共查询到19条相似文献，搜索用时 375 毫秒
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采用高速均质剪切法制备氰酸酯树脂（CE）/纳米二氧化硅（nano-SiO2）复合材料,通过测试粘度变化,考察了nano-SiO2对复合材料粘度的影响.结果表明：nano-SiO2能够极大提高复合材料的胶粘性;相对于纯CE,3.00%nano-SiO2含量,工作温度90℃时复合材料粘度的相对提高率为67.99%;工作时间8h时复合材料粘度的相对提高率为51.51%. 相似文献
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祝保林 《渭南师范学院学报》2012,(2):61-66
于加热熔融的氰酸酯树脂(BACDy)中加入异丁烯酸甲酯(MMA),在引发剂存在下,引发单体及预聚体MMA发生本体聚合,采用同步合成法和异步合成法分别制备互穿聚合物网络氰酸酯树脂/聚异丁烯酸甲酯(BACDy/MMA-SIPN)高分子材料,研究了几种不同配比的SIPN体系.结果表明,BACDy/MMA-SIPN网络形成的反应条件对体系的力学性能和耐热性能都有较大提高.给出了较合理的制备工艺条件. 相似文献
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采用分步聚合法合成了两网质量比不同,第二网交联度均为30%的聚二乙烯基苯/聚丙烯酸甲酯互穿聚合物网络（PDVB-PMA IPN）,将它们分别用20%的NaOH/甲醇溶液碱解,合成了一网疏水、一网亲水的聚二乙烯基苯/聚丙烯酸互穿聚合物网络（PDVB-PAA IPN）。测定了两网质量比对树脂的比表面积、平均孔容、孔径以及弱酸交换量的影响。比较了不同树脂对水溶液中苯酚的吸附性能差别,测定了此类树脂的热力学数据,探讨了此类树脂的吸附机理,建立了一种通过溶胀致孔合成吸附树脂的方法。 相似文献
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吴东翔 《重庆职业技术学院学报》2012,(4):159-161
在苯乙烯-丁二烯-苯乙烯三嵌段共聚物（SBS）中添加马来酸酐化聚丁二烯（MLPB）和胺化环氧丁二烯（LCP）可以适当提高胶粘剂的力学性能,其得到的最大拉伸强度分别为2．671MPa和8．652MPa。研究结果表明,温度以及添加胺化LCP和MLPB可以促进胶粘剂中互穿聚合物网络的形成,提高胶粘剂的强度。 相似文献
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将工业二乙烯基苯和致孔剂溶胀到磺化聚二乙烯基苯树脂球中,通过悬浮聚合合成了茶碱分子印迹和非分子印迹的大孔磺化聚二乙烯基苯/聚二乙烯基苯互穿聚合物网络（PDVB-SO3H/PDVBIPN）珠体,考察了反应时间、分散剂和吸附介质对其吸附性能的影响。结果表明,吸附平衡时间是24小时,最好的分散剂为3%NaCl、1%PVA;而且CHCl3对茶碱分子印迹PDVB-SO3H/PDVBIPN树脂有“拉平效应”,而水对树脂有“区分效应”。 相似文献
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采用微波辐照技术对玉米淀粉进行了间歇式交联改性,对CaCO3进行了表面亲油性处理,再将交联改性的玉米淀粉、聚乙烯醇（PVA）、甘油及其它助剂经混炼、压片得到交联淀粉/聚乙烯醇（C-CS/PVA）可降解树脂,对其进行了CaCO3增强改性,并采用红外光谱、扫描电镜、拉伸等测试方法对其进行了表征。研究结果表明:采用硬脂酸和月桂酸钠可成功对CaCO3进行表面有机改性,其表面亲油化度可达55.6%;淀粉交联改性后仍能保持分散及表面形貌,粒径为520μm;当淀粉用量为30份时C-CS/PVA可降解树脂的拉伸强度约为20MPa,断裂伸长率为233%,略低于行业标准;使用改性纳米CaCO3对C-CS/PVA可降解树脂增强,其拉伸强度可提高到22.5MPa,断裂伸长率由233%提升至350%,增强增韧效果显著。 相似文献
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李俊燕 《渭南师范学院学报》2013,(12):40-43
采用动态差示扫描量热法（DSC）对不同含量氰酸酯/水滑石复合体系进行了固化反应动力学研究,通过Kissinger法、Ozawa法和Crane法计算了复合体系的反应活化能及反应级数等固化反应参数.结果表明,水滑石纳米粒子的加入使氰酸酯固化反应放热峰的峰值温度和反应终止温度明显降低,同时降低了固化反应的表观活化能,但反应级数基本不变.这说明纳米水滑石的加入对固化反应有一定的促进作用,但并不改变氰酸酯的固化反应机理. 相似文献
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简要介绍了用原位聚合合成PET及PET／SiO2纳米复合材料的方法,并对合成材料的力学性能和摩擦性能进行了研究。研究表明：PET／SiO2纳米复合材料的拉伸强度、冲击强度、弯曲强度等较纯PET有较大提高。当SiO2含量为2％时,复合材料的拉伸强度、弯曲强度分别比纯PET提高26．4％、25．2％,当SiO2用量为1％时,其冲击强度是纯PET的1-31倍。PET／SiO2纳米复合材料比纯PET具有较好的耐磨性。 相似文献
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Projectile made of carbon fiber composite material shell and metal warhead penetrates concrete target at speeds of 336 m/s, 447 m/s and 517 m/s. The angles between the perpendicular of target surface and projectile axis are 0° and 30° . The thickness of concrete target is 200 mm and the compression strength is 30 MPa. The experimental results indicate that the strength of composite material structure is high. Composite projectile can go through concrete target without fiber segregation and breakage. The percent fill is 18.5% in the composite material projectile. It is about twice as that of metal projectile, if the density of metal is taken as 7.8 g/cm^3. Comparing with metal projectile, low-density, high-strength composite material can lessen projectile weight, improve charge-weight ratio of detonator and enhance destructive powder. 相似文献
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This paper deals with the hydration of a blend of Portland cement and activated coal gangue in order to determine the relationship
between the degree of hydration and compressive strength development. The hydration process was investigated by various means:
isothermal calorimetry, thermal analysis, non-evaporable water measurement, and X-ray diffraction analysis. The results show
that the activated coal gangue is a pozzolanic material that contributes to the hydration of the cement blend. The pozzolanic
reaction occurs over a period of between 7 and 90 d, consuming portlandite and forming both crystal hydrates and ill-crystallized
calcium silicate hydrates. These hydrates are similar to those found in pure Portland cement. The results show that if activated
coal gangue is substituted for cement at up to 30% (w/w), it does not significantly affect the final compressive strength
of the blend. A long-term compressive strength improvement can in fact be achieved by using activated coal gangue as a supplementary
cementing material. The relationship between compressive strength and degree of hydration for both pure Portland cement and
blended cement can be described with the same equation. However, the parameters are different since blended cement produces
fewer calcium silicate hydrates than pure Portland cement at the same degree of hydration. 相似文献
14.
