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1.
聚对苯二甲酸类塑料(Polyethylene terephthalate,PET),是一种具备优良耐热性、电性能、耐候性、刚度和强度的综合性能较好的工程塑料材料,应用广泛,但是其自身的结晶速度较为缓慢,且效果不好,存在成型模温度高、周期长等缺点,从而限制了这种材料在工程领域的进一步发展应用。影响PET结晶行为的因素有很多,本文以成核剂为主要影响因素,分析了成核剂对PET结晶行为及力学性能的影响,结果表明成核剂可以有效地提升PET的结晶速率,促进其结晶。  相似文献   

2.
《科技风》2015,(17)
以甲醇为结晶析出溶剂,以维生素C和碳酸氢钠为原料反应合成维生素C钠盐。考察了维生素C钠盐合成过程和结晶过程中各个影响因素。以红外光谱为分析手段,确定维生素C钠盐合成的最佳条件为:维生素C与碳酸氢钠的比为1:1.1,反应时间2h,反应温度65℃,甲醇滴加速度200m L/min,搅拌速度50r/min,结晶温度0℃。  相似文献   

3.
以ZL201为研究对象,优化其时效处理工艺。运用示差扫描量热仪(DSC)对经过固溶处理后的铝合金在5℃/min的加热速度下进行热分析,得到DSC曲线峰值温度为240℃。综合考虑影响强化相析出的各种因素,新时效工艺采用加热速度为5℃/min的连续加热方式将固溶处理后的试样分别加热到230℃、235℃、240℃、245℃、250℃后炉冷,然后测定其硬度及应力腐蚀性能,并与传统时效工艺下的性能相比较。研究结果表明:新的时效工艺在235℃时,出现硬度峰值,同时应力腐蚀性能符合要求,证明ZL201连续加热的时效工艺是可行的。  相似文献   

4.
230℃和250℃温度下溶液中CH_4和CO_2之间的碳同位素交换反应的实验初步证实它们在水溶液中要比在于系统中容易进行同位素的交换。不同条件实验的比较表明溶液的酸度(或pH)、CH_4/CO_2(摩尔)和反应容器的大小等都会明显地影响同位素交换的速度。文中描述了实验方法,并从机制上初步讨论了实验结果。  相似文献   

5.
贵州石头寨二叠系古油藏是滇黔桂地区众多上古生界生物礁型古油藏的典型代表。该古油藏发育了三期溶孔、裂缝充填方解石,其中含丰富的油气包裹体,三期油气包裹体组合依次为:少量液烃包裹体一液烃包裹体+气烃包裹体一气烃包裹体,与油气包裹体共生的气液水包裹体的均一温度分别为77℃~84℃、91℃~103℃和103℃~155℃。根据含油气包裹体的均一温度,结合沉积盆地热演化史和储层埋藏史,确定石头寨古油藏三期油气充注时间分别为238—235Ma、233—230Ma和230—185Ma,第三期裂缝充填方解石的sm-Nd等时线年龄为182±21Ma。古油藏的油气充注始于印支中期,于印支晚期至燕山早期达到高峰,燕山中晚期以来遭受破坏形成现今的残余古油藏。  相似文献   

6.
文章利用西南区域5个省(区、市)322个气象站点1961~2010年气温、相对湿度、风速等资料,分析了该区域年、夏季体感温度的变化趋势及空间分布特征。结果表明:近年来受全球变暖的影响,西南区域各省(区、市)体感温度也表现为不同程度的升高。近50年(1961~2009年)西南区域平均年体感温度以0.19℃/10a的速度显著升高,尤其是近20年增幅达到0.4℃/10a;西藏体感温度增幅明显高于西南其他省(市),大部分地方增幅在0.4℃/10a以上。使用国家气候中心发布的REA加权平均得到的西南地区预估数据,分析了在A2、B1情景下西南地区21世纪体感温度变化趋势,发现2041~2070年西南区域平均年体感温度将分别增加2.2℃和1.8℃,2070年以后将分别增加4.0℃和2.4℃。  相似文献   

