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1.
掺杂镧铒对纳米二氧化钛薄膜光催化性能的影响   总被引:1,自引:0,他引:1  
钛酸四丁酯作为前驱体,溶胶凝胶法经煅烧在玻璃载体上制备了稀土离子(La^3+、Er^3+)掺杂的纳米TiO2薄膜光催化剂.以罗丹明B作为有机污染物,可见吸光光度法测定太阳光降解作用的结果表明,未掺杂稀土离子的TiO2薄膜光催化效果差,掺杂稀土离子的纳米TiO2薄膜具有亲水性和更好的光催化活性.稀土离子掺杂光催化效果La^3+〉Er^3+,当摩尔比Ti^4+:La^3+为0.003时光催化效果最好,对罗丹明B的降解率为87.6%.  相似文献   

2.
采用等离子体增强化学气相沉积技术制备了硼掺杂氢化非晶硅薄膜,然后经过不同温度的热退火处理,获得硼掺杂纳米硅薄膜.结果表明,退火温度为700℃时,样品中开始有纳米晶形成,随着退火温度的增加,在1000℃时,薄膜的晶化率达到77%,晶粒大小为3.9nm.退火温度低于600℃时,光学带隙随着退火温度的升高而变窄,高于600℃...  相似文献   

3.
太阳能多晶硅铸锭用熔融石英坩埚氮化硅涂层的制备   总被引:1,自引:0,他引:1  
熔融石英坩埚是生产太阳能多晶硅铸锭的必要容器,为脱模方便,需在其内表面喷涂一层氮化硅.采用高纯氮化硅粉在国产石英坩埚上喷涂,研究喷涂氮化硅浆液时石英基底温度和涂膜厚度对石英坩埚氮化硅涂层结合强度的影响.结果表明:采用高纯氮化硅粉喷涂石英坩埚基底,温度应在40℃以下且喷涂涂层厚度不宜超过80μm.  相似文献   

4.
通过超高真空反应磁控共溅射方法制备了CoTiO_2薄膜样品,在退火过程中加入了紫外光照射,研究了退火温度在反应共溅法中对薄膜微结构和磁性能的影响。形貌和结构研究表明,随着退火温度的升高样品的表面颗粒尺度逐渐减小,温度越高越有利于磁性相的形成,且500℃退火温度下锐钛矿结构的衍射峰较明显,晶胞变大;磁滞回线显示出样品呈现铁磁性特征,并且随着退火温度的升高样品的磁化强度逐渐降低;热磁曲线测量显示有序温度高于120℃。退火过程中进行辐照干预的处理,发现在薄膜制备过程中对薄膜的结构及磁性有重要影响。铁磁性有可能是起源于在热处理过程中引起的磁性离子和氧空位导致的晶格缺陷。  相似文献   

5.
采用蒸发镀膜方法,在孔径约为200 nm的多孔阳极氧化铝(AAO)模板上室温沉积名义厚度为300 nm的银薄膜样品,研究真空退火对AAO模板上Ag纳米颗粒膜的结构和光学性质的影响。微观结构利用X射线衍射仪和扫描电镜观测,光学性质采用分光光度计检测。结果表明,(111)取向的银衍射峰强度随退火温度的升高逐渐增强,当退火温度为250℃时达到最大值;银纳米颗粒平均直经随退火温度的升高呈现先缓慢增大,后迅速增大,再减小的态势,当退火温度为250℃时达到最大值140 nm,比制备态大47 nm;薄膜经真空退火后,漫反射率普遍得到提高,在可见光区域,当退火温度为200℃时,漫反射率达到最大,其值为80%,大约为制备态的3倍左右。  相似文献   

6.
采用磁控溅射方法在Si片沉积了Ti-50.9at%Ni形状记忆合金薄膜,并将薄膜分别在不同温度下进行退火.利用示差扫描量热方法(DSC)、X射线衍射仪(XRD)、透射电镜(TEM)研究了薄膜退火前后形貌、相变特征及应力随退火温度的变化.实验结果表明:溅射态薄膜为非晶态,其晶化温度范围为430℃-535℃,晶化同时伴随着Ti3Ni4相的析出;退火后的薄膜随着退火温度的升高,Rs、Af、Ms均呈上升趋势.薄膜的残余应力随着退火温度的增加而逐渐减少.  相似文献   

7.
本文采用磁控溅射法制备了HfOxNy高介电薄膜,结合XRD、XPS等手段研究了退火温度对薄膜的结构和化学键态的影响,发现N的掺入使Hf4f峰位向低能方向移动.而随着退火温度的升高,Hf4f的双峰峰位向着高结合能的方向移动,这表明N的含量随着退火温度的升高而降低.XRD结果显示N的掺人能提高薄膜的晶化温度.  相似文献   

8.
应用燃烧法在较低温度(600℃)下成功合成了CaAl2O4:Eu^2+,Nd^3+荧光粉,并研究了稀土离子Eu^2+和Nd^3+含量及点火温度对荧光粉发光性能的影响,确定了合成余辉亮度大、持续发光时间长的荧光粉时.稀土离子的最佳掺量和最佳合成温度。在此基础上研究了燃烧反应前驱体溶液中物质的结合情况。  相似文献   

