Polarography     

V.?LakshminarayananEmail author 《Resonance》2004,9(9):51-61

J Heyrovsky’s invention of polarography in which a dropping mercury electrode is used in the electrochemical cell revolutionised electroanalysis, study of electrode kinetics and adsorption studies on mercury electrodes. Polarography has also directly contributed to the development of new and innovative ideas in electrochemical techniques, instrumentation and applications  相似文献   

DyCl3-KCl和DyCl3-CaCl2体系相图的热力学优化计算     

姚永香  张继红  马芝森  孟祥珍  孙益民  乔芝郁 《上海大学学报(英文版)》2006,10(6):547-552

1 Introduction Molten salts are considered to be used as fluid tar-gets in the nuclear incineration of transuranic elementswith proto accelerators .The molten salts are also usedas the media in high temperature chemical reprocess-ing of spent nuclear fuel of fast reactors .The phase di-agrams of rare earth metal halides in combination withalkali metal halide systems are of pri me i mportance inapplication. The thermodynamic properties and phase diagramsof the DyCl3-MClnsystems ( M =alkali or…  相似文献   

电化学在中学化学教学中的指导作用     

张心宽  王顺梅 《新乡师范高等专科学校学报》2001,15(2):95-97

运用电化学理论解决了中学化学教学中的一系列疑难问题，阐述了电化学在中学化学教学中的指导作用。  相似文献   

Using a modified argument-driven inquiry to promote elementary school students’ engagement in learning science and argumentation     

Hsiang-Ting Chen  Hsin-Hui Wang  Ying-Yan Lu  Huann-shyang Lin 《International Journal of Science Education》2016,38(2):170-191

This study explored the effects of a modified argument-driven inquiry approach on Grade 4 students’ engagement in learning science and argumentation in Taiwan. The students were recruited as an experimental group (EG, n?=?36) to join a 12-week study, while another 36 Grade 4 students from the same schools were randomly selected to be the comparison group (CG). All participants completed a questionnaire at the beginning and end of this study. In addition, four target students with the highest and the other four students with the lowest pretest engagement in learning science or argumentation to be observed weekly and interviewed following the posttest. Initial results revealed that the EG students’ total engagement in learning science and argumentation and the claim and warrant components were significantly higher than the CG students. In addition, the EG students’ anxiety in learning science significantly decreased during the study; and their posttest total engagement in learning science scores were positively associated with their argumentation scores. Interview and observation results were consistent with the quantitative findings. Instructional implications and research recommendations are discussed.  相似文献   

甲基纤维素修饰电极对H2O2电催化还原的研究     

李业梅  戴月 《郧阳师范高等专科学校学报》2004,24(6):18-20

用甲基纤维素(MC)将过氧化氢酶(Cat)固载于热裂解石墨电极表面,制备了Cat-MC膜修饰电极.甲基纤维素膜中的过氧化氢酶与电极直接传递电子.在pH6.0的磷酸盐缓冲溶液中可得到一对可逆的过氧化氢酶辅基血红素Fe(III)/Fe(II)电对氧化还原峰,式电势为-0.331V(vsSCE).其式电势随溶液的pH值增加而负移且成线性关系,直线斜率为-38.0mV/pH,说明过氧化氢酶的电子传递过程伴随有质子的转移.并研究了过氧化氢酶修饰电极对H2O2的电催化性能.在H2O2一定浓度范围(15.6～110.1μmol/L)内,催化电流与H2O2浓度成线性关系.  相似文献   

5-溴水杨醛甘氨酸修饰碳糊电极测定微量Cu2+的研究     

匡云飞  邹建陵  李薇  杨颖群 《衡阳师范学院学报》2006,27(6):44-46

在pH=9.0 H3BO3-Na2B4O7缓冲体系中,以5-溴水杨醛甘氨酸修饰碳糊电极为工作电极,Cu2 于 120mV(vs.SCE)处产生一灵敏的吸附波,其二阶导数峰电流与Cu2 浓度在4.0×10-9~8.0×10-7mol.dm-3范围内呈良好的线性关系,相关系数为0.9964,检出限为6.0×10-10mol.dm-3(3倍信噪比)。应用该法测定发样中Cu2 的含量,结果令人满意。  相似文献   

纳米碳—PVC膜修饰电极测定镉     

黎江鹏  胡小安  王浩华  罗永刚 《楚雄师范学院学报》2007,22(3):52-54,59

介绍了用纳米碳-PVC膜修饰电极测定痕量镉的新方法。优化了各种试验条件,如支持电解质的选择、pH值的影响、修饰剂的用量、富集电位及时间、扫描速率等。  相似文献   

Clinical detection and movement recognition of neuro signals     

Zhang XW  Yang YP  Xu XM  Hu TP  Gao ZH  Zhang J  Chen TY  Chen ZW 《Journal of Zhejiang University. Science. B》2005,6(4):272-279

INTRODUCTION Human limbs are complex, delicate systems.Their reconstruction, both for appearance and forfunction compensations, proves to be complicatedprojects. With the development of science and tech-nology, both researchers and disabilities hope to haveartificial limb much more perky, comfortable, dex-terous and effective. Although thousands of pros-thetic limbs are commercially available worldwide,most of them, from mechanical styles to electricstyles, from motion controlled t…  相似文献   

改善光纤熔接机性能的三种途径     

莫徽忠 《柳州职业技术学院学报》2007,7(2):80-82,92

简单定义了光纤熔接机的兼容性、准确性和稳定性,并提出了三种可以改善光纤熔接机性能、提高光纤熔接使用者工作效率、提高光纤接续质量和延长光纤熔接设备的使用寿命的途径.  相似文献   

黄嘌呤在多壁炭纳米管化学修饰的玻炭电极上伏安行为的研究     

孙延一 《襄樊学院学报》2003,24(5):39-41,78

研究了黄嘌呤在多壁炭纳米管化学修饰的玻炭电极上的伏安行为,其结果表明,在0.1mol·L-1磷酸盐(pH=6.5)介质中,修饰电极对黄嘌呤具有强力的吸附催化作用,其催化电流与黄嘌呤浓度在310-8～610-5mol·L-1范围内线性关系,检出限为110-8mol·L-1. 利用本法测定了人体血清中黄嘌呤的含量,效果颇佳.  相似文献