Dissolved oxygen sensor based on sol-gel matrix doped with tris(2,2’-bipyridine)ruthenium dichloride
To establish a immobilization method of oxygen sensitive dye, a dissolved oxygen sensor based on a sol-gel matrix doped with ruthenium complex ([Ru(bpy)3]2+) as the oxygen-sensitive material is reported. The results indicate that the I0 /I100 value of the [Ru(bpy)3]2+-doped in tetraethylorthosilane (TEOS) composite films are estimated to be 10.6, where I0 and I100 correspond to the detected fluorescence intensities in pure nitrogen saturated water and pure oxygen saturated water, respectively. Also, the Stern-Volmer plot shows a very good linearity at low dissolved oxygen concentrations. The response time of the composite films is 5 s upon switching from nitrogen saturated water to oxygen saturated water and 10 s from oxygen saturated water to nitrogen saturated water. The dissolved oxygen sensors based on the ruthenium complex/TEOS composite films exhibit greater sensitivity, stability and faster response time as compared to the existing ones. Furthermore, the thin films possess greatly minimized dye leaching effect. 相似文献
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以高分子微球聚苯乙烯（PST）和聚甲基丙烯酸甲酯（PMMA）作为组装体,采用自组装方法在PST和PMMA微球表面自组装制备纳米α-Fe2O3电池负极材料,组装温度为PST（T=70℃）和PMMA（T=60℃）聚合温度.结果显示,采用PST作为组装体获得的α-Fe2O3纳米粒子颗粒更细,约70nm,粒径更均匀,分散性更好;而PMMA组装体获得的纳米粒径约80nm,分散性相对较差,主要原因是PMMA微球质地较软,易发生变形,而使α-Fe2O3纳米粒子吸附在PMMA表面不均匀,在热处理过程中受热不均导致α-Fe2O3纳米粒子尺寸不均,且有团聚趋势.XRD显示,两种组装体获得的均为纯相α-Fe2O3结构.电化学性能显示,采用PST作为组装体制备的纳米α-Fe2O3作为电池负极电化学性能明显优于PMMA组装体. 相似文献
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对工业化生产的C-Mn-Al系高强度、高塑性冷轧钢板的组织和性能进行了研究,材料的抗拉强度为730MPa,屈服强度为470MPa,延伸率达到28%,屈强比为0.63;钢中的主要强化元素为C、Mn、Al,相应的最大含量分别小于0.21%、1.5%、1.6%,材料的原料成本低,生产工艺适应性好。 相似文献
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王亦农 《江西教育学院学报》2012,33(3):39-41
LDPE是一种使用量较大的高分子材料,但其存在耐热性不高,硬度低,容易屈服变形等缺点,本文采用低密度聚乙烯搀杂炭黑,研究低密度聚乙烯/炭黑复合材料中炭黑不同含量对其力学性能、热学性能的影响。发现拉伸强度和耐热温度与炭黑的含量呈正比。当炭黑含量为3%时,LDPE/CB复合材料获得了最佳改性效果,LDPE/CB复合材料综合性能为最好。 相似文献
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Ten slender steel reinforced cencrete (SRC) composite columns are tested under eccentric loading conditions.Effects of concrete strength, slenderness of columns and eccentricity of the axial load are studied. The load-carrying capacity is reduced with increased slenderness ratio and eccentricity. Concrete strength has no obvious influence on eccentrically loaded columns. Then, a nonlinear numerical method of pin-ended slender columns is also presented. This method is applicable for determining the material failure load or buckling failure load of a slender steel reinforced concrete composite column. In this method both material and geometric nonlinearities are taken into account. The results of numerical analysis accord well with the test results. The test results are also compared with the results predicted by ACI318-05 and the China Specifications. 相似文献
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利用一次烧成和二次烧成两种方法制备了Al2TiO5-Al2O3复相陶瓷,研究了Al2TiO5-Al2O3复相陶瓷的烧结工艺和原料组成对其性能的影响．研究结果表明：Al2TiO5-Al2O3复相陶瓷的组成和烧成工艺对其性能具有重要影响．利用一次烧成制得的Al2TiO5-Al2O3复相陶瓷的综合性能优于二次烧成．一次烧成组成为80wt％氧化铝和20wt％钛酸铝的复相陶瓷,其吸水率仅有0．11％,显气孔率为0．32％,体积密度为3．00g·cm^-3,弯曲强度达152．88MPa,热膨胀系数为7．5×10^-6/℃． 相似文献