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1.
In this work we study the behaviour of the dielectric constant of BaTiO3 single crystals doped with Cu and Fe for different ion percentages, particularly, the influence of these hetemvalent substitutions on the ferroelectric-paraelectric phase transition whose temperature is found at Tc=120℃ for pure samples. The dielectric constant e in terms of temperature shows that the Curie temperature decreases when the quantity of impurities increases and presents a broadening and flattering of the maximum oft（T） within higher values, with the transition becoming more and more diffuse. It is interesting to have a material with very high permittivity （high-k） because of its capacity to store an important quantity of electric charges. The t anisotropy and the Curie-Weiss law are also verified with a good ratio between the slopes ofε^-l（T） from both sides of the transition, leading to a Curie constant： C= 13 × 10^4 K for BaTiO3：1.6%Fe in the polar phase. BaTiO3 is a displacive ferroelectric going through a first-order phase transition. The substitutions have an effect on the dynamics of the perovskite lattice. They induce charges transfer to Ti and a diminution of elastic forces in BaTiO3. Then we discuss the transition but on the nature of the material. fact that the maximum of permittivity does not depend on the phase  相似文献   

2.
INTRODUCTION Enzymes are efficient and specific biocatalysts widely used in food industries, but their application in industrial process often involves special properties not found in natural source enzymes. In order to ob- tain desirable enzymes, in the past ten years, scientists have developed rational (Kurth et al., 1998; Mouratou et al., 1999; DeSantis et al., 1999) and irrational de- sign methods (Babbitt and Gerlt, 1997; O’Brien and Herschlag, 1999) to improve the enzyme propert…  相似文献   

3.
A discriminant method for optimizing activity in nuclear medicine studies is validated by comparison with ROC （received operating characteristic）-curves. The method is tested in 21 single photon emission computerized tomography （SPECT）, performed with a cardiac phantom. Three different lesions （Lb L2 and L3） were placed in the myocardium-wall by pairs fbr each SPECT. Three activities （84, 37 or 18.5 MBq） of 99mTc were used as background. Linear discriminant analysis was used to select the parameters that characterize image quality among the measured variables in the images [（Background-to-Lesion （B/Li） and Signal-to-Noise （S/N） ratios）]. Two clusters with different image quality （P=0.021 ） were obtained. The ratios B/Lj, B/L2 and B/L3 are the parameters used to construct the function with 100% of cases correctly classified into the clusters. The value of 37 MBq was the lowest tested activity for which good results for the B/Li ratios were obtained. The result coincides with the applied ROC-analysis （r=0.89）.  相似文献   

4.
In this paper, crude monkshood polysaccharide was isolated from Radix Aconiti Lateralis Preparata. The effects of crude monkshood polysaccharide on Escherichia coli and Staphylococcus aureus were investigated by microcalorimetry. The power-time curves of the bacterial growth at various concentrations (c) of crude monkshood polysaccharide were plotted with a TAM air isothermal microcalorimeter at 37 °C. The growth rate constant (μ), inhibitory ratio (I), peak-height (P m), and peak-time (t m) were calculated. From the data, the relationship between μ and c also was established. The growth rate constant μ decreased with the increasing concentrations of crude monkshood polysaccharide. Moreover, P m reduced and t m increased with increasing concentrations. The experimental results revealed that crude monkshood polysaccharide had inhibitory activity towards S. aureus and E. coli. Results obtained from our study strongly suggest that microcalorimetry is a fast, simple, and more sensitive technology that can be easily performed to study the effect of drugs on bacteria.  相似文献   

5.
The magnetic properties of as-quenched and annealed Fe73.5Ag1Nb3Si13.5B9 alloys were investigated. X-ray diffraction was used to monitor the structure changes of the samples under different annealing temperatures. It was found that by Cu addition, the crystallization temperature T x1 of Fe-Nb-Si-B alloy is decreased, whereas by Ag addition, the T x1 is increased. A small amount of α-Fe and Ag were obtained after the sample was annealed at 500°C for 1 h. With increasing the annealing temperature, Fe23B6, Fe2B, Fe3B were separated out and magnetic properties of the samples were impaired quickly. A mostly single nanocrystalline grain of a-Fe phase could not be obtained in the annealed samples.  相似文献   