7.
采用超声分散法使SiO_2和EG混合,然后用半连续酯化法合成PET,研究发现SiO_2能在PET中达到均匀分散,对其热性能和结晶性能进行了测试。  相似文献   

8.
青霉素G钾工业盐生产在提纯过程中一直采用减压共沸结晶工艺,除对成品质量控制有关的参数PH、效价外,其共沸结晶工艺中真空度高低直接决定结晶液的饱和温度和水溶液蒸发速率,对青霉素G钾盐收率是关键的控制参数.通过大量的实践数据进行分析总结,得出提高共沸结晶过程中的真空度是降低结晶温度,缩短共沸周期及提高成品收率的最有效途径.对青霉素G钾工业盐共沸结晶单元操作起着有效的指导意义.  相似文献   

9.
《科技风》2016,(16)
基于高钢级管线钢的成分体系,建立双亚点阵模型:(Nbx,Ti1-x)(Cy N1-y)-Al N复合析出的热力学模型,计算出800℃~1450℃温度区间内两种不同Nb含量的管线钢中碳氮化物复合析出数据,并于Jmatpro软件计算结果进行比较,结果表明:Nb含量的增加,提高了Nb的全固溶温度,扩大了高温析出温度区域;Ti元素1200℃~1450℃温度区间内析出速度很快,1200℃时两种成分钢中Ti的析出量均大于50%;800℃平衡态时,析出物均以Nb C为主;Nb对Ti元素的交互作用,间接影响到Al N的析出。热力学计算结果与JMatpro软件计算结果进行比较,试验数据有着良好的一致性。  相似文献   

10.
目的:研究GC法测定砂仁配方颗粒中乙酸龙脑酯的含量。方法:色谱柱为DB-1毛细管柱(100%二甲基聚硅氧烷为固定相,柱长30m,内径0.25mm,膜厚度为0.25μm),检测器(FID),温度250℃,进样口温度230℃,柱温100℃,分流比为10:1。结果:加样回收率为97.84%;RSD为1.2%;相关系数r=0.9999;五批砂仁配方颗粒中乙酸龙脑酯的含量均值为42.1mg/g。结论:砂仁配方颗粒中砂仁含量以乙酸龙脑酯含量计算不得少于34mg/g。  相似文献   

11.
Aresearch group led by Prof. ZHAI Qiwei from the Institute for Nutritional Sciences under the CAS Shanghai Institutes for Biological Sciences has discovered that even relatively low doses of resveratrol--a chemical found in the skins of red grapes and in red wine--can improve the sensitivity of mice to the hormone insulin, according to a report in the October,2007 issue of Cell Metabolism. As insulin resistance is often characterized as the most critical factor contributing to the development of Type 2 diabetes, the findings“provide a potential new therapeutic approach for preventing or treating” both conditions, the researchers said.  相似文献   

12.
CAS should stick to the principle of rendering service to, and giving impetus for, the development of China's science enterprise by making S&T innovations, said CAS President LU Yongxiang. The CAS president made the remarks in a recent talk to communicate the gist of the winter session of the Party's Leading-member Group at CAS, which was held from 7 to 11 January in Beijing.  相似文献   

13.
This study examined how students who had no prior experience with videoconferencing would react to the use of videoconferencing as an instructional medium. Students enrolled in seven different courses completed a questionnaire at the beginning of the semester and again at the end of the semester. Students at the origination and remote sites did not differ in their reactions toward videoconferencing but there was a significant difference for gender. Women reacted less favorably to videoconferencing. Compared to the beginning of the semester, students reported significantly less positive attitudes toward taking a course through videoconferencing at the end of the semester. There were no significant differences in students' attitudes toward videoconferencing across courses at the beginning of the semester but there were significant differences across the courses at the end of the semester. The results suggest the need for better preparation for both students and instructors.  相似文献   

