共查询到19条相似文献，搜索用时 202 毫秒
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探讨了粒径分布较宽的粗颗粒氧化锆粉末的分散性、浆料的流变性和稳定性及其凝胶注模成型。实验结果表明,选用适量的分散荆柠檬酸铵,调整pH在8.6-10.5之间,可制备出流动性较好的固相含量高达63Vol.％的ZrO2浆料,沉降实验表明一定体积百分数的浆料的稳定性较好,悬浮粒子不会发生沉降,凝胶注模成型出的形状复杂的氧化锆湿坯体性能良好,均匀致密。 相似文献
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粗颗粒氧化锆粉体凝胶注模成型工艺研究 总被引：4，自引：0，他引：4
探讨了粒径分布较宽的粗颗粒氧化锆粉末的分散性、浆料的流变性和稳定性及其凝胶注模成型。实验结果表明，选用适量的分散剂柠檬酸铵，调整pH在8．6—10．5之间，可制备出流动性较好的固相含量高达63Vol.％的ZrO2浆科，沉降实验表明一定体积百分数的浆料的稳定性较好，悬浮粒子不会发生沉降，凝胶注模成型出的形状复杂的氧化锆湿坯体性能良好，均匀致密。 相似文献
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研究了Y-TZP/α-Al2O3复相陶瓷的凝胶注模成型工艺,着重研究了低粘度高固相体积分数浓悬浮体的制备.利用自制分散剂PA对Y-TZP、a-Al2O3进行表面吸附修饰改性,通过PA对两种颗粒的电空间稳定机制,在pH=9.5及最佳分散剂用量条件下制得低粘度高固相量的Y-TZP/α-Al2O3复相陶瓷悬浮体. 相似文献
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研究了Y-TZP/α-Al2O3复相陶瓷,在低粘度高固相体积分数浓悬浮体时的凝胶注模成型制备工艺.利用自制分散剂PA对Y-TZP、α-Al2O3进行表面吸附修饰改性,通过PA对两种颗粒的电空间稳定机制,在pH=9.5及最佳分散剂用量条件下制得低粘度高固相量的Y—TZP/α—Al2O3复相陶瓷悬浮体. 相似文献
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选用ZrO2（5wt．％Y2O2）和Al2O2为粉体原料,采用溶胶凝胶法制备氧化锆基氧化铝（YSZ／Al2O3）复合陶瓷,研究了悬浮体的Zeta电位、分散性、流变性及其显微结构．结果表明：在pH=9～10附近、选用SD-00为分散剂,加入量为1．0wt．％,粉体最佳配比为70wt．％ZrO2（5wt．％Y2O2）和30wt．％Al2O3获得固相含量为50Vol．％的悬浮体,制备出了均匀致密、高强度的YSZ／Al2O3复合陶瓷． 相似文献
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均相催化剂的固载化研究 总被引：1，自引：0，他引：1
张一平 《浙江教育学院学报》2004,(5):13-18
介绍了均相催化剂的固载化研究进展.可以通过离子交换、密封和接枝等方法将均相催化剂固载于载体之上,而载体和接枝过渡物质的接枝长度也会影响固载化催化剂的活性. 相似文献
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固相萃取技术分析环境水样中痕量铬的研究 总被引：1，自引：0，他引：1
固相萃取技术在环境样品痕量元素的分析中表现出了突出优点,重点研究了无机纳米氧化物颗粒,离子交换树脂、C18键合硅胶、分子印迹聚合物和活性炭等作为固相萃取吸附剂分析环境水样中铬形态的最新研究进展. 相似文献
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凝胶注模成型是一种制备均匀性好、强度高和形状复杂的陶瓷部件的成型技术 ,目前已在各种精密陶瓷材料的近净尺寸成型制备中得到了广泛应用 .但已有研究工作主要针对微米和亚微米尺寸的陶瓷粉末的成型 ,而大多数高级耐火材料制品都属毫米级粗颗粒的高温材料 .本文研究了粒径为毫米级粗颗粒体系SiC/Si粉末的Zeta电位、分散性以及SiC/Si浓悬浮体的流变性 ,制备了固相体积分数高达 72 %的SiC/Si浓悬浮体并浇注出形状复杂的均一致密的SiC/Si坯体 相似文献
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本文采用胶体与表面化学中的“电空间稳定机制” ,以聚甲基丙烯酸铵 (DarvanC)作为分散剂 ,以沉降高度作为衡量浆料稳定性的主要参数 ,研究了Al2 O3 粉末水悬浮液的流变特性及分散剂DarvanC加入量对Al2 O3 浆料稳定性的影响 .在最佳pH值和分散剂加入量条件下 ,制备出了高固相含量 ( 5 8vol%)、稳定性和分散性好的Al2 O3 浆料 相似文献
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Studies on the sintering, microstructure, mechanical properties and low temperature degradation behavior of yttria stabilized-tetragonal zirconia polycrystal （3Y-TZP） were carried out. The results show that the addition of Al2O3 and MgO improve the sintering at low temperatures, and cause exaggerated grain growth and the transformation of tetragonaI-ZrO2 to monoclinic-ZrO2 with corresponding changes in the mechanical properties. The addition of the yttria-free monoclinic zirconia particles change the overall yttria distribution and induce an active transformation toughening mechanism. Furthermore, the dispersed yttria-free ZrO2 can inhibit the tetragonal zirconia transformation, which is beneficial to the improvement of the low temperature degradation behavior of 3Y- TZP ceramics. 相似文献
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采用ＸＰＳ、ＵＰＳ方法,研究了存在于Ｎｉ－ＺｒＯ２复合镀层中的界面相互作用．研究结果表明,基质金属Ｎｉ与ＺｒＯ２微粒间并无新相形成,但在其界面确实存在轨道相互作用,且这种轨道相互作用是通过界面处Ｎｉ原子和Ｚｒ＋３离子之间ｄ轨道的相互搭接实现的． 相似文献