6.
Transgenic Brassica compestris L.spp.chinensis plants expressing a choline oxidase(codA) gene from Arthrobacter globiformis were obtained through Agrobacterium tumefaciens-mediated transformation.In the transgenic plants,codA gene expression and its product transportation to chloroplasts were detected by the enzyme-linked immunosorbent assay(ELISA) examination,immunogold localization,and 1 H-nuclear magnetic resonance( 1 H-NMR) . Stress tolerance was evaluated in the T3 plants under extreme temperature and salinity conditions.The plants of transgenic line 1(L1) showed significantly higher net photosynthetic rate(Pn) and Pn recovery rate under high(45°C,4 h) and low temperature(1°C,48 h) treatments,and higher photosynthetic rate under high salinity conditions(100,200,and 300 mmol/L NaCl,respectively) than the wild-type plants.The enhanced tolerance to high temperature and high salinity stresses in transgenic plants is associated with the accumulation of betaine,which is not found in the wild-type plants.Our results indicate that the introduction of codA gene from Arthrobacter globiformis into Brassica compestris L.spp.chinensis could be a potential strategy for improving the plant tolerance to multiple stresses.  相似文献   

7.
Octenyl succinic anhydride （OSA） modified early Indica rice starch was prepared in aqueous slurry systems using response surface methodology. The paste properties of the OSA starch were also investigated. Results indicated that the suitable parameters for the preparation of OSA starch from early Indica rice starch were as follows： reaction period 4 h, reaction temperature 33.4℃, pH of reaction system 8.4, concentration of starch slurry 36.8% （in proportion to water, w/w）, amount of OSA 3% （in proportion to starch, w/w）. The degree of substitution was 0.0188 and the reaction efficiency was 81.0%. The results of paste properties showed that with increased OSA modification, the starch derivatives had higher paste clarity, decreased retrogradation and better freeze-thaw stability.  相似文献   

8.
1　Ｉｎｔｒｏｄｕｃｔｉｏｎ　Ｉｎｔｈｅｐａｓｔｄｅｃａｄｅｏｒｓｏ ,ｔｈｅｅｘｉｓｔｅｎｃｅｏｆｇｌｏｂａｌａｔ ｔｒａｃｔｏｒｓａｎｄｔｈｅｅｓｔｉｍａｔｅｓｏｆｔｈｅｉｒＨａｕｓｄｏｒｆｆａｎｄｆｒａｃｔａｌｄｉｍｅｎｓｉｏｎｓｈａｖｅｂｅｅｎｉｎｖｅｓｔｉｇａｔｅｄｆｏｒｎｕｍｅｒｏｕｓｄｉｓｓｉｐａ ｔｉｖｅｎｏｎｌｉｎｅａｒｐａｒｔｉａｌｄｉｆｆｅｒｅｎｔｉａｌｅｑｕａｔｉｏｎｓｗｈｉｃｈａｒｅａｕ ｔｏｎｏｍｏｕｓ[1～ 4 ].Ｔｈｅｎｏｎ ａｕｔｏｎｏｍｏｕｓｉｎｆｉｎｉｔｅ ｄｙｎａｍｉ…  相似文献   

9.
This two-part article considers certain fundamental symmetries of nature, namely the discrete symmetries of parity (P), charge conjugation (C) and time reversal (T), and their possible violation. Recent experimental results are discussed in some depth. In this second part, we discussCP andT violation and arrive at a synthesis.  相似文献   