14.
With great care, Dr. ZHOU Zhonghe takes out a package wrapped by cotton tissue from a drawer and says: "This is the gem of our collections: the fossil of a bird that lived 125 million years ago!" Then, pointing at a tiny mound, he explains: "Look, this is the claw and that is the head. It was in the egg shell and ready to hatch ... The species fell into a family of waterside inhabitants."  相似文献   

15.
Ajoint study by Prof. ZHANG Zhibin from the CAS Institute of Zoology and his co-workers from Norway, US and Swiss have indicated that historical outbreaks of migratory locusts in China were associated with cold spells, suggesting that China's projected climate warming could decrease the pest's numbers. The study was published in Proceedings of theNational Academy of Sciences on 17 September, 2007.  相似文献   

16.
A computer-mediated group is a complex entity whose members exchange many types of information via multiple means of communication in pursuit of goals specific to their environment. Over time, they coordinate technical features of media with locally enacted use to achieve a viable working arrangement. To explore this complex interaction, a case study is presented of the social networks of interactions and media use among members of a class of computer-supported distance learners. Results show how group structures associated with project teams dominated who communicated with whom, about what, and via which media over the term, and how media came to occupy their own communication niches: Webboard for diffuse class-wide communication; Internet Relay Chat more to named others but still for general communication across the class; and e-mail primarily for intrateam communication. Face-to-face interaction, occurring only during a short on-campus session, appears to have had a catalytic effect on social and emotional exchanges. Results suggest the need to structure exchanges to balance class-wide sharing of ideas with subgroup interactions that facilitate project completion, and to provide media that support these two modes of interaction.  相似文献   

17.
Active biological molecules and functional structures can be fabricated into a bio-mimetic system by using molecular assembly method. Such materials can be used for the drug delivery, disease diagnosis and therapy, and new nanodevice construction.  相似文献   

18.
Electronic data interchange (EDI) provides means for interorganizational communication, creates network externalities, requires an advanced information technology (IT) infrastructure, and relies on standards. In the diffusion of such innovations, institutional involvement is imperative. Such institutions contain governmental agencies, national and global standardization organizations, local government, and nonprofit private organizations like industry associations. The last type of organizations we call intermediating institutions. They intermediate or coordinate ("inscribe") the activities of a group of would-be adopters. Unfortunately, little is known of how these organizations shape the EDI diffusion trajectory. In this article we examine one specific type of intermediating organizations?industry associations?and how they advanced the EDI diffusion process in the grocery sectors of Hong Kong, Denmark and Finland. We identify six institutional measures, placed into a matrix formed by the mode of involvement (influence vs. regulation) and the type of diffusion force (supply push vs. demand pull), that can be mobilized to further the EDI diffusion. Industry associations were found to be active users of all these measures to varying degrees. Their role was critical especially in knowledge building, knowledge deployment, and standard setting. Furthermore, institutional involvement varied due to policy and cultural contingencies and power dependencies.  相似文献   

19.
This essay focuses on universal service and the Internet as means to support social and political participation. The emphasis on access to telecommunications systems in conventional approaches to universal service is contrasted with access to content. A model of the information environment is described that accounts for the roles of content and conduit, both of which are necessary conditions to achieve true access. A method is outlined for employing information indicators to observe or measure the information environment.  相似文献   

20.
The increasing prospects of digital piracy has prompted the perceived need by electronic publishers to adopt technical systems of protection, and governments to reform their copyright laws. This article is a preliminary study of the management of intellectual property by electronic publishers, defined as those involved in the production of online databases, and CD-ROMs. It focuses on three main issues: (1) how electronic publishers view the increasing threat of piracy; (2) the methods of protection employed to protect intellectual property in digital format; and (3) the importance of technological protection of intellectual property in electronic publications. The analysis is based on a sample of 23 UK electronic publishers. The interviews revealed an interesting assortment of protection methods and did not show that technological protection was a preferred way. Instead, the means of protection, in addition to copyright law, comprised niche markets, pricing, trust, bad publicity, and nontechnical and technical means.  相似文献   

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