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Nanosized TiO2 particles,synthesized by microemulsion-mediated method,were characterized by XRD,TEM,EDS and BET.To judge the activity of TiO2 particles,the photocatalytic destruction of phenol in areated suspension was studied.The result shows that the photocatalytic activity of lab-made nanometer anatase TiO2 is comparable to or higher than that of commercial titania perticles.The effects of smoe processing parameters such as TiO2 content,oxygen flow rate,pH value on phenol removal were also investigated.The experimental results indicate that there is an optimum value for the TiO2 content,Sufficient O2 supply is needed, but too high gas flow rate induces large bubbles that eliminate the gas residence time and the gas/liquid contact interface,The pH value of the phenol solutions has a complex effect on the photocatalytic activity of the particles. 相似文献
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Siliconcarbide (SiC)ceramicmaterialsareusefulad vancedmaterialsinmanyfields,suchasmedicalbiomateri als ,hightemperaturesemiconductors ,synchrotronopticalel ementsandhighstrength /lightweightstructuralmaterials[1] .However,theactualapplicationisstilllimitedduetoitslowreliability ,highmachiningcosts[2 ] .Gelcastingprovidesane conomicalandfeasiblenet shape forminghomogeneousandflawlessgreenbodieswithcomplexgreenshapes. Gelcastingconsistsofin situpolymerizationthroughwhichamacromolecularnetwor… 相似文献
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刘青 《马钢职工大学学报》2013,(3):35-37
应用正交法试验设计研究了添加SiO2、α—Al2O2、ZrO2、MgO及ZrO2-MgO五种微粉的配比变化对刚玉一尖晶石质浇注料的抗折性能的影响,研究了浇注料的性能及不同微粉对浇注料的影响。 相似文献
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Ayesha K. Hashim Katharine O. Strunk Tasminda K. Dhaliwal 《Peabody Journal of Education》2018,93(2):174-189
To address disproportionalities in suspensions for students of color, many districts have prohibited schools from suspending students for willful defiance of school authorities and implemented restorative justice programs (RJP) that address student misconduct using alternative conflict resolution practices. However, there is limited evidence on the efficacy of these new policies. This article examines how the Los Angeles Unified School District's (LAUSD) suspension ban and RJP are associated with student suspensions over time, as well as suspensions across different groups of students and schools targeted by these policies. We employ an interrupted time series design using 12 years of studentlevel administrative data from the 2003–2004 to 2014–2015 school years, which allows us to examine trends in student suspensions in LAUSD before and after its suspension ban in 2011–2012 and rollout of restorative justice practices and training to schools in 2014–2015. We find large rates of decline in suspensions in the years following LAUSD's suspension ban relative to the years leading up to the ban, as well as evidence of reduced suspension gaps between frequently disciplined students and their less-disciplined peers. Additionally, we find the district's public identification of schools most in need of continued reform, and provision of restorative justice training to these schools, is associated with further reductions in suspensions. Despite this progress, suspension gaps between black and non-black students, and between special education (SPED) and non-SPED students, still persist in our data, suggesting that districts may need more time and comprehensive strategies to fully resolve these inequities. 相似文献
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运用晶格玻尔兹曼方法研究了两个颗粒在Poiseuille流中的运动行为.分析了颗粒直径和管道直径之比d/D对颗粒相互作用的影响;讨论了颗粒的水平距离、颗粒的平衡位置与颗粒直径之间的关系.研究发现当d/D小于0.5时,颗粒的水平距离稳定在4.2倍的颗粒直径左右.研究对于理解多颗粒系统中颗粒之间的相互作用等具有一定的价值. 相似文献
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根据汽车隔振基本原理,提出了悬架振动的混沌描述问题.采用汽车制动悬架隔振效率实验台获取了实验汽车前、后悬架的振动曲线,计算了系统参数如一阶固有频率和阻尼比,并计算了混沌参数如最小嵌入相空间维数和关联维,获得了汽车悬架的隔振性能、混沌参数与系统参数三者之间的对应关系.研究结果表明:对于吉普车型,可采用最小嵌入相空间维数Mmin评价前悬架隔振性能的变化,Mmin值越小,隔振性能趋差,对应于前悬架的刚度和阻尼值越小;对于不同车型,可采用关联维D2区分吉普车型或轿车型的悬架,吉普车型的D2值高于轿车型. 相似文献