共查询到20条相似文献，搜索用时 156 毫秒
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Yong NIE ;Xiao-jiang LIANG ;Mei-zhen LU ;Feng-wen YU ;Da-yong GU ;Min MIN ;Jian-bing JI 《浙江大学学报(A卷英文版)》2014,15(7):540-546
研究目的：研究方法：重要结论：确定氢氧化钠溶液化学吸收硫酰氟的传质反应动力学区域,建立增强因子模型。研究气液传质测定设备双搅拌釜中氢氧化钠溶液化学吸收硫酰氟的过程,并结合实验研究与理论分析建立了增强因子模型。基于氢氧化钠溶液化学吸收硫酰氟过程的实验研究,确定了氢氧化钠溶液化学吸收硫酰氟的传质反应动力学区域为快速拟一级反应。得到了298K下其二级反应速率常数为1．44m3／（mol·s）,并建立了增强因子模型E=68．08CBL1/2,为脱除熏蒸后残留硫酰氟的工业化应用提供了理论依据。 相似文献
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两种方法提取生姜中挥发性化学成分的研究 总被引：1，自引：1，他引：0
报道了用水蒸汽蒸馏萃取法和同时蒸馏萃取法提取姜科植物生姜中的挥发性物质,并用气相色谱-质谱联用仪对其挥发性化学成分进行分析,分别分离并确定出28种和22种化学成分,分别占总挥发油总检出量的98．24％和97．99％。结果表明：生姜挥发油的主要化学成分是萜类化合物β-水芹烯、茨烯、冰片、柠檬醛、姜烯等． 相似文献
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赵洪喜 《洛阳师范学院学报》2002,21(5):53-54
现行的用于蒸馏和化学反应的烧瓶类玻璃仪器 ,有园底烧瓶、两颈瓶、三颈瓶等 .其存在的共同问题是为防止暴沸需加沸石 ,如反应需要搅拌 ,还必须安装搅拌装置 .加入沸石和搅拌密封 ,不但麻烦而且又容易引进杂质 .特别是对于微量、半微量试验 ,这一点尤其不能忽视 .本文介绍的这种新型反应蒸馏装置 ,不仅不易暴沸且具有自搅拌作用 ,无需另外安装搅拌装置和加沸石 ,就可以使反应和蒸馏比较容易地进行 . 相似文献
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水蒸气蒸馏法提取薄荷中挥发油 总被引：3，自引：0，他引：3
水蒸气蒸馏技术是分离和提纯中草药中挥发油的重要方法，采用水蒸馏蒸馏方法，对薄荷进行了出油率的测定．实验结果表明，出油率为1．649ml／100g，达到理论含油量的91．61％． 相似文献
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以生姜、西柚皮和香樟叶为实验材料,探讨高中生物实验有关植物芳香油提取的方法,并优化实验方案。采用水蒸气蒸馏法和水蒸气同时蒸馏萃取法两种提取方法,结果表明水蒸气同时蒸馏萃取法提取植物芳香油出油率比水蒸气蒸馏法的高,同时可用生姜、西柚皮和香樟叶代替教材中玫瑰花瓣作为实验材料,成本更低,同时也能达到教学效果。 相似文献
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借鉴动物红细胞流变学模型,提出植物细胞悬浮培养体系流变特性的物理模型和数学模型.根据模型得出此体系是假塑性流体,且流动特性指数随细胞浓度的变化规律与实验结果一致.模型还可解释植物细胞悬浮培养体系根据植物细胞悬浮培养体系流变特性的其它流变特性(如表观粘度随细胞浓度、搅拌转速和空气流量及细胞团大小的变化规律).通过对模型的进一步研究,可望对植物细胞培养体系的工艺设计、最佳操作和反应器评价与放大提供依据. 相似文献
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大蒜油提取方法及其研究进展 总被引：3，自引：0，他引：3
阐述了水蒸汽蒸馏、溶剂萃取和超临界二氧化碳萃取三种提取大蒜油的方法，比较了三种方法的特点，并对超声波技术应用于溶剂萃取作了初步探讨． 相似文献
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CHERALATHAN M VELRAJ R. RENGANARAYANAN S. 《浙江大学学报(A卷英文版)》2006,7(11):1886-1895
INTRODUCTION Cool thermal energy storage (CTES) using the latent heat concept as an alternative to sensible heat storage offers a good option because of its high storage density and the nearly constant temperature heat removal characteristics during the discharging cycle. Since the principle of latent cool storage nec- essarily involves a change of state, heat transfer must occur in different modes depending on the state of charging and discharging. During the periods of low cooling dema… 相似文献
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The relation between the critical radius and the particle size distribution for generalized Ostwald type ripening processes whereby the mass transfer coefficient is modelled by a power law was derived. The critical radius is determined by the growth rate, the mass transfer coefficient and the mass balance, and is independent of whether the limiting stationary growth regime has been obtained. 相似文献
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INTRODUCTION A polydisperse precipitate produced by nuclea-tion in a metastable supersaturated solution is far from thermodynamic equilibrium, i.e. a state of minimal free energy. A decrease of free energy is accom-plished by a coarsening of the precipitate which es-sentially reduces the surface free energy with respect to the surrounding solution. The process is called Ostwald ripening and is a direct consequence of the Kelvin effect (Adamson and Gast, 1997), that is the higher solubi… 相似文献
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A mathematical model of the dynamic behavior of countercurrent chromatography was proposed, and the model parameters, including the partition coefficient, the axial dispersion coefficient, the intraparticle diffusion coefficient and the external mass ransfer coefficient were calculated by the method of chromatogram moment analysis. Comparison of the experimental chromatograms of caffeine and theophylline determined in this work with the simulated curves computed by the proposed model showed fairly good agreement. Further, the difference between the average identified the partition coefficients by chromatogram moment analysis and the experimental values was small also, and the relationship between the external mass transfer rate and the linear velocity was similar to that obtained with solid-liquid chromatography. 相似文献
