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1.
Qing-Fang Guan Zi-Meng Han Tong-Tong Luo Huai-Bin Yang Hai-Wei Liang Si-Ming Chen Guang-Sheng Wang Shu-Hong Yu 《国家科学评论(英文版)》2019,6(1):64
Although a variety of nanoparticles with better-than-bulk material performances can be synthesized, it remains a challenge to scale the extraordinary properties of individual nanoscale units to the macroscopic level for bulk nanostructured materials. Here, we report a general and scalable biosynthesis strategy that involves simultaneous growth of cellulose nanofibrils through microbial fermentation and co-deposition of various kinds of nanoscale building blocks (NBBs) through aerosol feeding on solid culture substrates. We employ this biosynthesis strategy to assemble a wide range of NBBs into cellulose nanofibril-based bulk nanocomposites. In particular, the biosynthesized carbon nanotubes/bacterial cellulose nanocomposites that consist of integrated 3D cellulose nanofibril networks simultaneously achieve an extremely high mechanical strength and electrical conductivity, and thus exhibit outstanding performance as high-strength lightweight electromagnetic interference shielding materials. The biosynthesis approach represents a general and efficient strategy for large-scale production of functional bulk nanocomposites with enhanced performances for practical applications. Industrial-scale production of these bulk nanocomposite materials for practical applications can be expected in the near future. 相似文献
2.
Qi Shi Yongjun Ji Wenxin Chen Yongxia Zhu Jing Li Hezhi Liu Zhi Li Shubo Tian Ligen Wang Ziyi Zhong Limin Wang Jianmin Ma Yadong Li Fabing Su 《国家科学评论(英文版)》2020,7(3):600
Single-atom catalysts are of great interest because they can maximize the atom-utilization efficiency and generate unique catalytic properties; however, much attention has been paid to single-site active components, rarely to catalyst promoters. Promoters can significantly affect the activity and selectivity of a catalyst, even at their low concentrations in catalysts. In this work, we designed and synthesized CuO catalysts with atomically dispersed co-promoters of Sn and Zn. When used as the catalyst in the Rochow reaction for the synthesis of dimethyldichlorosilane, this catalyst exhibited much-enhanced activity, selectivity and stability compared with the conventional CuO catalysts with promoters in the form of nanoparticles. Density functional theory calculations demonstrate that single-atomic Sn substitution in the CuO surface can enrich surface Cu vacancies and promote dispersion of Zn to its atomic levels. Sn and Zn single sites as the co-promoters cooperatively generate electronic interaction with the CuO support, which further facilitates the adsorption of the reactant molecules on the surface, thereby leading to the superior catalytic performance. 相似文献
3.
Patric Wallin Carl Zandén Bj?rn Carlberg Nina Hellstr?m Erkenstam Johan Liu Julie Gold 《Biomicrofluidics》2012,6(2)
The properties of a cell’s microenvironment are one of the main driving forces in cellular fate processes and phenotype expression invivo. The ability to create controlled cell microenvironments invitro becomes increasingly important for studying or controlling phenotype expression in tissue engineering and drug discovery applications. This includes the capability to modify material surface properties within well-defined liquid environments in cell culture systems. One successful approach to mimic extra cellular matrix is with porous electrospun polymer fiber scaffolds, while microfluidic networks have been shown to efficiently generate spatially and temporally defined liquid microenvironments. Here, a method to integrate electrospun fibers with microfluidic networks was developed in order to form complex cell microenvironments with the capability to vary relevant parameters. Spatially defined regions of electrospun fibers of both aligned and random orientation were patterned on glass substrates that were irreversibly bonded to microfluidic networks produced in poly-dimethyl-siloxane. Concentration gradients obtained in the fiber containing channels were characterized experimentally and compared with values obtained by computational fluid dynamic simulations. Velocity and shear stress profiles, as well as vortex formation, were calculated to evaluate the influence of fiber pads on fluidic properties. The suitability of the system to support cell attachment and growth was demonstrated with a fibroblast cell line. The potential of the platform was further verified by a functional investigation of neural stem cell alignment in response to orientation of electrospun fibers versus a microfluidic generated chemoattractant gradient of stromal cell-derived factor 1 alpha. The described method is a competitive strategy to create complex microenvironments invitro that allow detailed studies on the interplay of topography, substrate surface properties, and soluble microenvironment on cellular fate processes. 相似文献
4.
