co atoms. The in-plane resonance line-width increases with decreasing too and increases with increasing tPt.  相似文献   
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