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Danckwert's method was used to determine the specific interfacial area, a, and the individual mass transfer coefficient, kL, during absorption of CO2 in a bubble column with an anionic surfactant in the carbonate-bicarbonate buffer solution and NaAsO2 as catalyst, the presence of which decreases the specific interfacial area and the individual mass transfer coefficient. The specific interfacial area and the individual mass transfer coefficient increase with increasing superficial gas velocity. The specific interfacial area decreases whereas the individual mass transfer coefficient increases with increasing temperature. The results of experiments were used to determine the dependence of a, kL, and kLa on the surface tension, the temperature of the absorption phase, and the superficial velocity of the gas. The calculated results from the correlation were found to be within 10% deviation from the actual experimental results. 相似文献
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This study deals with the effect of hydrotropes on the solubility and mass transfer coefficient of salicylic acid. The solubility and mass transfer studies were performed using the hydrotropes, i.e., sodium acetate, sodium salicylate, citric acid, and urea at concentrations of 0-3.0 mol/L and system temperatures of 303-333 K. It was found that the solubility and mass transfer coefficient of salicylic acid increases with increase in hydrotrope concentration and also with system temperature. All hydrotropes used in this work showed an enhancement in solubility and mass transfer coefficient to different degrees. The maximum enhancement factor values were determined for all hydrotropes used in this study. The highest value was 28.08 for solubility studies and 10.42 for mass transfer studies. The performance of hydrotropes was measured in terms of the Setschenow constant （Ks）. The highest value observed was 0.696. 相似文献
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通过对现有化工原理吸收实验装置的分析,设计出了一种多功能化工原理吸收实验装置,并将实验室的现有吸收实验装置进行了改造。与传统装置相比,新开发的实验装置具有以下功能:可以测定多种散装填料的吸收传质系数;不同类型填料的吸收传质系数;单一的规整填料的吸收传质系数以及规整填料和散装填料的混合吸收传质系数。通过填料吸收塔实验装置的改进,使学生对填料吸收实验的印象更加深刻,实验教学内容更加丰富,增强学生的创新意识,锻炼了学生的实践能力。 相似文献
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Numerical study of heat transfer characteristics of downward supercritical kerosene flow inside circular tubes 总被引：3，自引：0，他引：3
The heat transfer characteristics of China RP-3 aviation kerosene flowing in a vertical downward tube with an inner diameter of 4 mm under supercritical pressures are numerically studied. A ten-species surrogate model is used to calculate the thermophysical properties of kerosene and the re-normalization group (RNG) k-ε turbulent model with the enhanced wall treatment is adopted to consider the turbulent effect. The effects of mass flow rate, wall heat flux, inlet temperature, and pressure on heat transfer are investigated. The numerical results show that three types of heat transfer deterioration exist for the aviation kerosene flow. The first type of deterioration occurred at the tube inlet region and is caused by the development of the thermal boundary layer, while the other two types are observed when the inner wall temperature or the bulk fuel temperature approaches the pseudo-critical temperature. The heat transfer coefficient increases with the increasing mass flow rate and the decreasing wall heat flux, while the inlet bulk fluid temperature only influences the starting point of the heat transfer coefficient curve plotted against the bulk fluid temperature. The increase of inlet pressure can effectively eliminate the deterioration due to the small variations of properties near the pseudo-critical point at relatively high pressure. The numerical heat transfer coefficients fit well with the empirical correlations, especially at higher pressures (about 5 MPa). 相似文献
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为了探索油气在冷凝回收过程中的冷凝规律,采用气液两相流模型描述了油气在竖直管内湍流流动时的冷凝过程.采用有效传质系数描述了油气组分的质量传递.模拟了油气在管内冷凝时的温度、管内压力、液膜厚度和Nusselt数的变化,得到了入口油气和管壁的温差、雷诺数对冷凝率和Nusselt数的影响.结果显示：增大入口雷诺数能显著增强传热和冷凝,但是增大入口油气和管壁的温差对冷凝率的影响较小;另外,还发现传质阻力对油气冷凝率有较大影响.此模型的计算结果与先前的实验数据能够很好地符合. 相似文献
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对顶喷流化床中的颗粒干燥过程进行模拟.引进润湿率参数表示喷雾液滴对流化颗粒的有限润湿,并利用聚丙烯和水物系的实验数据回归得到了该物系的润湿率表达式.通过得到的润湿率对顶喷流态化过程进行模拟,模拟结果与实验结果基本一致,润湿率及过程模型得到了验证. 相似文献