9.
实现了一个窄线宽36pm的Er:Yb共掺硅基光纤激光器,输出中心波长是1569.4nm.激光器的谐振腔是由一个高反的Bragg光纤光栅和另一端光纤端面4%的菲涅尔反射组成.用3.8m长的Er:Yb共掺光纤,在975m的LD激光器泵浦下,获得了最大输出功率达到6W,斜率效率达到23.5%,在输出功率范围内有明显的功率饱和现象.  相似文献   

10.
利用磁控溅射的方法在n型硅基底制备了Cu/CoN/Si(100)和Cu/CoSiN/Si(100)薄膜,并对它们进行了不同温度的退火.用原子力显微镜观察了它们的表面形貌.用扫描透射电镜能谱分析法得到了在不同退火温度下铜在上面两种薄膜中浓度与表面距离的分布,然后利用菲克第二定律对Cu/CoN/Si和Cu/CoSiN/Si体系中cu的扩散进行了计算和分析,得出中温条件(300℃-700℃)下Cu在CoN和CoSiN两种薄膜中的扩散系数表达式分别为8.98×10^-13exp(-0.45eV/kT)cHf/s和5.39×10^-11exp(-0.49eV/kT)Cm2/s.  相似文献   

11.
汉字倒说     
汉字的六书,《说文》对“转注”一类,语焉不详。后世学者提及转注,也仅限于许慎所举出的例字。《汉字例说》一文,作者从转注的角度综合考虑,对部分现代常用字作了分析,跟传统的解释有所不同。希望能抛砖引玉,互相切磋,以推进学术研究。  相似文献   

12.
《海外英语》2007,(5):44-45
It is worthy of noting that, whilst Crookston Castle witnessed the earlier and happier portion of Mary's variegated life,  相似文献   

13.
一、吃和喝吃苹果 eat an apple, 吃药 take medicine,吃糖 have some sweets,吃饭 have one's meals,吃馆子 dine out,吃惊 be surprised/  相似文献   

14.
《海外英语》2007,(5):10-11
Many college freshmen arrive woefully unprepared to do college work, and as disadvantaged populations continue to grow, the share of the American work force that has made it through college is expected to plummet. Many experts blame that educational failure not just on high schools but also on colleges. School & College, a special report by The Chronicle, looks at efforts to fix the system. What reforms would better prepare students for college? What should schools and colleges be doing differently? How should state and federal officials help?  相似文献   

15.
钱生钱!     
我们绝大部分人都同意一件事情——我们喜欢金钱。但是你对金钱的喜欢之情足够到让你创立一份事业么?.财富通常被人忽视,主要在于人们不能真正了  相似文献   

16.
The problem on the geometrc inequalities involving an n-dimensional simplex and its inscribed simplex is studied. Aninequality is established, which reveals that the difference between the squared circumradius of the n-dimensional simplex andthe squared distance between its circumcenter and barycenter times the squared circumradius of its inscribed simplex is not lessthan the 2(n-1)th power of n times its squared inradius, and is equal to when the simplex is regular and its inscribed siplex is atangent point one. Deduction from this inequality reaches a generalization of n-dimensional Euler inequality indicating that thecircumradius of the simplex is not less than the n-fold inradius. Another inequality is derived to present the relationship betweenthe circumradius of the n-dimensional simplex and the circumradius and inradius of its pedal simplex.  相似文献   

17.
《海外英语》2007,(4):36
There are numbers of crossroads on our long and unpredictable life journey where we totally have no idea about which direction to choose. No matter what our decision is, we should not turn back, but face the music and go ahead instead. I am this kind of girl who always does try without regretting, one example is how I dealt with my love.  相似文献   

18.
王菲 《华章》2007,(12):273-273
Migration occurs behind a variety of reasons and has a great effect on the whole world. People may migrate in order to improve their economic situation, or in order to escape civil strife, persecution, and environmental disasters. The impact of migration is complex, bringing both benefits anddisadvantages. This paper briefly talks about the causes of migration, the allocation of benefits, and the ways in which individual countries and the international community deal with this important subject.  相似文献   

19.
现在,我们可以没有面包,没有钱,没有房子,没有车子……但我们唯独不能丢失的是高尚的情操,笃定的信念,还有,满满的希望!  相似文献   

20.
Using virtual reality for interactive design gives a designer an intuitive vision of a design and allows the designer to achieve a viable, optimal solution in a timely manner. The article discusses the process of making the Virtual Reality System of the Humble Administrator's Garden. Translating building data to the Virtual Reality Modeling Language (VRML) is by far unsatisfactory. This creates a challenge for computer designers to do optimization to meet requirements. Five different approaches to optimize models have been presented in this paper. The other methods are to optimize VRML and to reduce the file size. This is done by keeping polygon counts to a minimum and by applying such techniques as object culling and level-ofdetail switching.  相似文献   

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