10.
Chemically processed Nb-doped SrTiO3 films and properties   总被引：1，自引：0，他引：1  
Homogeneous, crack-free SrNbxTi1−x O3 thin films on (110) silicon substrates were successfully fabricated by sol-gel processing. The optimum route and conditions were systematically investigated. Sr(OAc)2 glacial acctic acid solution, after being refluxed and reacted with tartrate, formed Sr(OAc)2(C4H6O6)2; Ti(OBu)4 formed Ti(OAc)4−x (AcAc)x after having the ligand partially exchanged with AcAc, while Nb(OC2H5)5 formed (OAc)2Nb(AcAc) (C4H6O6) by exchanging of ligand in glacial acetic acid with (CH3CO)2O. All the metal species after undergoing partial hydrolysis and polymerization with hydroxyl or oxygen, formed SrNbxTi1−x O13 cluster sol. Methyl cellulose (MCL) caused SrNbxTi1−x O3 sol to have polymeric structure and easily form films. SrNbxTi1−x O3 films with perovskite were subsequently formed after being annealed at 650∼750 °C for 60 min in 25% N2+75% H2 (volume ratio) atmosphere. Resistivity of the SrNb0.1Ti0.9O3 films at room temperature was 64 μω·cm, a particular T 2 temperature dependence of the resistivity, from 25 K up to room temperature, was observed. Project (No. 2002CB613305) supported by the National Basic Research Program (973) of China  相似文献   

11.
Enantiomers (R(+) and S(-)),RS-racemate (double compound) and (R+S)-conglomerate (mechanical mixture of enantiomers) of malic acid C 4 H 6 O 5 have been investigated by means of X-ray diffractometry and high temperature X-ray diffraction method.The RS-racemate was found to be able to form three polymorphic modifications,which we denominated as M1 (monoclinic,space group P2 1 /c),M2 (monoclinic,space group Cc),and Tc (triclinic,space group P-1),the latter modification having been unknown before.Modification Tc was also described,and its Xray diffraction characteristics,including interplanar spacings d,hkl indices,unit cell parameters,were defined.In addition,X-ray diffraction characteristics for both reported earlier M1 and M2 monoclinic polymorphic modifications were measured with higher accuracy.The ability of RS-racemate to form one of the above three modifications (M1,M2,and Tc) or their mixtures containing various proportions and combinations of the components (M1+M2,M1+Tc,or M2 +Tc) was found to depend on the type of crystallization medium (a melt,aqueous medium,ethanol or acetone solution),crystallization rate (from 2-3 minutes to 4 months),and crystallization temperature.Heating S-enantiomer and M1 RS-racemate up to their respective melting points (100 ℃ and 124 ℃,correspondingly) only made them undergo thermal deformations,while heating (R+S)-conglomerate in the temperature range of 96-110 ℃ resulted in its homogenization to form M2 RS-racemate,which,near the melting point (118 ℃),namely,in the range of 112-116 ℃,was transformed into M1 RS-racemate.  相似文献   

12.
This study deals with the influence of surface roughness on the color of resin composites. Ten resin composites (microfilled, hybrid, and microhybrid) were each polished with 500-grit, 1 200-grit, 2 000-grit, and 4 000-grit SiC papers. The roughness parameter (R a) was measured using a Plμ confocal microscope, and field-emission scanning electron microscope (Fe-SEM) images were used to investigate filler morphology. Color was measured using a spectroradiometer and a D65 standard illuminant (geometry diffuse/0° specular component excluded (SCE) mode). Surface roughness decreased with grit number and was not influenced by filler size or size distribution. A significant influence of R a on lightness (L*) was found. Lightness increased with decreases in roughness, except for specimens that underwent polishing procedure 4 (PP4; 500-grit, 1 200-grit, 2 000-grit, and 4 000-grit SiC papers consecutively). Generally, it was found that surface roughness influenced the color of resin composites. The composites that underwent PP1 (500-grit SiC paper) exhibited significant differences in chroma (C*), hue (h°), and lightness (L*) compared to composites that underwent PP3 (500-grit, 1 200-grit, and 2 000-grit SiC papers consecutively) and PP4. Color difference (ΔE*) between the polishing procedures was within acceptability thresholds in dentistry.  相似文献   

13.
１ＩｎｔｒｏｄｕｃｔｉｏｎＤｉｆｅｒｅｎｔｉａｌｅｑｕａｔｉｏｎｓｗｉｔｈｔｕｒｎｉｎｇｐｏｉｎｔｓｅｘｉｓｔｗｉｄｅｌｙｉｎｍａｎｙｐｒｏｂｌｅｍｓｏｆｍａｔｈｅｍａｔｉｃｓｐｈｙｓｉｃｓ,ｓｏｔｈｅｓｅｐｒｏｂｌｅｍｓａｒｅｖｅｒｙｉｍｐｏｒｔａ...  相似文献   

