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介绍了燃料燃烧过程中NOx的形成机理,结合某厂SCR法烟气脱硝项目,介绍了SCR法脱硝技术的工艺流程、主要系统、催化剂选型、SCR法烟气脱硝工艺的影响因素以及实际运行调节状况和运行中易出现的问题和注意事项。 相似文献
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杨国诗 《淮南师范学院学报》2011,13(3):19-21
煤燃烧的污染排放是我国主要大气污染源之一。分析了燃煤锅炉中NOx生成的机理,介绍了减少NOx生成和排放的工业技术,在对国内外燃煤锅炉燃烧优化技术研究现状综述的基础上,对前沿现代技术应用于燃烧优化控制的发展趋势进行了展望。 相似文献
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INTRODUCTIONThecombustionoffossilfuelsgeneratesSO2andNOxpollutantscausingairpollutionandacidrain.Existingfluegasdesulfurization(FGD)scru-bbersareefficientforcontrollingSO2emission,butareincapableofremovingwater-insolublenitricoxide.WeandotherresearcheshadreportedtheuseofmetalchelateadditivesinFGDsystemsforcom-binedremovalofNOxandSO2(Shietal.,1996a;1996b;1996c;1997;LittlejohnandChang,1990;Tsaietal.,1989;Harriottetal.,1993).FeII(EDTA,ethylenediaminetetraacetate)isoneofthemostprom… 相似文献
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Experimental study on the inhibition of biological reduction of Fe(Ⅲ)EDTA in NOx absorption solution
LI Wei WU Cheng-zhi ZHANG Shi-han SHI Yao LEI Le-cheng 《Journal of Zhejiang University. Science. B》2005,6(10)
Scrubbing of NOx from the gas phase with Fe(Ⅱ)EDTA has been shown to be highly effective. A new biological method can be used to convert NO to N2 and regenerate the chelating agent Fe(Ⅱ)EDTA for continuous NO absorption. The core of this biological regeneration is how to effectively simultaneous reduce Fe(Ⅲ)EDTA and Fe(Ⅱ)EDTA-NO, two mainly products in the ferrous chelate absorption solution. The biological reduction rate of Fe(Ⅲ)EDTA plays a main role for the NOx removal efficiency. In this paper, a bacterial strain identified as Klebsiella Trevisan sp. was used to demonstrate an inhibition of Fe(Ⅲ)EDTA reduction in the presence of Fe(Ⅱ)EDTA-NO. The competitive inhibition experiments indicted that Fe(Ⅱ)EDTA-NO inhibited not only the growth rate of the iron-reduction bacterial strain but also the Fe(Ⅲ)EDTA reduction rate. Cell growth rate and Fe(Ⅲ)EDTA reduction rate decreased with increasing Fe(Ⅱ)EDTA-NO concentration in the solution. 相似文献
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Ferrous chelate absorption is deemed a promising method for NO removal from flue gas, but the key problem is the difficulty to regenerate the absorption solution, i.e. the complexes of FeⅡ(EDTA)NO and FeⅢ(EDTA) in the solution. Two bacterial strains isolated recently from the sludge of the denitrification step of a municipal wastewater treatment plant could be applied effectively to regenerate the absorbent were Pseudomonas sp. and klebsiella trevisan sp. Pseudomonas sp. exhibited high reduction ability on FeⅡ(EDTA)NO and the klebsiella trevisan sp. was more suitable for FeⅢ(EDTA) reduction. 相似文献
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宿鹏浩 《上海海事大学学报》2011,32(4):80-84
为有效去除氮氧化物,将以微电弧放电法制备的TiO2光催化剂与直流电晕放电结合,考察放电极性、放电功率对脱硝效果的影响,分析脱硝机理,评价脱硝体系的能量效率.实验结果表明：TiO2光催化剂在正电晕放电显现出显著的光催化效应,光催化效应强弱与放电功率成正比;在TiO2光催化剂与直流电晕放电结合的情况下增大放电功率,可以提高脱硝效果,但是能量效率无损失. 相似文献
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霾和正常天气下西安大气颗粒物中水溶性离子特征 总被引：12，自引：0，他引：12
为了探讨西安市大气颗粒物在霾天气下水溶性离子的组分特征，2005年9月至2006年9月对西安大气TSP和PM2.5进行了观测研究。结果显示，西安大气TSP和PM2.5在霾天气的总水性离子浓度分别为135.0和72.4µg∙m-3。分析的11种阴阳离子(Na+、NH4+、K+、Mg2+、Ca2+、F-、Cl-、Br-、NO2-、NO3-和SO42-)中SO42-、NO3-、NH4+是TSP和PM2.5中的主要成分，这三种离子占总水溶性离子的百分比霾天气明显高于正常天气。pH测定的结果显示，霾天气大气颗粒物均比正常天气偏酸性。对比了不同天气下的SOR(SO2转化率)和NOR(NOX转化率)，发现霾天气SO2和NOX转化率高于正常天气，尤其是SO2在霾天气更易转化为SO42-。 相似文献
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In order to investigate the effects of methyl ester moiety on polycyclic aromatic hydrocarbons (PAHs) and NO x formation in biodiesel combustion, the combined models were developed based on detailed methyl butanoate (MB) oxidation model and n-butane model. Also, PAHs detailed reaction mechanism and NO x formation mechanism were added to the detailed models to form the combined models. The combined models were used to compare the combustion of n-butane and MB in a shock tube simulation to understand the effects of methyl ester moiety. The results indicated that compared with n-butane, the methyl ester moiety in MB leads to different reaction pathways, more CO and CO 2 formation and less formation of PAHs precursors such as ethylene and acetylene. In addition, a better chemical insight into the effects of methyl ester moiety on NO x formation was given, which will help to understand the combustion process of biodiesel. 相似文献
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运用实地调查和定量定性分析的研究方法,针对内江市城区大气中的三大主要污染物SO2、NOx、总悬浮颗粒物的环境质量监测数据,分析其污染因素：生活污染、工业污染、交通污染、农业污染和其他污染,并由此提出污染防治的措施和建议：控制污染源,合理规划城市建设,改变能源结构,加大植树造林力度． 相似文献