Construction of sustainable high-performance structural materials is a core part of the key global sustainability goal. Many efforts have been made in this field; however, challenges remain in terms of lowering costs by using all-green basic building blocks and improving mechanical properties to meet the demand of practical applications. Here, we report a robust and efficient bottom-up strategy with micro/nanoscale structure design to regenerate an isotropic wood from natural wood particles as a high-performance sustainable structural material. Regenerated isotropic wood (RGI-wood) exceeds the limitations of the anisotropic and inconsistent mechanical properties of natural wood, having isotropic flexural strength of ∼170 MPa and flexural modulus of ∼10 GPa. RGI-wood also shows superior water resistance and fire retardancy properties to natural pine wood. Mass production of large sized RGI-wood and functional RGI-wood nanocomposites can also be achieved. 相似文献
5.
6.
This paper describes the use of Surface Plasmon Resonance imaging (SPRi) as an emerging technique to study bacterial physiology in real-time without labels. The overwhelming majority of bacteria on earth exist in large multicellular communities known as biofilms. Biofilms are especially problematic because they facilitate the survival of pathogens, leading to chronic and recurring infections as well as costly industrial complications. Monitoring biofilm accumulation and removal is therefore critical in these and other applications. SPRi uniquely provides label-free, high-resolution images of biomass coverage on large channel surfaces up to 1 cm2 in real time, which allow quantitative assessment of biofilm dynamics. The rapid imaging capabilities of this technique are particularly relevant for multicellular bacterial studies, as these cells can swim several body lengths per second and divide multiple times per hour. We present here the first application of SPRi to image Escherichia coli and Pseudomonas aeruginosa cells moving, attaching, and forming biofilms across a large surface. This is also the first time that biofilm removal has been visualized with SPRi, which has important implications for monitoring the biofouling and regeneration of fluidic systems. Initial images of the removal process show that the biofilm releases from the surface as a wave along the direction of the fluid flow. 相似文献
7.
Zois Boukouvalas Yuri Levin-Schwartz Vince D. Calhoun Tülay Adalı 《Journal of The Franklin Institute》2018,355(4):1873-1887
Because of its wide applicability in various disciplines, blind source separation (BSS), has been an active area of research. For a given dataset, BSS provides useful decompositions under minimum assumptions typically by making use of statistical properties—types of diversity—of the data. Two popular types of diversity that have proven useful for many applications are statistical independence and sparsity. Although many methods have been proposed for the solution of the BSS problem that take either the statistical independence or the sparsity of the data into account, there is no unified method that can take into account both types of diversity simultaneously. In this work, we provide a mathematical framework that enables direct control over the influence of these two types of diversity and apply the proposed framework to the development of an effective ICA algorithm that can jointly exploit independence and sparsity. In addition, due to its importance in biomedical applications, we propose a new model reproducibility framework for the evaluation of the proposed algorithm. Using simulated functional magnetic resonance imaging (fMRI) data, we study the trade-offs between the use of sparsity versus independence in terms of the separation accuracy and reproducibility of the algorithm and provide guidance on how to balance these two objectives in real world applications where the ground truth is not available. 相似文献
8.