14.
Surface morphologies of Zr52.5 Al10 Ni10 Cu15 Be12.5 bulk metallic glass after being rolled at both a temperature around T9 and near （ Tx - 50） K were investigated with a scanning electron microscopy. Macroscopic and microscopic observation results show that squamae, cracks, steps and wedges exist on the surface when the samples were rolled at temperatures around Ty. However, a smooth and fiat surface appears when the samples were rolled at temperatures near （ Tx - 50） K. These results indicate that the mode of deformation in the supercooled liquid region is a partially homogeneous flow at a temperature around T9, and a fully homogeneous one at temperatures near （ Tx - 50） K. According to the results, it is more feasible to roll the amorphous alloys at temperatures near （ Tx - 50） K to obtain parts with smooth and fiat surface.  相似文献   

15.
A feeding trial was conducted for nine weeks to investigate the effects of partially replacing Ca(H2PO4)2 with neutral phytase on the growth performance, phosphorus utilization, nutrient digestibility, serum biochemical parameters, bone and carcass mineral composition, and digestive-enzyme-specific activity in crucian carp (Carassius auratus). The diets prepared with 0.8%, 0%, and 1.8% Ca(H2PO4)2 (1%=1 g/100 g) supplements were regarded as the P1E0, negative control (NC), and positive control (PC) groups, respectively; the other three experimental diets were prepared with the addition of 200, 300, and 500 U/kg of neutral phytase, respectively, based on the P1E0 group. Three hundred and eighty-four fish ((1.50±0.01) g) were randomly distributed in the six treatments with four replicates each. The fish were initially fed with 2%–3% diets of their body weight per day, with feeding twice daily (08:00 and 16:00), under a 12-h light/12-h dark cycle at the temperature of (27.56±0.89) °C. The results showed that supplemental phytase at different levels in the diet improved the final body weight, average daily gain, feed conversion ratio, phosphorus utilization, and protein efficiency ratio of crucian carp (P<0.05). Phytase supplementation increased the mineral content in serum (P), bone (P, Ca), and carcass (P, Ca, Zn, Na, and Mg) (P<0.05); the trypsin and chymotrypsin activity soared when fed with the phytase-supplemented diets (P<0.05). We may conclude that supplemental dietary neutral phytase improved the growth performance, phosphorus utilization as well as nutrient utilization in crucian carp, and it can be considered an important nutritional replacement for Ca(H2PO4)2.  相似文献   

16.
A straight, non-sporulating, Gram-variable bacillus (HKU24T) was recovered from the blood culture of a patient with metastatic breast carcinoma. After repeated subculturing in BACTEC Plus Anaerobic/F blood culture broth, HKU24T grew on brucella agar as non-hemolytic, pinpoint colonies after 96 h of incubation at 37 °C in an anaerobic environment and aerobic environment with 5% CO2. Growth was enhanced with a streak of Staphylococcus aureus. HKU24T was non-motile and catalase-negative, but positive for alkaline phosphatase, β-glucosidase, and α-glucosidase. It hydrolyzed phenylphosphonate and reduced resazurin. 16S rRNA, groEL, gyrB, recA, and rpoB sequencing showed that HKU24T occupies a distinct phylogenetic position among the Leptotrichia species, being most closely related to Leptotrichia trevisanii. Using HKU24T groEL, gyrB, recA, and rpoB gene-specific primers, fragments of these genes were amplified from one of 20 oral specimens. Based on phenotypic and genotypic characteristics, we propose a new species, Leptotrichia hongkongensis sp. nov., to describe this bacterium.  相似文献   

