共查询到20条相似文献，搜索用时 328 毫秒
1.
郭宝会 《渭南师范学院学报》2012,(6):29-32
为了获得质量较好,经济实惠的扫描隧道显微镜针尖,设计了利用电化学腐蚀法制备针尖的控制电路.该电路包括直流腐蚀控制电路和交流腐蚀控制电路,以及利用比较器实现直流控制电路向交流电路跳转的控制电路.经过计算机仿真实验表明随着腐蚀进行,预设实际电压大于预设参考电压时,可以实现比较器反转和交流腐蚀,达到预设的功能,说明该控制电路可以制备理想的扫描隧道显微镜所用的钨针尖. 相似文献
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梁宏宇 《中小学实验与装备》2019,29(2):49-51
金属活动性顺序是通过置换反应概念以及一些实验事实的基础上归纳得出的,比如铝丝浸入硫酸铜溶液中、铜丝浸入硝酸银溶液中以及铜丝浸入硫酸铝溶液中.教师在演示铜丝浸入硝酸银溶液中的实验时,从理论的角度分析,应该看到铜丝表面有银白色的固体物质生成,溶液由无色变为蓝色,但在实际操作过程中发现,把铜丝浸入硝酸银溶液后发现铜丝表面立刻出现黑色固体物质,并不像想象的那样生成银白色固体物质,如图1所示.且经过很长时间才从黑色固体物质上长出银白色的固体(银),如图2所示. 相似文献
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持续荷载下混凝土的硫酸盐腐蚀研究 总被引：1，自引：0，他引：1
研究了普通混凝土和高强混凝土在2．5％,5．0％和10％Na2SO4溶液（质量分数）,以及承受不同应力比（0.25％和50％）弯曲荷载作用下的损伤失效规律、特点．结果表明：混凝土在硫酸盐溶液中腐蚀,其损伤劣化包括初始劣化段、性能改善段和性能劣化段．腐蚀溶液中Na2SO4浓度从2．5％增加到5．0％,混凝土失效时间缩短了25％左右;Na2SO4浓度增加到10％,失效时间缩短了40％．弯曲荷载在腐蚀后期加速混凝土的损伤劣化速度,应力比由0增加到25％,混凝土破坏时间降低15％;应力比增加到50％,其破坏时间降低25％～35％．此外,用SEM、能谱和XRD分析了混凝土在硫酸盐腐蚀作用下的腐蚀产物． 相似文献
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铜/锌在海水中的接触腐蚀行为 总被引：2，自引：0，他引：2
研究了金属铜与锌在海水中偶接时的接触腐蚀行为,考察了偶接时间、溶液中Cl-浓度、电偶对中阴阳极面积比、实验温度等因素对阳极腐蚀速度的影响.结果表明:偶接时间为24h时,腐蚀速度趋于稳定;腐蚀速度随温度升高,溶液中Cl-浓度的增大;阴阳面积比的增大而增大. 相似文献
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从热力学及动力学两个角度分析电解FeCl2溶液中阴、阳离子放电的可能性,并通过改变电解的电压、溶液pH和电解质浓度,探究电解FeCl2溶液阴、阳极电极反应的可能情况。得出阴极还原反应：Fe2+优先得电子析出银白色金属铁,而H+得电子析出H2与溶液pH和电解电压有关;阳极氧化反应：Fe2+优先失电子氧化为Fe3+,而Cl-失电子与电解电压有关的结论。 相似文献
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1.确定金属活动性顺序例1.(1993年上海高考化学题)有A、B、C、D四种金属,将A与B用导线联结起来,浸入电解质溶液中,B不易被腐蚀;将A、D分别投入到等浓度的盐酸中,D比A反应剧烈;将铜浸入B的盐溶液中无明显变化;将铜浸入C的盐溶液中,有金属C析出。据此可推知它们的金属活动性由强到弱的顺序为()。 相似文献
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研究了以石墨电极作阳极、不锈钢丝刷为阴极、Na2SO4为电解质,采用不同电解电压（20 V、5 V）对模拟硝基苯（NB）废水进行电解。测量了不同电解时间溶液的紫外光谱,结果表明：20 V电压时,硝基苯被还原为苯胺（AN）;而5 V电压时,产物除苯胺外,可能还有马来酸、对氨基苯酚、对苯二酚等。对20 V电解电压的体系,采用双波长等吸收消除干扰法求解出不同电解时间混合体系中硝基苯和苯胺各自的含量;而对5 V的电解体系,采用萘乙二胺偶氮光度法来测定电解处理后废水中苯胺和硝基苯的含量。结果显示,随着电解电压的下降,除产物成分变化外,硝基苯转化率、最大转化率需要的时间也发生变化。 相似文献
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制备了纳米复合催化剂TiSiW12O40/TiO2,利用IR、XRD和TEM对其进行了表征.研究了钨硅酸的负载量、溶液pH值、溶液浓度、光照时间等对TiSiW12O40/TiO2光催化降解亚甲基蓝的影响.TiSiW12O40/TiO2光催化降解亚甲基蓝的反应符合一级反应动力学. 相似文献
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采用失重法和电化学方法研究了不同因素对Q235钢在H2S介质中腐蚀的影响,结果表明:H2S饱和的3%NaCl溶液中,Q235钢腐蚀速率随时间延长逐渐变小而后趋向平稳,随温度的升高出现先增大较快而后趋于平缓的变化规律;含3%NaCl的H2S溶液中,随着H2S浓度的增大,Q235钢的腐蚀速率出现先增大后减小的趋势。 相似文献
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在碱性条件下,以二乙胺、二硫化碳为原料合成二乙基氨荒酸钠缓蚀剂.分别研究了反应物摩尔比、反应温度、缓蚀剂浓度、介质环境等对缓蚀效果的影响.结果表明：当二乙胺与二硫化碳摩尔比为0.7：1,氢氧化钠浓度30%,反应温度为5℃-10℃,二乙基氨荒酸钠产率为90.98%,用作缓蚀剂浓度为0.04mol·L-1时,在酸性介质中的缓蚀效率最佳,可达到98.28%,腐蚀速率0.0016g/（h·y）.该合成二乙基氨荒酸钠缓蚀剂方法简单,得到的缓蚀剂效果好. 相似文献
12.
