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INTRODUCTION Chlorinated phenols compounds used widely in industry were intentionally or inadvertently released into environment in large quantities. These chlorin-ated aromatic compounds have strong resistance to physical, chemical and biological treatments and have been listed as a priority pollutant by the U.S. Envi-ronmental Protection Agency (Lin and Tseng, 1999). Wastewater containing chlorophenols has malodor-ous odor, high toxicity, bioaccumulation and car-cinogenic potential. … 相似文献
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采用循环伏安法,在含有0.2mol.L-1苯胺的0.5 mol.L-1的硫酸溶液中,以50mv.s-1的扫描速度,在-0.1~0.9V范围内实现苯胺在碳纳米管-纳米TiO2膜电极上的电化学聚合,得到翠绿色的聚苯胺膜,并用交流阻抗谱对复合膜的电化学性质进行了表征。在该电极上修饰铂,制得铂微粒修饰聚苯胺复合膜电极,研究了其对抗坏血酸的电催化氧化,发现修饰后的电极对抗坏血酸的氧化有很高的催化活性。 相似文献
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金属着色 总被引：2，自引：0，他引：2
景维本 《雁北师范学院学报》1995,(6)
本文剖析了金属着色的一些范例,探讨了浸渍着色与电化着色的着色液的工艺配方,生产过程及生产条件,并讨论了其优缺点和实用价值, 相似文献
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Shi-fang ZHAO Wen-jing DONG Qiao-hong JIANG Fu-ming HE Xiao-xiang WANG Guo-li YANG 《Journal of Zhejiang University. Science. B》2013,14(6):518-525
Objective:The purpose of this study was to investigate the effects of a zinc-substituted nano-hydroxyapatite(Zn-HA) coating,applied by an electrochemical process,on implant osseointegraton in a rabbit model.Methods:A Zn-HA coating or an HA coating was deposited using an electrochemical process.Surface morphology was examined using field-emission scanning electron microscopy.The crystal structure and chemical composition of the coatings were examined using an X-ray diffractometer(XRD) and Fourier transform infrared spectroscopy(FTIR).A total of 78 implants were inserted into femurs and tibias of rabbits.After two,four,and eight weeks,femurs and tibias were retrieved and prepared for histomorphometric evaluation and removal torque(RTQ) tests.Results:Rod-like HA crystals appeared on both implant surfaces.The dimensions of the Zn-HA crystals seemed to be smaller than those of HA.XRD patterns showed that the peaks of both coatings matched well with standard HA patterns.FTIR spectra showed that both coatings consisted of HA crystals.The Zn-HA coating significantly improved the bone area within all threads after four and eight weeks(P<0.05),the bone to implant contact(BIC) at four weeks(P<0.05),and RTQ values after four and eight weeks(P<0.05).Conclusions:The study showed that an electrochemically deposited Zn-HA coating has potential for improving bone integration with an implant surface. 相似文献
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对LaxCe0 .9-x(PrNd) 0 .1 (Ni3 .5 5 Co0 .75 Mn0 .4Al0 .3)合金 (x =0 .4～ 0 .9)在不同温度下( 2 98K～ 333K)的电化学性能进行了系统的研究 .结果表明 ,随着温度由 2 98K升高到 333K ,合金的活化性能得到改善 ;合金的最大放电容量增大 ,并在 313K时达到最大值 (平均提高了 2 2 .9mAh/g) ,而当温度提高到 3 33K时 ,各合金的最大放电容量又大幅度下降 (平均降低了 83 .9mAh/g) ;随着温度的升高 ,合金的高倍率放电性能得到改善 ,但合金的循环稳定性明显降低 (在 1C充放电电流下经2 2 0次充放电循环后的容量保持率平均降低了 4 0 %以上 ) . 相似文献
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Qing WEN Ying WU Li-xin ZHAO Qian SUN Fan-ying KONG 《Journal of Zhejiang University. Science. B》2010,11(2):87-93
A sequential anode-cathode double-chamber microbial fuel cell (MFC), in which the effluent of anode chamber was used as a continuous feed for an aerated cathode chamber, was constructed in this experiment to investigate the performance of brewery wastewater treatment in conjugation with electricity generation. Carbon fiber was used as anode and plain carbon felt with biofilm as cathode. When hydraulic retention time (HRT) was 14.7 h, a relatively high chemical oxygen demand (COD) removal efficiency of 91.7%–95.7% was achieved under long-term stable operation. The MFC displayed an open circuit voltage of 0.434 V and a maximum power density of 830 mW/m3 at an external resistance of 300 ?. To estimate the electrochemical performance of the MFC, electrochemical measurements were carried out and showed that polarization resistance of anode was the major limiting factor in the MFC. Since a high COD removal efficiency was achieved, we conclude that the sequential anode-cathode MFC constructed with bio-cathode in this experiment could provide a new approach for brewery wastewater treatment. 相似文献
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A novel fluidized electrochemical reactor that integrated advanced electrochemical oxidation with activated carbon (AC) fluidization in a single cell was developed to model pollutant p-nitrophenol (PNP) abatement. AC fluidization could enhance COD removal by 22%-30%. In such a combined process, synergetic effects on PNP and COD removal was found, with their removal rate being enhanced by 137.8% and 97.8%, respectively. AC could be electrochemically regenerated and reused, indicating the combined process would be promising for treatment of biorefractory organic pollutants. 相似文献
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A novel fluidized electrochemical reactor that integrated advanced electrochemical oxidation with activated carbon (AC) fluidization in a single cell was developed to model pollutant p-nitrophenol (PNP) abatement. AC fluidization could enhance COD removal by 22%-30%. In such a combined process, synergetic effects on PNP and COD removal was found, with their removal rate being enhanced by 137.8% and 97.8%, respectively. AC could be electrochemically regen erated and reused, indicating the combined process would be promising for treatment of biorefractory organic pollutants. 相似文献
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INTRODUCTIONBinaryskutteruditeshavecubicIm35()hTstructureandthechemicalformofAB3,whereArepresentsametalatomandBrepresentsapnico-genatom.Thereareeightformulaunitspercubicunitcell,inwhichthereareadditionallytwostructuralvoidswiththeradiivariedfrom1.63?forCoP3to2.040?forIrSb3.Thevoidislargeenoughforanalkalineearthorrareearthatomtoinsertintoitandtoformternarycompoundscalledfilledskutterudites.Inthesecompounds,theinsertinglooselyboundatomscanmoveorbouncearoundinsidethevoidsduetotherelative… 相似文献
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