When quasiparticles move in condensed matters, the texture of their internal quantum structure as a function of position and momentum can give rise to Berry phases that have profound effects on the material’s properties. Seminal examples include the anomalous Hall and spin Hall effects from the momentum-space Berry phases in homogeneous crystals. Here, we explore a conjugate form of the electron Berry phase arising from the moiré pattern: the texture of atomic configurations in real space. In homobilayer transition metal dichalcogenides, we show that the real-space Berry phase from moiré patterns manifests as a periodic magnetic field with magnitudes of up to hundreds of Tesla. This quantity distinguishes moiré patterns from different origins, which can have an identical potential landscape, but opposite quantized magnetic flux per supercell. For low-energy carriers, the homobilayer moirés realize topological flux lattices for the quantum-spin Hall effect. An interlayer bias can continuously tune the spatial profile of the moiré magnetic field, whereas the flux per supercell is a topological quantity that can only have a quantized jump observable at a moderate bias. We also reveal the important role of the non-Abelian Berry phase in shaping the energy landscape in small moiré patterns. Our work points to new possibilities to access ultra-high magnetic fields that can be tailored to the nanoscale by electrical and mechanical controls. 相似文献
9.
Xinyu Wang Jiahua Pu Yi Liu Fang Ba Mengkui Cui Ke Li Yu Xie Yan Nie Qixi Mi Tao Li Lingli Liu Manzhou Zhu Chao Zhong 《国家科学评论(英文版)》2019,6(5):929
Nanoscale objects feature very large surface-area-to-volume ratios and are now understood as powerful tools for catalysis, but their nature as nanomaterials brings challenges including toxicity and nanomaterial pollution. Immobilization is considered a feasible strategy for addressing these limitations. Here, as a proof-of-concept for the immobilization of nanoscale catalysts in the extracellular matrix of bacterial biofilms, we genetically engineered amyloid monomers of the Escherichia coli curli nanofiber system that are secreted and can self-assemble and anchor nano-objects in a spatially precise manner. We demonstrated three scalable, tunable and reusable catalysis systems: biofilm-anchored gold nanoparticles to reduce nitro aromatic compounds such as the pollutant p-nitrophenol, biofilm-anchored hybrid Cd0.9Zn0.1S quantum dots and gold nanoparticles to degrade organic dyes and biofilm-anchored CdSeS@ZnS quantum dots in a semi-artificial photosynthesis system for hydrogen production. Our work demonstrates how the ability of biofilms to grow in scalable and complex spatial arrangements can be exploited for catalytic applications and clearly illustrates the design utility of segregating high-energy nano-objects from injury-prone cellular components by engineering anchoring points in an extracellular matrix. 相似文献
10.
超疏水性纳米界面材料的制备与研究 总被引：8，自引：0，他引：8
制备并研究了几种超疏水性纳米界面材料,具体包括(1)以多孔氧化铝为模板,通过一种新的模板挤压法制备了聚丙烯腈纳米纤维,该纤维表面在没有任何低表面能物质修饰时即具有超疏水性,与水的接触角可高达173.8°.(2)利用亲水性聚合物聚乙烯醇制备了具有超疏水性的表面,打破了传统上只有利用疏水材料才能得到超疏水性表面的局限性,扩大了制备材料的应用范围.研究表明,这种特殊的现象是由于聚乙烯醇分子在纳米结构表面发生重排,使得疏水基团向外,分子间氢键向内,从而导致整个体系的表面能降低引起的.(3)将聚丙烯腈纳米纤维通过典型的热解过程,得到了具有类石墨结构的纳米结构碳膜,该膜表面在广泛pH值范围内都具有超疏水的特征,在基因传输、无损失液体输送、微流体等方面具有更广阔的应用前景.(4)利用喷涂-干燥技术制备了一种新型的同时具有超疏水及超亲油性的油水分离网膜.研究表明,网膜表面特殊的微米与纳米尺寸相结合的粗糙结构导致这种特殊的性质,该网膜具有很高的油水分离效率,具有极其广阔的应用前景. 相似文献
11.