Yu Yunman Zhang Min 《大连大学学报》1991,(1)
本文介绍了蜗杆步进机构中蜗形凸轮啮合的几个理论问题。主要有轮廓曲线要求分析。啮合曲面方程及曲率半径方程推导。曲面任意点压力角精确解和坐标方程。该理论已由实践证明是正确的。 相似文献
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The corrosion process of tinplate in deaerated functional beverage was investigated by using electrochemical impedance spectroscopy (EIS) combined with scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) techniques. The results reveal that the uncoated tinplate shows a poor corrosion resistance and the corrosion type is detinning. During the initial stage of immersion, EIS spectrum consisted of two capacitance arcs with obvious time-constant dispersion effect, which was attributed to the two-dimensional and three-dimensional inhomogeneous distribution of the electrode surface. With the increase of immersion time, the capacitance arc of high frequency shrunk and degenerated, due to the corrosion of tin coating. The pore resistance of tin coating and the charger transfer resistance of substrate, which are determined from the electrochemical equivalent circuit, can be used as the indicators of tinplate corrosion process. The decrease of the pore resistance of tin coating indicates that the corrosion degree of tin layer becomes more severe, whereas the decrease of the charger transfer resistance of substrate implies that the corrosion degree of steel substrate also becomes more severe as the immersion time prolongs. 相似文献
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纯镁及AZ61镁合金在磷酸盐中形成转化膜后,分别在水、碱溶液及钒盐溶液中进行封闭处理.采用点滴腐蚀试验、孔隙率测试和模拟海水浸泡法对封闭后的膜层的耐腐蚀性能进行研究,用显微镜对腐蚀前后的微观形貌进行了观察,讨论了腐蚀机理.试验表明,在水中封闭的膜层的耐蚀性最好,膜层的孔隙率最低;纯镁的表面转化膜层的耐海水腐蚀性能比镁合金AZ61的表面转化膜层耐海水腐蚀性能好. 相似文献
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An Mg-Zn-Mn-Ca alloy with high Zn content was fabricated by vacuum melting. The as-cast microstructure was investigated using XRD, SEM and EDS. It was shown that the alloy was composed of α-Mg, strip-like Ca2Mg6Zn3 and a few Mn- containing phases. Most of the Ca2Mg6Zn3 phase was distributed at grain boundaries while Mn-containing particles were deposited within grains. The as-cast samples were immersed in a Hank＇s balanced salt solution （HBSS） up to 24 h. The corroded surface morphology and cross-section microstructure were analyzed after different time of immersion so as to understand the corrosion behavior of the alloy. During immersion in the HBSS, the alloy corroded homogeneously at the very beginning and then localized corrosion occurred. The secondary phases protruded on the surface due to the dissolution of α-Mg, suggesting micro- galvanic corrosion occurred with secondary phases acting as the cathode and ct-Mg as the anode. Micro-cracks were formed at the interfaces between Ca2Mg6Zn3 and α-Mg, indicating an undermining tendency of the secondary phases. 相似文献
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Carol A. Smith Rodney Parks Jesse Parrish Ryan Swirski 《Journal of Adventure Education & Outdoor Learning》2018,18(1):1-14
Technology plays an integral role in the lives of the majority of the US population. As technology becomes integrated into young people’s lives, questions arise regarding its effects on learning. This exploratory study draws on interviews with students who attend university in the United States to determine how separating students from technology deepens experiential learning. Participants were interviewed following a study abroad course to New Zealand, during which they were disconnected from technologies such as cell phones, the Internet and social media. In the interviews, students discussed their feelings of being disconnected and describe how disconnecting impacted their overall experience. Participants agreed that disconnecting from technology had positive effects on experiential learning and the global experience. Major themes that emerged include students’ enhanced immersion and engagement, the value of disconnection in providing opportunities for personal growth and the difficulty of initial separation from technology as a result of conditioning. 相似文献
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丁忱陈顺玉肖秀峰 《福建工程学院学报》2020,(1):12-17
采用氨解结合乳化及热致相分离的技术来制备改性聚乳酸微球,通过浸泡法让卵磷脂包裹在改性微球上,进一步提高改性微球的亲水性。探讨了卵磷脂溶液的浓度、浸泡时间对改性微球形貌和亲水性能的影响。实验结果表明,卵磷脂修饰改性微球的最佳制备工艺条件为:卵磷脂溶液的浓度为1%,浸泡时间为5h,在此条件下制备的微球卵磷脂包裹均匀且亲水性得到了改善。通过红外光谱,X射线光电子能谱表征微球,结果表明卵磷脂已经成功接枝到改性微球上,通过水接触角测试,卵磷脂修饰后的改性微球亲水性得到了进一步提高。 相似文献
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用无穷小数法和增量极限法重新定义了空间光滑曲线在某点处的密切面、密切圆、切线、法线、副法线、曲率、曲率半径、曲率中心、曲率半径矢量以及自然坐标系.证明了质点沿空间光滑曲线运动的方向为该空间光滑曲线的切线方向. 相似文献
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针对自动控制原理中根轨迹入射角和出射角公式不能用于实数极点和零点的局限性,提出了如何求实数极点和零点的入射角和出射角的公式,说明了应用中要注意的问题,并给出了应用实例。 相似文献