17.
Emotion regulation (ER) is an integral aspect of emerging adults’ mental health, yet little is known about interpersonal factors that influence ER in during this period. This investigation examines emerging adults’ desire to emulate parental ER skills in the relation between perceived parental ER and emerging adults’ emotion dysregulation.A sample of 79 emerging adults (Mage = 18.55 years, SD = .32; 88.6% female, 69.6% White) completed measures of perceived parental ER (Affective Style Questionnaire [ASQ]Hofmann and Kashdan 2010), emotion dysregulation (Difficulties in Emotion Regulation Scale [DERS]Gratz and Roemer 2004), and desire to emulate parental ER (Perception of Emotion Regulation Scale [PERS]).A desire to emulate parental ER skills moderated the relationship between perceived parental ER and emerging adults’ emotion dysregulation in general (B = -.10, SE = .048, t = ?2.07, p = .043), and low emotional awareness in particular (B = -.04 SE = .02, t = ?2.47, p = .02).Findings suggest that emerging adults with an increased desire to emulate parents with lower ER skills report greater emotion dysregulation. Implications for clinical practice, along with future directions for the field of ER, are discussed.  相似文献   

18.
The asymptotically distribution free (ADF) method is often used to estimate parameters or test models without a normal distribution assumption on variables, both in covariance structure analysis and in correlation structure analysis. However, little has been done to study the differences in behaviors of the ADF method in covariance versus correlation structure analysis. The behaviors of 3 test statistics frequently used to evaluate structural equation models with nonnormally distributed variables, χ2 test TAGLS and its small-sample variants TYB and TF(AGLS) were compared. Results showed that the ADF method in correlation structure analysis with test statistic TAGLS performs much better at small sample sizes than the corresponding test for covariance structures. In contrast, test statistics TYB and TF(AGLS) under the same conditions generally perform better with covariance structures than with correlation structures. It is proposed that excessively large and variable condition numbers of weight matrices are a cause of poor behavior of ADF test statistics in small samples, and results showed that these condition numbers are systematically increased with substantial increase in variance as sample size decreases. Implications for research and practice are discussed.  相似文献   

19.
A Gram-negative, aerobic, non-motile, rod-shaped bacterial strain, designated 25-1T, was isolated from the air inside giant panda enclosures at the Chengdu Research Base of Giant Panda Breeding, China. Strain 25-1T grew optimally at pH 7.0–8.0, at 28–30 °C and in the presence of NaCl concentrations from 0.0% to 0.5 %. 16S rRNA gene sequence analysis indicated that strain 25-1T belongs to the genus Chryseobacterium within the family Flavobacteriaceae and is related most closely to C. carnis G81T (96.4% similarity), C. lathyri RBA2-6T (95.8% similarity), and C. zeae JM1085T (95.8% similarity). Its genomic DNA G+C molar composition was 36.2%. The major cellular fatty acids were iso-C15:0 (44.0%), iso-C17:0 3OH (19.8%) and C16:1 ω7c/16:1 ω6c (12.7%). The only isoprenoid quinone was menaquinone 6 (MK-6). The major polar lipids were phosphatidylethanolamine, two unidentified amino lipids and two unidentified lipids. The DNA-DNA relatedness between strain 25-1T and C. lathyri RBA2-6T was 38%. Phenotypic, genotypic, and phylogenetic characteristics indicated that strain 25-1T is a novel member of the genus Chryseobacterium, for which the name C. chengduensis sp. nov. is proposed. The type strain is 25-1T (CCTCC AB2015133T=DSM 100396T).  相似文献   

20.
Cu(In,Ga)Se2 (CIGS) precursor films were deposited on Mo/glass by electrodeposition, and then annealed in Se vapor. The annealing temperature ranged from 450 °C to 580 °C, and two heating rates were selected. The results showed that the crystalline quality of the CIGS films and formation of the Cu-Se compound could be strongly influenced by the selenization temperature and heating rate. Raman spectroscopy and X-ray diffraction (XRD) analysis showed that when the selenization temperature was increased from 450 °C to 550 °C, the amount of binary CuSe phase decreased and the amount of Cu2Se increased. After annealing at 580 °C, a minimum amount of Cu2?xSe compounds was obtained and the degree of CIGS film crystallinity was higher than in other samples. The relationship between the properties of the film and the heating rate was studied. XRD and Raman spectra showed a decrease in the Cu2?xSe phase with increasing heating rate. Scanning electron microscopy (SEM) and XRD showed a remarkable increase in the grain size of CIGS during rapid heating.  相似文献   

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