《Journal of The Franklin Institute》2018,355(18):9351-9373
This paper deals with an application of the Sliding Mode Control (SMC) in the presence of lumped temperature disturbances in Peltier Cells (PCs). A controller is proposed so that a temperature disturbance reduction is obtained. A constructive Theorem based on a particular sliding mode surface using Lyapunov approach is demonstrated. Specifically, the proven Theorem shows a structural control law which consists of an interacting input law between the two available inputs of current and forced heat convection transfer function (ventilation input). The sliding mode surface is defined in terms of cold and hot state variables, emphasizing a new two sided control approach for PCs. In terms of applications, the localization problems are very important to minimize errors in all cases in which PCs are used. The application approach is targeted on a novel workpiece clamping device, which uses PCs to freeze water on a metallic plate under subzero temperatures. The ice structure is capable of evolving enough bonding strength to clamp workpieces form and force-fitted during machining operations without deforming the piece mechanically. This capability is especially crucial for micro parts as well as for hard to clamp pieces made of brittle or soft materials and irregular shaped complex geometries. The proposed SMC approach shows a robustness against the parametric uncertainties due to the nonlinear model of PCs. Computer simulation results as well as measurements are shown. 相似文献
12.
We present an optofluidic microvalve utilizing an embedded, surface plasmon-enhanced fiber optic microheater. The fiber optic microheater is formed by depositing a titanium thin film on the roughened end-face of a silica optical fiber that serves as a waveguide to deliver laser light to the titanium film. The nanoscale roughness at the titanium-silica interface enables strong light absorption enhancement in the titanium film through excitation of localized surface plasmons as well as facilitates bubble nucleation. Our experimental results show that due to the unique design of the fiber optic heater, the threshold laser power required to generate a bubble is greatly reduced and the bubble growth rate is significantly increased. By using the microvalve, stable vapor bubble generation in the microchannel is demonstrated, which does not require complex optical focusing and alignment. The generated vapor bubble is shown to successfully block a liquid flow channel with a size of 125 μm × 125 μm and a flow rate of ∼10 μl/min at ∼120 mW laser power. 相似文献
13.
Leonardo Lesser-Rojas K. K. Sriram Kuo-Tang Liao Shui-Chin Lai Pai-Chia Kuo Ming-Lee Chu Chia-Fu Chou 《Biomicrofluidics》2014,8(1)
We have developed a two-step electron-beam lithography process to fabricate a tandem array of three pairs of tip-like gold nanoelectronic detectors with electrode gap size as small as 9 nm, embedded in a coplanar fashion to 60 nm deep, 100 nm wide, and up to 150 μm long nanochannels coupled to a world-micro-nanofluidic interface for easy sample introduction. Experimental tests with a sealed device using DNA-protein complexes demonstrate the coplanarity of the nanoelectrodes to the nanochannel surface. Further, this device could improve transverse current detection by correlated time-of-flight measurements of translocating samples, and serve as an autocalibrated velocimeter and nanoscale tandem Coulter counters for single molecule analysis of heterogeneous samples. 相似文献
14.
Electrosprays are a powerful technique to generate charged micro/nanodroplets. In the last century, the technique has been extensively studied, developed, and recognized with a shared Nobel price in Chemistry in 2002 for its wide spread application in mass spectrometry. However, nowadays techniques based on microfluidic devices are competing to be the next generation in atomization techniques. Therefore, an interesting development would be to integrate the electrospray technique into a microfluidic liquid-liquid device. Several works in the literature have attempted to build a microfluidic electrospray with disputable results. The main problem for its integration is the lack of knowledge of the working parameters of the liquid-liquid electrospray. The “submerged electrosprays” share similar properties as their counterparts in air. However, in the microfluidic generation of micro/nanodroplets, the liquid-liquid interfaces are normally stabilized with surface active agents, which might have critical effects on the electrospray behavior. In this work, we review the main properties of the submerged electrosprays in liquid baths with no surfactant, and we methodically study the behavior of the system for increasing surfactant concentrations. The different regimes found are then analyzed and compared with both classical and more recent experimental, theoretical and numerical studies. A very rich phenomenology is found when the surface tension is allowed to vary in the system. More concretely, the lower states of electrification achieved with the reduced surface tension regimes might be of interest in biological or biomedical applications in which excessive electrification can be hazardous for the encapsulated entities. 相似文献
15.
Weijie Zhao 《国家科学评论(英文版)》2019,6(4):703
Materials can be ferroelectric, having a spontaneous electric polarization that can be reversed by an external electric field, or they can be ferromagnetic, exhibiting spontaneous magnetization that is switchable by an applied magnetic field. However, until the 1960s, scientists did not expect that these two ferroic properties could co-exist in a single material. Today, materials exhibiting more than one of the primary ferroic properties are called multiferroics. Here, the primary ferroic properties can be ferroelectricity, ferromagnetism, antiferromagnetism, ferroelasticity, ferrotoroidicity or others. Basically, the multiferroic effect originates from the simultaneous breaking of space inversion and time-reversal symmetries. Multiferroics can be imagined as a pas de deux of electricity and magnetism. Recently, National Science Review interviewed Professor Sang-Wook Cheong from Rutgers University, who is one of the pioneering scientists in this field. Cheong talked about the multiferroics field, which has been fast developing since the early 2000s. His introductions and opinions on diverse multiferroic materials and potential multiferroic devices, as well as future research directions, may provide a useful resource for researchers both inside and outside the multiferroic research field. 相似文献
16.
Seyed Amin Mirlohi Falavarjani Fattane Zarrinkalam Jelena Jovanovic Ebrahim Bagheri Ali A. Ghorbani 《Information processing & management》2019,56(6):102070
The ever increasing presence of online social networks in users’ daily lives has led to the interplay between users’ online and offline activities. There have already been several works that have studied the impact of users’ online activities on their offline behavior, e.g., the impact of interaction with friends on an exercise social network on the number of daily steps. In this paper, we consider the inverse to what has already been studied and report on our extensive study that explores the potential causal effects of users’ offline activities on their online social behavior. The objective of our work is to understand whether the activities that users are involved with in their real daily life, which place them within or away from social situations, have any direct causal impact on their behavior in online social networks. Our work is motivated by the theory of normative social influence, which argues that individuals may show behaviors or express opinions that conform to those of the community for the sake of being accepted or from fear of rejection or isolation. We have collected data from two online social networks, namely Twitter and Foursquare, and systematically aligned user content on both social networks. On this basis, we have performed a natural experiment that took the form of an interrupted time series with a comparison group design to study whether users’ socially situated offline activities exhibited through their Foursquare check-ins impact their online behavior captured through the content they share on Twitter. Our main findings can be summarised as follows (1) a change in users’ offline behavior that affects the level of users’ exposure to social situations, e.g., starting to go to the gym or discontinuing frequenting bars, can have a causal impact on users’ online topical interests and sentiment; and (2) the causal relations between users’ socially situated offline activities and their online social behavior can be used to build effective predictive models of users’ online topical interests and sentiments. 相似文献
17.
Ying Wang Guoxing You Peipei Chen Jianjun Li Gan Chen Bo Wang Penglong Li Dong Han Hong Zhou Lian Zhao 《Biomicrofluidics》2016,10(2)
The mechanical properties of red blood cells (RBCs) are critical to the rheological and hemodynamic behavior of blood. Although measurements of the mechanical properties of RBCs have been studied for many years, the existing methods, such as ektacytometry, micropipette aspiration, and microfluidic approaches, still have limitations. Mechanical changes to RBCs during storage play an important role in transfusions, and so need to be evaluated pre-transfusion, which demands a convenient and rapid detection method. We present a microfluidic approach that focuses on the mechanical properties of single cell under physiological shear flow and does not require any high-end equipment, like a high-speed camera. Using this method, the images of stretched RBCs under physical shear can be obtained. The subsequent analysis, combined with mathematic models, gives the deformability distribution, the morphology distribution, the normalized curvature, and the Young''s modulus (E) of the stored RBCs. The deformability index and the morphology distribution show that the deformability of RBCs decreases significantly with storage time. The normalized curvature, which is defined as the curvature of the cell tail during stretching in flow, suggests that the surface charge of the stored RBCs decreases significantly. According to the mathematic model, which derives from the relation between shear stress and the adherent cells'' extension ratio, the Young''s moduli of the stored RBCs are also calculated and show significant increase with storage. Therefore, the present method is capable of representing the mechanical properties and can distinguish the mechanical changes of the RBCs during storage. The advantages of this method are the small sample needed, high-throughput, and easy-use, which make it promising for the quality monitoring of RBCs. 相似文献
18.
Ever-increasing hardware capabilities and computation powers have enabled acquisition and analysis of big scientific data at the nanoscale routine, though much of the data acquired often turn out to be redundant, noisy and/or irrelevant to the problems of interest, and it remains nontrivial to draw clear mechanistic insights from pure data analytics. In this work, we use scanning probe microscopy (SPM) as an example to demonstrate deep data methodology for nanosciences, transitioning from brute-force analytics such as data mining, correlation analysis and unsupervised classification to informed and/or targeted causative data analytics built on sound physical understanding. Three key ingredients of such deep data analytics are presented. A sequential excitation scanning probe microscopy (SE-SPM) technique is first developed to acquire high-quality, efficient and physically relevant data, which can be easily implemented on any standard atomic force microscope (AFM). Brute-force physical analysis is then carried out using a simple harmonic oscillator (SHO) model, enabling us to derive intrinsic electromechanical coupling of interest. Finally, principal component analysis (PCA) is carried out, which not only speeds up the analysis by four orders of magnitude, but also allows a clear physical interpretation of its modes in combination with SHO analysis. A rough piezoelectric material has been probed using such a strategy, enabling us to map its intrinsic electromechanical properties at the nanoscale with high fidelity, where conventional methods fail. The SE in combination with deep data methodology can be easily adapted for other SPM techniques to probe a wide range of functional phenomena at the nanoscale. 相似文献
19.
Yogesh Sankarasubramaniam Krishnan Ramanathan Subhankar Ghosh 《Information processing & management》2014
Automatic text summarization has been an active field of research for many years. Several approaches have been proposed, ranging from simple position and word-frequency methods, to learning and graph based algorithms. The advent of human-generated knowledge bases like Wikipedia offer a further possibility in text summarization – they can be used to understand the input text in terms of salient concepts from the knowledge base. In this paper, we study a novel approach that leverages Wikipedia in conjunction with graph-based ranking. Our approach is to first construct a bipartite sentence–concept graph, and then rank the input sentences using iterative updates on this graph. We consider several models for the bipartite graph, and derive convergence properties under each model. Then, we take up personalized and query-focused summarization, where the sentence ranks additionally depend on user interests and queries, respectively. Finally, we present a Wikipedia-based multi-document summarization algorithm. An important feature of the proposed algorithms is that they enable real-time incremental summarization – users can first view an initial summary, and then request additional content if interested. We evaluate the performance of our proposed summarizer using the ROUGE metric, and the results show that leveraging Wikipedia can significantly improve summary quality. We also present results from a user study, which suggests that using incremental summarization can help in better understanding news articles. 相似文献
20.
Yongge Tian 《Journal of The Franklin Institute》2009,346(6):557-10057
Suppose that AXB=C is a consistent matrix equation and partition its solution X into a 2×2 block form. In this article we give some formulas for the maximal and minimal ranks of the submatrices in a solution X to AXB=C. From these formulas, we derive necessary and sufficient conditions for the submatrices to be zero and nonsingular, respectively. As applications, we give a group of formulas for the maximal and minimal ranks of submatrices in generalized inverses of matrices and their properties. 相似文献